7-氮杂荧蒽 | 206-49-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 7-氮杂荧蒽
• 英文名称: 7-Aza-fluoranthen
• 英文别名: 7-Azafluoranthene；11-azatetracyclo[7.6.1.05,16.010,15]hexadeca-1,3,5(16),6,8,10(15),11,13-octaene
• CAS: 206-49-5
• 化学式: C₁₅H₉N
• 分子量: 203.243
• InChiKey: XJWJTIKXJYAHBE-UHFFFAOYSA-N

物化性质

• 熔点：
  96-97 °C(Solv: hexane (110-54-3))
• 沸点：
  385.5±11.0 °C(Predicted)
• 密度：
  1.309±0.06 g/cm3(Predicted)
• 保留指数：
  2176.9;2124.3;350.37;350.5;351.38;349.47

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2933990090

反应信息

• 作为反应物：
  描述：

  7-氮杂荧蒽 在 potassium permanganate 、 水 作用下， 生成 5-oxo-5H-indeno[1,2-b]pyridine-6-carboxylic acid 、 9-oxo-9H-indeno[2,1-b]pyridine-8-carboxylic acid
  参考文献：
  名称：

  Oberkobusch, Chemische Berichte, 1953, vol. 86, p. 975,978

  摘要：

  DOI：
• 作为产物：
  描述：

  [(E)-3-[2-(dimethylamino)acenaphthylen-1-yl]prop-2-enylidene]-dimethylazanium;tetrafluoroborate 以65%的产率得到
  参考文献：
  名称：

  JUTZ C.; WAGNER R.-M.; KRAATZ A.; LOEBERING H.-G., J. LIEBIGS ANN. CHEM. , 1975, NO 5, 874-900

  摘要：

  DOI：

文献信息

• Acenaphthopyridine Derivative, Material of Light-Emitting Element, Light-Emitting Element, Light-Emitting Device, and Electronic Appliance
  申请人：Takasu Takako

  公开号：US20090247753A1

  公开（公告）日：2009-10-01

  It is an object to provide a new compound which is suitable for a material of an electron-transporting layer of a light-emitting element. In particular, it is an object to provide a compound which can be used for forming a light-emitting element capable of emitting light at a low drive voltage. An acenaphthopyridine derivative represented by the following general formula (G1) is provided. In the formula, Het represents a pyridyl group or a quinolyl group.

  提供一种适用于发光元件电子传输层材料的新化合物是一个目标。特别是，提供一种可用于形成能够以低驱动电压发光的发光元件的化合物是一个目标。提供了以下一般式（G1）所代表的一种蒽醌吡啶衍生物。在该式中，Het代表吡啶基团或喹啉基团。
• COMPOUND, MATERIAL FOR ORGANIC ELECTROLUMINESCENCE ELEMENT, ORGANIC ELECTROLUMINESCENCE ELEMENT, AND ELECTRONIC DEVICE
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP3312159A1

  公开（公告）日：2018-04-25

  Provided are an organic EL device having a high emission efficiency, a material for organic EL devices, which is capable of realizing the same, and the like. More specifically, provided are a compound represented by the following formula (1), a material for organic electroluminescence devices, which contains the compound, an organic electroluminescence device using the compound, and an electronic equipment provided with the organic electroluminescence device: wherein Ar represents a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, a substituted or unsubstituted heteroaryl group having 5 to 50 ring atoms, or a group formed by a combination of these groups, and R1 to R9 each independently represent a hydrogen atom or a substituent, provided that any pair of R2 and R3, R3 and R4, R4 and R5, R6 and R7, R7 and R8, and R8 and R9 are optionally bonded to each other to form a benzene ring.

  本发明提供了一种具有高发射效率的有机电致发光器件、一种能够实现高发射效率的有机电致发光器件材料等。更具体地说，本发明提供了由下式（1）表示的化合物、含有该化合物的有机电致发光器件材料、使用该化合物的有机电致发光器件以及配备该有机电致发光器件的电子设备： 其中 Ar 代表具有 6 至 50 个环碳原子的取代或未取代的芳基、具有 5 至 50 个环原子的取代或未取代的杂芳基或由这些基团的组合形成的基团，R1 至 R9 各自独立地代表氢原子或取代基，条件是 R2 和 R3、R3 和 R4、R4 和 R5、R6 和 R7、R7 和 R8 以及 R8 和 R9 中的任意一对可任选地相互键合以形成苯环。
• Composition, compound, material for organic electroluminescence element, ink composition, organic electroluminescence element, and electronic device
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10290815B2

  公开（公告）日：2019-05-14

  A composition or a compound suitable for use in forming the layer of organic EL device by a coating method, a material for organic electroluminescence devices including the composition or the compound, an ink composition including the composition or the compound, an organic electroluminescence device employing the composition or the compound, and an electronic device including the organic electroluminescence device are provided. The compound includes a nitrogen-containing hetero aromatic hydrocarbon group which has a substituent with a specific structure. The composition includes the compound.

  本发明提供了一种适用于通过涂层方法形成有机电致发光器件层的组合物或化合物、一种包括该组合物或化合物的有机电致发光器件材料、一种包括该组合物或化合物的油墨组合物、一种采用该组合物或化合物的有机电致发光器件以及一种包括该有机电致发光器件的电子器件。化合物包括含氮杂芳烃基团，该基团具有具有特定结构的取代基。组合物包括该化合物。
• Compound, material for organic electroluminescent elements using same, and organic electroluminescent element and electronic device each using same
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10629821B2

  公开（公告）日：2020-04-21

  The present invention provides a material useful as an organic electroluminescence device material, and particularly provides: a compound having, as a substituent, a substituted aromatic heterocyclic group having a specific structure wherein any of the 1-position to 6-position or the 7-position to 10-position of fluoranthene is substituted with a nitrogen atom; a material for low-voltage organic electroluminescence devices using the compound; and an organic electroluminescence device and an electronic equipment using the material.

  本发明提供了一种可用作有机电致发光器件材料的材料，特别是提供了：一种化合物，其取代基为具有特定结构的取代芳香杂环基团，其中氟蒽的 1 位至 6 位或 7 位至 10 位中的任意一位被氮原子取代；一种使用该化合物的低压有机电致发光器件材料；以及一种使用该材料的有机电致发光器件和电子设备。
• Compound, material for organic electroluminescence element, organic electroluminescence element, and electronic device
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10790449B2

  公开（公告）日：2020-09-29

  Provided are an organic EL device having a high emission efficiency, a material for organic EL devices, which is capable of realizing the same, and the like. More specifically, provided are a compound represented by the following formula (1), a material for organic electroluminescence devices, which contains the compound, an organic electroluminescence device using the compound, and an electronic equipment provided with the organic electroluminescence device: wherein Ar represents a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, a substituted or unsubstituted heteroaryl group having 5 to 50 ring atoms, or a group formed by a combination of these groups, and W to R9 each independently represent a hydrogen atom or a substituent, provided that any pair of R2 and R3, R3 and R4, R4 and R5, R6 and R7, R7 and R8, and R8 and R9 are optionally bonded to each other to form a benzene ring.

  本发明提供了一种具有高发射效率的有机电致发光器件、一种能够实现高发射效率的有机电致发光器件材料等。更具体地说，本发明提供了由下式（1）表示的化合物、含有该化合物的有机电致发光器件材料、使用该化合物的有机电致发光器件以及配备该有机电致发光器件的电子设备： 其中 Ar 代表具有 6 至 50 个环碳原子的取代或未取代的芳基、具有 5 至 50 个环原子的取代或未取代的杂芳基或由这些基团组合而成的基团，而 W 至 R9 各自独立地代表氢原子或取代基，条件是 R2 和 R3、R3 和 R4、R4 和 R5、R6 和 R7、R7 和 R8 以及 R8 和 R9 中的任意一对可任选地相互键合以形成苯环。

表征谱图