6-[7-(9,9-Dimethylfluoren-2-yl)-9,9-dimethylfluoren-2-yl]-2-oxapentacyclo[11.7.1.03,8.09,21.014,19]henicosa-1(20),3(8),4,6,9,11,13(21),14,16,18-decaene | 1532542-11-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: 6-[7-(9,9-Dimethylfluoren-2-yl)-9,9-dimethylfluoren-2-yl]-2-oxapentacyclo[11.7.1.03,8.09,21.014,19]henicosa-1(20),3(8),4,6,9,11,13(21),14,16,18-decaene
• 英文别名: 6-[7-(9,9-dimethylfluoren-2-yl)-9,9-dimethylfluoren-2-yl]-2-oxapentacyclo[11.7.1.03,8.09,21.014,19]henicosa-1(20),3(8),4,6,9,11,13(21),14,16,18-decaene
• CAS: 1532542-11-2
• 化学式: C₅₀H₃₆O
• 分子量: 652.835
• InChiKey: YPQJRYSLEGGWSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.9
• 重原子数：
  51
• 可旋转键数：
  2
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4,4,5,5-tetramethyl-2-(9,9,9',9'-tetramethyl-9H,9'H-[2,2'-bifluorene]-7-yl)-1,3,2-dioxaborolane 、 在 2-双环己基膦-2',6'-二甲氧基联苯 、 potassium phosphate 、 tris-(dibenzylideneacetone)dipalladium(0) 、 水 作用下， 以 甲苯 为溶剂， 反应 7.0h， 以35%的产率得到6-[7-(9,9-Dimethylfluoren-2-yl)-9,9-dimethylfluoren-2-yl]-2-oxapentacyclo[11.7.1.03,8.09,21.014,19]henicosa-1(20),3(8),4,6,9,11,13(21),14,16,18-decaene
  参考文献：
  名称：

  [EN] DIBENZOXANTHENE COMPOUND, ORGANIC LIGHT-EMITTING DEVICE, DISPLAY, IMAGE INFORMATION PROCESSOR, AND IMAGE-FORMING APPARATUS
  [FR] COMPOSÉ DE DIBENZOXANTHÈNE, DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE, AFFICHAGE, PROCESSEUR DE DONNÉES D'IMAGES, ET APPAREIL FORMANT DES IMAGES

  摘要：

  提供的是一种具有高最低三重激发能级（T1能级）、窄带隙和浅最高占据分子轨道（HOMO）能级的新化合物。其中，式[1]所述的二苯并噻吩化合物由权利要求1描述。在式[1]中，R1至R7分别独立地选自氢、烷基、芳基、杂环基、芳氧基、烷氧基、氨基、硅烷基和氰基的群组。

  公开号：

  WO2014007186A1

文献信息

• Organic light-emitting element
  申请人：CANON KABUSHIKI KAISHA

  公开号：US10038152B2

  公开（公告）日：2018-07-31

  Provided is an organic light-emitting element improved in luminous efficiency and lifetime. The organic light-emitting element includes a pair of electrodes and an organic compound layer placed between the pair of electrodes, in which the organic compound layer includes an iridium complex having a benzo[f]isoquinoline of a specific structure as a ligand and a heterocycle-containing compound of a specific structure.

  本发明提供了一种在发光效率和寿命方面均有改进的有机发光元件。该有机发光元件包括一对电极和置于这对电极之间的有机化合物层，其中有机化合物层包括以特定结构的苯并[f]异喹啉为配体的铱络合物和特定结构的含杂环化合物。
• DIBENZOXANTHENE COMPOUND, ORGANIC LIGHT-EMITTING DEVICE, DISPLAY, IMAGE INFORMATION PROCESSOR, AND IMAGE-FORMING APPARATUS
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20150194609A1

  公开（公告）日：2015-07-09

  Provided is a novel compound having a high lowest triplet excited level (T1 level), a narrow bandgap, and a shallow highest occupied molecular orbital (HOMO) level. A dibenzoxanthene compound is represented by formula [1] described in Claim 1 . In formula [1], R 1 to R 7 are each independently selected from the group consisting of hydrogen, alkyl groups, aryl groups, heterocyclic groups, aryloxy groups, alkoxy groups, amino groups, silyl groups, and cyano groups.
• ORGANIC LIGHT-EMITTING ELEMENT
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20150295188A1

  公开（公告）日：2015-10-15

  Provided is an organic light-emitting element improved in luminous efficiency and lifetime. The organic light-emitting element includes a pair of electrodes and an organic compound layer placed between the pair of electrodes, in which the organic compound layer includes an iridium complex having a benzo[f]isoquinoline of a specific structure as a ligand and a heterocycle-containing compound of a specific structure.
• ORGANIC LIGHT-EMITTING DEVICE
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20150372244A1

  公开（公告）日：2015-12-24

  Provided is an organic light-emitting device having high efficiency and improved driving durability performance. The organic light-emitting device includes a pair of electrodes and an organic compound layer placed between the pair of electrodes, in which the organic compound layer includes an iridium complex having a specific skeleton and a heterocycle-containing compound as a host.
• US9899613B2
  申请人：——

  公开号：US9899613B2

  公开（公告）日：2018-02-20