2-(1",10"-phenanthrol-2"-yl)-9,9'-spirobifluorene | 1174660-93-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 2-(1",10"-phenanthrol-2"-yl)-9,9'-spirobifluorene
• 英文别名: 2-(9,9'-Spirobi[fluorene]-2-yl)-1,10-phenanthroline；2-(9,9'-spirobi[fluorene]-2-yl)-1,10-phenanthroline
• CAS: 1174660-93-5
• 化学式: C₃₇H₂₂N₂
• 分子量: 494.595
• InChiKey: QMVIRQAUHCNWJW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  39
• 可旋转键数：
  1
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-acetyl-9,9'-spirobifluorene 、 8-胺基-7-醛基喹啉 在 potassium hydroxide 作用下， 以 乙醇 为溶剂， 反应 5.0h， 以76%的产率得到2-(1",10"-phenanthrol-2"-yl)-9,9'-spirobifluorene
  参考文献：
  名称：

  Synthesis and Properties of 9,9’-Spirobifluorene-Based Heterocycles

  摘要：

  A series of 9,9'-spirobifluorene-derived N-heterocycles were prepared by Friedlander reaction of 2-acetyl-9,9'-spirobifluorene with a series of ortho-aminoaldehydes in 74-88% yields. Spectral properties and abilities to form Ru(II) complexes were examined.

  DOI：

  10.3987/com-09-11666

文献信息

• VERBINDUNGEN FÜR ELEKTRONISCHE VORRICHTUNGEN
  申请人：Merck Patent GmbH

  公开号：EP2737554B1

  公开（公告）日：2017-01-11
• HETEROCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING ELEMENT INCLUDING SAME
  申请人：LG Chem, Ltd.

  公开号：EP3575290B1

  公开（公告）日：2020-11-18
• Heterocyclic Compound and Organic Light-emitting Element Including Same
  申请人：LG Chem, Ltd.

  公开号：US20190355915A1

  公开（公告）日：2019-11-21

  The present specification relates to a heterocyclic compound represented by Chemical Formula 1 and an organic light emitting device comprising the same.
• US9780311B2
  申请人：——

  公开号：US9780311B2

  公开（公告）日：2017-10-03
• Synthesis and Properties of 9,9’-Spirobifluorene-Based Heterocycles
  作者：Yurngdong Jahng、Jong Myoung Chea

  DOI：10.3987/com-09-11666

  日期：——

  A series of 9,9'-spirobifluorene-derived N-heterocycles were prepared by Friedlander reaction of 2-acetyl-9,9'-spirobifluorene with a series of ortho-aminoaldehydes in 74-88% yields. Spectral properties and abilities to form Ru(II) complexes were examined.