Dineopentyl-sulphon | 10269-17-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 磺酰类
• 英文名称: Dineopentyl-sulphon
• 英文别名: bis-(2,2-dimethyl-propyl) sulfone；di-neopentylsulfone；1-(2,2-Dimethylpropylsulfonyl)-2,2-dimethylpropane
• CAS: 10269-17-7
• 化学式: C₁₀H₂₂O₂S
• 分子量: 206.349
• InChiKey: PIVGMZXJZZYIPS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  neopentylmagnesium bromide 在 过氧化氢苯甲酰 作用下， 以 乙醚 为溶剂， 反应 3.0h， 生成 Dineopentyl-sulphon
  参考文献：
  名称：

  氧化有机硫化物十五：对亚砜碱氧化成砜的立体效应

  摘要：

  高度支化的戊基亚烷基和二烷基亚砜的氧化表明，在碱性氧化中，即使位阻作用不是很大，位阻也比在酸性氧化中具有更显着的影响。基于这些和先前的结果，提出了关于碱性氧化的过渡态的几何构型的一些建议。

  DOI：

  10.1016/s0040-4020(01)99414-1

文献信息

• TRICYCLIC HETEROCYCLIC COMPOUNDS, COMPOSITIONS AND METHODS OF USE THEREOF
  申请人：Babu Srinivasan

  公开号：US20110201593A1

  公开（公告）日：2011-08-18

  The invention provides novel compounds of formula I having the general formula: wherein R 1 , R 2 , R 3 , X and Y are as described herein. Accordingly, the compounds may be provided in pharmaceutically acceptable compositions and used for the treatment of immunological or hyperproliferative disorders.

  本发明提供了具有以下一般式的新化合物I： 其中R1、R2、R3、X和Y如本文所述。因此，这些化合物可以在药学上可接受的组合物中提供，并用于治疗免疫或过度增生性疾病。
• Radiation curable ink jet ink, comprising a polymerisation initiation sensitising dye
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP1657286A2

  公开（公告）日：2006-05-17

  The invention provides an inkjet recording ink which is curable by radiation irradiation containing a colorant, a polymerizable compound, and a polymerization initiation system, wherein the polymerization initiation system contains a sensitizing dye including one or more compounds selected from compounds represented by any one of formula (XIV) and formulae (XVI) to (XXVI) and a polymerization initiator; and a method of producing a planographic printing plate to obtain a hydrophobic image by ejecting the ink onto a hydrophilic support, and by irradiating radiation. Moreover, the invention provides an ink composition containing a sensitizing dye including a specific skeleton or a sensitizing dye represented by formula (I), a polymerizable compound, and a polymerization initiator; an inkjet recording method using the same; a printed material; a planographic printing plate; and a method of producing a planographic printing plate.

  本发明提供了一种可通过辐射辐照固化的喷墨记录墨水，该墨水含有着色剂、可聚合化合物和聚合引发体系，其中聚合引发体系含有敏化染料，包括一种或多种选自式(XIV)和式(XVI)至(XXVI)中任一种所代表的化合物和聚合引发剂的化合物；以及一种通过将墨水喷射到亲水性支持物上并通过辐射辐照来制作平版印刷板以获得疏水性图像的方法。此外，本发明还提供了一种墨水组合物，其中含有包括特定骨架的敏化染料或由式（I）表示的敏化染料、可聚合化合物和聚合引发剂；使用该墨水组合物的喷墨记录方法；印刷材料；平版印刷板；以及平版印刷板的制作方法。
• NON-AQUEOUS ELECTROLYTE SOLUTION AND NON-AQUEOUS ELECTROLYTE RECHARGEABLE BATTERY USING SAME
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3086398A1

  公开（公告）日：2016-10-26

  A task is to provide a non-aqueous electrolytic solution exhibiting excellent cycle capacity maintaining ratio and excellent low-temperature resistance characteristics and a non-aqueous electrolyte secondary battery using the same. An object of the present invention is to provide a non-aqueous electrolytic solution which improves the cycle capacity maintaining ratio and low-temperature resistance characteristics, and a non-aqueous electrolyte secondary battery using the non-aqueous electrolytic solution. The present invention is a non-aqueous electrolytic solution comprising an electrolyte and a non-aqueous solvent dissolving therein the electrolyte, wherein the non-aqueous electrolytic solution contains a compound represented by formula (1) (wherein X represents an organic group containing a heteroatom, Y represents a sulfur atom, a phosphorus atom, or a carbon atom, n represents an integer of 1 or 2, m represents an integer of 2 to 4, 1 represents an integer of 1 or 2, and Z represents an organic group having 4 to 12 carbon atoms and optionally having a heteroatom), and a non-aqueous electrolyte secondary battery comprising the non-aqueous electrolytic solution.

  本发明的任务是提供一种非水电解质溶液，该溶液具有优异的循环容量保持率和低温电阻特性，以及使用该溶液的非水电解质二次电池。本发明的目的是提供一种可提高循环容量保持率和低温电阻特性的非水电解溶液，以及使用该非水电解溶液的非水电解质二次电池。本发明是一种非水电解质溶液，包括电解质和溶解在电解质中的非水溶剂，其中非水电解质溶液含有由式（1）代表的化合物（其中 X 代表含有杂原子的有机基团，Y 代表硫原子、磷原子或碳原子）、其中 X 代表含有杂原子的有机基团，Y 代表硫原子、磷原子或碳原子，n 代表 1 或 2 的整数，m 代表 2 至 4 的整数，1 代表 1 或 2 的整数，Z 代表具有 4 至 12 个碳原子且任选具有一个杂原子的有机基团），以及包含该非水性电解溶液的非水性电解质二次电池。
• Non-aqueous electrolytic solution and non-aqueous electrolyte secondary battery using the same
  申请人：Mitsubishi Chemical Corporation

  公开号：US10734680B2

  公开（公告）日：2020-08-04

  A task is to provide a non-aqueous electrolytic solution exhibiting excellent cycle capacity maintaining ratio and excellent low-temperature resistance characteristics and a non-aqueous electrolyte secondary battery using the same. An object of the present invention is to provide a non-aqueous electrolytic solution which improves the cycle capacity maintaining ratio and low-temperature resistance characteristics, and a non-aqueous electrolyte secondary battery using the non-aqueous electrolytic solution. The present invention is a non-aqueous electrolytic solution comprising an electrolyte and a non-aqueous solvent dissolving therein the electrolyte, wherein the non-aqueous electrolytic solution contains a compound represented by formula (1), and a non-aqueous electrolyte secondary battery comprising the non-aqueous electrolytic solution.

  本发明的任务是提供一种非水电解质溶液，该溶液具有优异的循环容量保持率和低温电阻特性，以及使用该溶液的非水电解质二次电池。本发明的目的是提供一种可提高循环容量保持率和低温电阻特性的非水电解溶液，以及使用该非水电解溶液的非水电解质二次电池。本发明是一种非水电解质溶液，包括电解质和溶解在电解质中的非水溶剂，其中非水电解质溶液含有一种由式（1）表示的化合物，以及一种包含该非水电解质溶液的非水电解质二次电池。
• Responsive microgel and methods related thereto
  申请人：——

  公开号：US20030152623A1

  公开（公告）日：2003-08-14

  A responsive microgel is provided which responds volumetrically and reversibly to a change in one or more aqueous conditions selected from the group consisting of (temperature, pH, and ionic conditions) comprised of an ionizable network of covalently cross-linked homopolymeric ionizable monomers wherein the ionizable network is covalently attached to an amphiphilic copolymer to form a plurality of ‘dangling chains’ and wherein the ‘dangling chains’ of amphiphilic copolymer form immobile micelle-like aggregates in aqueous solution. A responsive microgel is further provided that comprises at least one therapeutic entity and delivers a substantially linear and sustained release of the therapeutic entity under physiological conditions.

  本发明提供了一种响应型微凝胶，该微凝胶可对选自由温度、pH 值和离子条件组成的组中的一种或多种水性条件的变化作出体积上和可逆的响应、和离子条件）组成的共价交联均聚可离子化单体的可离子化网络，其中可离子化网络与两性共聚物共价连接，形成多条 "悬链"，两性共聚物的 "悬链 "在水溶液中形成不动的胶束状聚集体。还提供了一种响应性微凝胶，它包含至少一种治疗实体，并能在生理条件下提供治疗实体的线性和持续释放。