N-[bis[[tris(dimethylamino)-lambda5-phosphanylidene]amino]phosphinothioylimino-bis(dimethylamino)-lambda5-phosphanyl]-N-methylmethanamine

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: N-[bis[[tris(dimethylamino)-lambda5-phosphanylidene]amino]phosphinothioylimino-bis(dimethylamino)-lambda5-phosphanyl]-N-methylmethanamine
• 英文别名: N-[bis[[tris(dimethylamino)-λ5-phosphanylidene]amino]phosphinothioylimino-bis(dimethylamino)-λ5-phosphanyl]-N-methylmethanamine
• 化学式: C₁₈H₅₄N₁₂P₄S
• 分子量: 594.7
• InChiKey: USVLKKOZCNSKJN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  35
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  98.3
• 氢给体数：
  0
• 氢受体数：
  13

文献信息

• A phosphine sulfide, a manufacturing process therefor and a use thereof
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP0972776A1

  公开（公告）日：2000-01-19

  A basic organic compound which is soluble in an organic solvent, does not have problems in its preparation or handling and exhibits catalytic activity as a basic compound, is a phosphine sulfide represented by the (1): The phosphine sulfide represented by formula (1), is made by reacting one molecule of thiophosphoryl chloride with three molecules of a phosphorane represented by formula (2): A process for effectively manufacturing a poly(alkylene oxide) involves polymerizing an alkylene oxide in the presence of the above organic compound (phosphine sulfide), or in the presence of the phosphine sulfide and an active hydrogen compound selected from water and organic compounds having a partial structure of -OH or -NH-. A process for manufacturing a 1,2-dioxyethane derivative from an epoxy compound, i.e. manufacturing a 1,2-dioxyethane derivative involves reacting an epoxy compound with a carboxylate, carboxylic anhydride, carbonate or phenol compound, respectively, in the presence of the phosphine sulfide.

  一种可溶于有机溶剂、在制备或处理过程中不会出现问题并具有催化活性的碱性有机化合物是硫化膦，其代表式为（1）： 式（1）代表的硫化膦是由一分子硫代磷酰氯与三分子式（2）代表的磷烷反应制得的： 一种有效制造聚环氧亚烷烃的工艺是在上述有机化合物（硫化膦）存在下，或在硫化膦和选 自水和部分结构为-OH 或-NH-的有机化合物的活性氢化合物存在下，聚合环氧亚烷烃。 由环氧化合物制造 1，2-二氧乙烷衍生物的工艺，即制造 1，2-二氧乙烷衍生物的工艺包括在硫化膦存在下，环氧化合物分别与羧酸盐、羧酸酐、碳酸盐或苯酚化合物反应。
• POLYETHER POLYOL, HARD POLYURETHANE FOAM AND THEIR PRODUCTION METHODS
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2080778A1

  公开（公告）日：2009-07-22

  Highly-functionalized, low-viscosity polyether polyols are obtained by dehydration condensation reaction of alcohols. The polyether polyols are obtained by dehydration condensation of glycerin and monohydric and/or dihydric alcohol with the glycerin percentage being more than 50 mol% relative to 100 mol% of the total of the glycerin and alcohol. The glycerin may be crude glycerin obtained by hydrolysis or alcoholysis of natural fat and oils.

  高官能度、低粘度的聚醚多元醇是通过醇的脱水缩合反应获得的。 聚醚多元醇是通过甘油和一元醇和/或二元醇的脱水缩合反应获得的，其中甘油的比例相对于甘油和醇的总比例 100 mol% 要大于 50 mol%。甘油可以是通过水解或醇解天然油脂获得的粗甘油。
• RESIN PREMIX COMPOSITION, COMPOSITION FOR HARD POLYURETHANE FOAM, AND HARD POLYURETHANE FOAM
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2915850A1

  公开（公告）日：2015-09-09

  An object of the invention is to provide resin premix compositions which include a polyol and a hydrocarbon foaming agent while still exhibiting good storage stability, the polyol being obtained without the use of ring-opening polymerization reaction of a cyclic ether. The resin premix composition of the invention includes at least a polyol and a hydrocarbon foaming agent, the polyol including a polyether ester polyol (A) obtained by reacting a polyether polyol with a fatty acid and/or a fatty acid ester, the polyether polyol being obtained by condensing a polyhydric alcohol including 50 mol% or more of a trihydric or higher alcohol.

  本发明的目的是提供一种树脂预混料组合物，其中包括一种多元醇和一种烃类发泡剂，同时还具有良好的储存稳定性，这种多元醇是在不使用环醚开环聚合反应的情况下获得的。本发明的树脂预混料组合物至少包括一种多元醇和一种烃类发泡剂，多元醇包括一种聚醚酯多元醇 (A)，该多元醇是通过聚醚多元醇与脂肪酸和/或脂肪酸酯反应获得的，聚醚多元醇是通过缩合含有 50 摩尔%或更多三水或三水以上醇的多元醇获得的。
• PHOSPHAZENYL PHOSPHINES, METAL COMPLEXES OF PHOSPHAZENYL PHOSPHINES AND THEIR MANUFACTURING AND USAGE
  申请人：Philipps-Universität Marburg

  公开号：EP3733677A1

  公开（公告）日：2020-11-04

  The invention provides new compounds, phosphazenyl phosphines, metal complexes of phosphazenyl phosphines and manufacturing and usage of phosphazenyl phosphines as well as of their metal complexes. The new compounds are stronger P-superbases than the corresponding Schwesinger type phosphazene N-superbases and can be used as catalysts for chemical reactions.

  本发明提供了新化合物、膦氮基膦、膦氮基膦的金属络合物以及膦氮基膦及其金属络合物的制造和使用方法。与相应的施维辛格型膦氮 N-超级碱相比，新化合物是更强的 P-超级碱，可用作化学反应的催化剂。
• JP2000239288A
  申请人：——

  公开号：JP2000239288A

  公开（公告）日：2000-09-05