benzil bis(semicarbazone) | 5928-89-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: benzil bis(semicarbazone)
• 英文别名: [(Z)-[(2Z)-2-(carbamoylhydrazinylidene)-1,2-diphenylethylidene]amino]urea
• CAS: 5928-89-2
• 化学式: C₁₆H₁₆N₆O₂
• 分子量: 324.342
• InChiKey: NTFDIPFWUOYWSW-AXPXABNXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  135
• 氢给体数：
  4
• 氢受体数：
  4

安全信息

• 海关编码：
  2928000090

反应信息

• 作为反应物：
  描述：

  lead(II) nitrate 、 benzil bis(semicarbazone) 在 LiOH*H₂O 作用下， 以 甲醇 、 水 为溶剂， 以80%的产率得到[Pb(benzil bis(semicarbazone))2(NO3)]NO3
  参考文献：
  名称：

  Unreported coordination behaviour of a bis(semicarbazone) ligand in a lead(II) complex

  摘要：

  A novel lead(II) complex with the Schiff base benzil bis(semicarbazone), [Pb(LH(2))(2)(NO(3))]NO(3) center dot 1/2H(2)O, has been synthesised and structurally characterized as well as the free ligand. The coordination number of Pb(II) is seven provided by two neutral ligand molecules and one nitrato group. The most interesting characteristic of this complex is the different behaviour observed in the two bis(semicarbazone) molecules. One of them is a N(2)O(2) chelate ligand, whereas the other one is bonded to the lead ion only through one of the semicarbazone branches. The seventh position in the lead coordination sphere is provided by one oxygen atom from a nitrato ligand. (c) 2008 EIsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.10.058

文献信息

• Unreported coordination behaviour of a bis(semicarbazone) ligand in a lead(II) complex
  作者：Elena López-Torres、M. Antonia Mendiola、César J. Pastor

  DOI：10.1016/j.poly.2008.10.058

  日期：2009.2

  A novel lead(II) complex with the Schiff base benzil bis(semicarbazone), [Pb(LH(2))(2)(NO(3))]NO(3) center dot 1/2H(2)O, has been synthesised and structurally characterized as well as the free ligand. The coordination number of Pb(II) is seven provided by two neutral ligand molecules and one nitrato group. The most interesting characteristic of this complex is the different behaviour observed in the two bis(semicarbazone) molecules. One of them is a N(2)O(2) chelate ligand, whereas the other one is bonded to the lead ion only through one of the semicarbazone branches. The seventh position in the lead coordination sphere is provided by one oxygen atom from a nitrato ligand. (c) 2008 EIsevier Ltd. All rights reserved.