A conductive polymer material can exhibit good heat resistance and good moisture resistance, in which the conductive polymer comprises as a dopant at least one of aromatic sulfonic acid derivatives represented by general formula 1:
wherein at least one of R
1
to R
6
represents a sulfonic acid group having a counter cation selected from the group consisting of a hydrogen ion, an alkali metal ion, an alkaline-earth ion and a transition metal ion belonging to groups 8 to 10 in the periodic table; and the remaining R
1
to R
6
, which may be the same or different, represent hydrogen, alkyl having four or less carbon atoms or phenyl; or any two or more of R
1
to R
6
may be combined together to form an aromatic or aliphatic ring; and general formula 2:
wherein at least one of R
7
to R
10
represents a sulfonic acid group having a counter cation selected from the group consisting of a hydrogen ion, an alkali metal ion, an alkaline-earth ion and a transition metal ion belonging to groups 8 to 10 in the periodic table; and the remaining R
7
to R
12
, which may be the same or different, represent hydrogen, alkyl having four or less carbon atoms or phenyl; or any two or more of R
7
to R
10
may be combined together to form an aromatic or aliphatic ring.
一种导电
聚合物材料可表现出良好的耐热性和防潮性,其中导电
聚合物包括通式 1 所代表的至少一种芳香族
磺酸衍
生物作为掺杂剂:
其中 R
1
至 R
6
代表
磺酸基团,其反离子选自
氢离子、碱
金属离子、碱土离子和属于元素周期表中第 8 至 10 族的过渡
金属离子;其余 R
1
至 R
6
可以相同或不同,代表
氢、具有四个或更少
碳原子的烷基或
苯基;或任意两个或多个 R
1
至 R
6
可结合在一起形成芳香族或
脂肪族环;以及通式 2:
其中至少一个 R
7
至 R
10
代表
磺酸基团,其反离子选自
氢离子、碱
金属离子、碱土离子和属于元素周期表中第 8 至 10 族的过渡
金属离子组成的组;其余 R
7
至 R
12
可以相同或不同,代表
氢、具有四个或更少
碳原子的烷基或
苯基;或任意两个或多个 R
7
至 R
10
可结合在一起形成芳香环或脂环。