N,N'-双(1,2,4-三唑-1-基甲基)哌嗪 | 91272-91-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 中文名称: N,N'-双(1,2,4-三唑-1-基甲基)哌嗪
• 中文别名: 哌嗪,1,4-二(1H-1,2,4-三唑-1-基甲基)-
• 英文名称: N,N'-bis((1H-1,2,4-triazole-1-yl)methyl)piperazine
• 英文别名: N,N-bis(1-H-1,2,4-triazole-1-yl)piperazine；btp；Piperazine, 1,4-bis(1H-1,2,4-triazol-1-ylmethyl)-；1,4-bis(1,2,4-triazol-1-ylmethyl)piperazine
• CAS: 91272-91-2
• 化学式: C₁₀H₁₆N₈
• 分子量: 248.291
• InChiKey: WHFGLPOOBLVZRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  67.9
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N,N'-双(1,2,4-三唑-1-基甲基)哌嗪 、 mercury(II) iodide 以 甲醇 为溶剂， 以48%的产率得到
  参考文献：
  名称：

  A Linear Piperazine-Containing Ligand and Its Hg Coordination Polymer

  摘要：

  Reactions of piperazine hexahydrate with triazol and paraformaldehyde afford a new piperazine-containing ligand: (N,N'-bis(1-H-1,2,4-triazole-1-yl) piperazine) (btp). X-ray crystal diffraction reveals that btp is an overall linear structure. Its Hg2+ polymer displays a zigzag chain in which piperazine is held in the chair conformation. In addition, the spectra properties of the btp and 1 are investigated, the strong luminescence characteristics of btp and 1 are found.

  DOI：

  10.1080/15533174.2011.609220
• 作为产物：
  描述：

  哌嗪 、 1H-1,2,3-三氮唑 、 聚合甲醛 在 三乙胺 作用下， 以 甲醇 为溶剂， 以77.34%的产率得到N,N'-双(1,2,4-三唑-1-基甲基)哌嗪
  参考文献：
  名称：

  A Linear Piperazine-Containing Ligand and Its Hg Coordination Polymer

  摘要：

  Reactions of piperazine hexahydrate with triazol and paraformaldehyde afford a new piperazine-containing ligand: (N,N'-bis(1-H-1,2,4-triazole-1-yl) piperazine) (btp). X-ray crystal diffraction reveals that btp is an overall linear structure. Its Hg2+ polymer displays a zigzag chain in which piperazine is held in the chair conformation. In addition, the spectra properties of the btp and 1 are investigated, the strong luminescence characteristics of btp and 1 are found.

  DOI：

  10.1080/15533174.2011.609220

文献信息

• Photographic coupler and silver halide color photographic material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0571959A2

  公开（公告）日：1993-12-01

  A 1H-pyrazolo[1,5-b][1,2,4]triazole magenta coupler having a t-alkyl group at the position-6 and an amido group-substituted phenyl group at the position-2 is disclosed. There is also disclosed a silver halide color photographic material containing the same.

  本发明公开了一种 1H-吡唑并[1,5-b][1,2,4]三唑品红色耦合剂，其第 6 位是一个 t-烷基，第 2 位是一个氨基取代的苯基。此外，还公开了一种含有相同成分的卤化银彩色感光材料。
• A photographic processing composition and a processing process therewith
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0649057A2

  公开（公告）日：1995-04-19

  A processing composition for a silver halide photographic material, which comprises at least one of Fe (III), Mn (III), Co (III), Rh (II), Rh (III), Au (II), Au (III), and Ce (IV) chelate compounds of a compound represented by formula (I) or a salt thereof: wherein R1 represents a hydrogen atom, an aliphatic group or an aromatic group; R2 represents an aromatic group; L3 represents a divalent aliphatic group; n represents 0 or 1; X1 represents a hydrogen atom or -L4-A2; L1, L2 and L4 each represents a divalent aliphatic group, a divalent aromatic group, or a divalent linkage group comprising a combination thereof; A1 and A2 each represent a carboxy group, a phosphono group, a sulfo group, or a hydroxy group; and Z represents an oxygen atom or a sulfur atom.

  一种用于卤化银感光材料的冲洗组合物，它包含由式 (I) 所代表的化合物或其盐组成的 Fe (III)、Mn (III)、Co (III)、Rh (II)、Rh (III)、Au (II)、Au (III) 和 Ce (IV) 螯合物中的至少一种： 其中 R1 代表氢原子、脂肪族基团或芳香族基团；R2 代表芳香族基团；L3 代表二价脂肪族基团；n 代表 0 或 1；X1 代表氢原子或 -L4-A2；L1、L2 和 L4 分别代表二价脂肪族基团、二价芳香族基团或由其组合而成的二价连接基团；A1 和 A2 分别代表羧基、膦基、磺基或羟基；Z 代表氧原子或硫原子。
• Method for processing silver halide color photographic material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0657777A2

  公开（公告）日：1995-06-14

  To achieve superior desilvering property and reduced stains even with the use of a biodegradable bleaching agent in a dilute concentration, the processing is conducted with a processing solution comprising a ferric complex salt of the compound of formula (I) or (II) and, for example, a 2-carboxypyridyl and having bleaching ability. (In the formulae, R1 to R5 represent, for example, a hydrogen atom or a carboxyl group, L1 to L5 represent, for example, an alkylene group, G1 and G2 represent, for example, a carboxyl group or an aryl group and X represents, for example, a hydrogen atom).

  为了在使用稀释浓度的可生物降解漂白剂的情况下也能获得优异的去银性能并减少污渍，可使用由式(I)或(II)化合物的铁络合盐和例如具有漂白能力的 2-羧基吡啶组成的加工液进行加工。(在式中，R1 至 R5 代表氢原子或羧基，L1 至 L5 代表亚烷基，G1 和 G2 代表羧基或芳基，X 代表氢原子）。
• Color developing agent, processing composition and color image-forming method
  申请人：Fuji Photo Film Co., Ltd.

  公开号：EP0670312A1

  公开（公告）日：1995-09-06

  A method for forming a color image comprises the step of developing an image-wise exposed silver halide color photographic photosensitive material in the presence of a 6-aminotetrahzdroquinoline color developing agent (claimed) which is the following compound or its analogue. According to this method, the rapid process can be attained and an image of a low fog density can be obtained. Examples of the developing agent include

  一种形成彩色图像的方法包括以下步骤：在 6-氨基四氢喹啉显色剂（权利要求）（即以下化合物或其类似物）存在的情况下，对已曝光的卤化银彩色感光材料进行显影。根据这种方法，可以实现快速冲洗，并获得雾密度低的图像。 显影剂的例子包括
• Silver halide color photographic material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0664480A2

  公开（公告）日：1995-07-26

  A silver halide color photographic material is described, which comprises a support having thereon at least one photographic layer, wherein at least one of said photographic layers contains at least one radical scavenger, and the support comprises a poly(alkylene aromatic dicarboxylate) whose glass transition point is from 50 to 200°C and has been subjected to a heat treatment at a temperature of lower than the glass transition point thereof and not lower than 40°C either before formation of a subbing layer or after formation of a subbing layer and before formation of a silver halide emulsion layer.

  描述了一种卤化银彩色感光材料，它包括一个支撑体，支撑体上有至少一个感光层，其中至少一个感光层含有至少一种自由基清除剂，支撑体包括玻璃化转变点在 50 至 200°C 之间的聚(烷基芳香族二羧酸盐)，该聚(烷基芳香族二羧酸盐)已在低于其玻璃化转变点但不低于 40°C 的温度下进行过热处理，热处理的温度可以是在形成辅助层之前，也可以是在形成辅助层之后和形成卤化银乳剂层之前。