4,5,6,7-Tetramethyl-1,10-phenanthroline | 111558-75-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 4,5,6,7-Tetramethyl-1,10-phenanthroline
• CAS: 111558-75-9
• 化学式: C₁₆H₁₆N₂
• 分子量: 236.316
• InChiKey: QGVUZXSWJCPWKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  乙烯 、 4,5,6,7-Tetramethyl-1,10-phenanthroline 、 Ir(COT)2Cl 以 苯 为溶剂， 生成 Ir(3,4,7,8-Me4phen)(CH2=CH2)2Cl*0.5C6H6
  参考文献：
  名称：

  物[Ir（3,4,7,8-ME 4 phen）的（CH 2 CH 2）2 CL]：用于从醇氢转移到不饱和的有机基片A非常活泼的催化剂前体

  摘要：

  类型的Ir一些新的复合物1 CHEL（CH 2 CH 2）2 4,4'--ME;氯（CHEL =联吡啶2联吡啶; 4,4'--PH 2联吡啶;苯; 5,6--ME 2苯； 4,7-Ph 2 phen; 3,4,7,8-Me 4 phen）充当从醇到酮和席夫碱的氢转移的催化剂前体。络合物中活性最高的是3,4,7,8-Me 4 phen衍生物，在83°C下，使用环己酮的周转速度高达2850个循环/分钟，使用4-叔丁基环己酮的周转速度高达2700个循环/分钟。催化剂浓度为4 X 10 -5 M时，用亚苄基苯胺以5000个循环/分钟的速度和8×10 KOH（助催化剂）浓度-4中号。在室温下也观察到良好的催化活性。即使在没有KOH的情况下，在低底物浓度下也会发现某些催化活性。在4-叔丁基环己酮的还原中达到的最大立体选择性为97％，形成了反式醇。

  DOI：

  10.1016/s0022-328x(00)82290-1

文献信息

• Imaging system
  申请人：——

  公开号：US20040176248A1

  公开（公告）日：2004-09-09

  There are disclosed imaging members wherein a chemical compound in a crystalline form is converted, at least partially, and preferably substantially completely or completely, to a liquid in the amorphous form, the liquid having intrinsically a different color from the crystalline form. Also described are imaging methods utilizing the imaging members. The conversion of the compound from the crystalline form to the liquid form can be effected by the application of thermal energy or by other imaging techniques.

  本文披露了成像成员，其中化学化合物以晶体形式至少部分地转化为液体形式，最好是基本完全或完全转化，液体的颜色与晶体形式本质上不同。还描述了利用这些成像成员的成像方法。将化合物从晶体形式转化为液体形式可以通过施加热能或其他成像技术来实现。
• IMAGING SYSTEM
  申请人：CHU Peter K.

  公开号：US20100016154A1

  公开（公告）日：2010-01-21

  There are disclosed imaging members wherein a chemical compound in a crystalline form is converted, at least partially, and preferably substantially completely or completely, to a liquid in the amorphous form, the liquid having intrinsically a different color from the crystalline form. Also described are imaging methods utilizing the imaging members. The conversion of the compound from the crystalline form to the liquid form can be effected by the application of thermal energy or by other imaging techniques.

  本文介绍了成像元件，其中一种化合物以晶体形式部分或者更好的是完全或完全转化为非晶态液体，该液体的颜色与晶体形式有本质不同。同时还介绍了使用这些成像元件的成像方法。将化合物从晶体形式转化为液体形式可以通过施加热能或其他成像技术来实现。
• Imaging System
  申请人：Vetterling William T.

  公开号：US20100099556A1

  公开（公告）日：2010-04-22

  There are disclosed imaging members wherein a chemical compound in a crystalline form is converted, at least partially, and preferably substantially completely or completely, to an amorphous form that has intrinsically a different color from the crystalline form. Also described are imaging methods utilizing the imaging members. The conversion of the compound from the crystalline form to an amorphous form can be effected by laser exposure.

  公开了成像元件，其中化合物以晶体形式转换为非晶态形式，至少部分地，而且最好是完全或完全地，具有与晶体形式本质上不同的颜色。还描述了利用成像元件的成像方法。通过激光照射可以将化合物从晶体形式转变为非晶态形式。
• METHOD FOR PRODUCING CONJUGATED AROMATIC COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2233459A1

  公开（公告）日：2010-09-29

  A method for producing a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of a nickel compound, a ligand, a manganese salt and a metal reducing agent.

  一种生产共轭芳香族化合物的方法，包括在镍化合物、配体、锰盐和金属还原剂的存在下，使一个或两个离去基团键合在芳香环上的芳香族化合物（A）与结构与上述芳香族化合物（A）相同的芳香族化合物（A）或结构与上述芳香族化合物（A）不同且一个或两个离去基团键合在芳香环上的芳香族化合物（B）反应。
• Novel dye complexes and use thereof in imaging members and methods
  申请人：——

  公开号：US20040171817A1

  公开（公告）日：2004-09-02

  There are described novel complexes formed between hydrogen bond acceptors and phenolic dye compounds and imaging members and imaging methods, including thermal imaging members and methods utilizing the complexes.

  本文描述了氢键受体与酚类染料化合物之间形成的新型复合物以及成像构件和成像方法，包括利用这些复合物的热成像构件和方法。