Thiophosphoric acid O,O'-didecyl ester | 76097-26-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: Thiophosphoric acid O,O'-didecyl ester
• 英文别名: Didecoxy-hydroxy-sulfanylidene-lambda5-phosphane；didecoxy-hydroxy-sulfanylidene-λ5-phosphane
• CAS: 76097-26-2
• 化学式: C₂₀H₄₃O₃PS
• 分子量: 394.599
• InChiKey: MEVGGUFWHARNOB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  25
• 可旋转键数：
  20
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  70.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  癸醇 以14%的产率得到
  参考文献：
  名称：

  MAZITOVA F. N.; XAJRULLIN V. K., ZH. OBSHCH. XIMII, 1980, 50, HO 8, 1718-1722

  摘要：

  DOI：

文献信息

• Catalyst and process for the polymerization of alpha-olefins and a process for preparing an alpha-olefin polymerization catalyst component
  申请人：Standard Oil Company

  公开号：EP0013744A1

  公开（公告）日：1980-08-06

  High activity alpha-olefin polymerization catalysts comprising an organometallic promoter and a component prepared from at least one compound of a Group IVB, VB, or VIB metal, at least one support material which is a divalent metal salt of a phosphorus acid ester having at least one phosphorus acid ester group bonded to metal through oxygen or sulfur, and at least one alkylaluminium halide.

  高活性α-烯烃聚合催化剂，包括有机金属促进剂和由至少一种 IVB、VB 或 VIB 族金属化合物制备的组分，至少一种支撑材料，该支撑材料是磷酸酯的二价金属盐，其中至少有一个磷酸酯基团通过氧或硫与金属键合，以及至少一种烷基卤化铝。
• Lubricant compositions
  申请人：ETHYL PETROLEUM ADDITIVES, INC.

  公开号：EP0459656A1

  公开（公告）日：1991-12-04

  Gear oils and gear oil additive concentrates of enhanced positraction performance are described. They comprise: (i) at least one oil-soluble sulfur-containing extreme pressure or antiwear agent; (ii) at least one oil-soluble amine salt of a partial ester of an acid of phosphorus; and (iii) at least one oil-soluble succinimide of the formula where R₁ is an alkyl or alkenyl group having an average of 8 to 50 carbon atoms, and each of R₂, R₃ and R₄ is a hydrogen atom or an alkyl or alkenyl group having an average of up to about 4 carbon atoms. These compositions preferably contain one, more preferably two, and most preferably all three of the following additional components: (iv) at least one amine salt of a carboxylic acid; (v) at least one nitrogen-containing ashless dispersant; and (vi) at least one trihydrocarbyl ester of a pentavalent acid of phosphorus.

  所述齿轮油和齿轮油添加剂浓缩物具有增强的正曳引性能。它们包括：(i) 至少一种油溶性含硫极压剂或抗磨剂；(ii) 至少一种磷酸部分酯的油溶性胺盐；(iii) 至少一种油溶性琥珀酰亚胺，其式为 其中 R₁ 是平均具有 8 至 50 个碳原子的烷基或烯基，R₂、R₃ 和 R₄ 各为氢原子或平均具有最多约 4 个碳原子的烷基或烯基。这些组合物最好含有一种，更优选两种，最优选全部三种下列附加成分：(iv) 至少一种羧酸胺盐； (v) 至少一种含氮无灰分散剂；以及 (vi) 至少一种五价磷酸三烃基酯。
• Polyalkylene glycol lubricant compositions
  申请人：ETHYL PETROLEUM ADDITIVES LIMITED

  公开号：EP0460317A1

  公开（公告）日：1991-12-11

  A lubricant composition comprising a major proportion of polyalkylene glycol of lubricating viscosity and a minor proportion dissolved therein of (a) at least one sulphur-containing antiwear or extreme pressure agent, (b) at least one amine salt of at least one partially esterified monothiophosphoric acid, and (c) at least one amine salt of at least one partially esterified phosphoric acid. Such compositions have improved resistance to wear, oxidative degradation and metallic corrosion.

  一种润滑剂组合物，主要成分为具有润滑粘度的聚亚烷基二醇，次要成分为(a) 至少一种含硫抗磨剂或极压剂，(b) 至少一种部分酯化单硫代磷酸的胺盐，以及(c) 至少一种部分酯化磷酸的胺盐。这种组合物具有更好的抗磨损、抗氧化降解和抗金属腐蚀性能。
• Oil additive concentrates and lubricants of enhanced performance capabilities
  申请人：ETHYL PETROLEUM ADDITIVES LIMITED

  公开号：EP0531585A1

  公开（公告）日：1993-03-17

  Additive concentrates, lubricating oil compositions and the use thereof are described. The compositions comprise one or more of each of the following oil-soluble additive components: a) a Mannich base ashless dispersant; b) a metal-free sulphur-containing antiwear and/or extreme pressure agent; c) a metal-free phosphorus-containing and nitrogen-containing antiwear and/or extreme pressure agent; and optionally but preferably, d) an amine salt of a carboxylic acid. Oils containing such additive components exhibit excellent performance under heavy duty service such as in the planetary spur gear test. In addition, such oils exhibit good demulsibility in the ASTM D1401 test procedure and good clean gear performance in the CRC L-60 test.

  本文描述了添加剂浓缩物、润滑油组合物及其用途。这些组合物包含以下每种油溶性添加剂成分中的一种或多种：a) 曼尼希基无灰分散剂；b) 不含金属的含硫抗磨剂和/或极压剂；c) 不含金属的含磷和含氮抗磨剂和/或极压剂；以及可选但最好是 d) 羧酸胺盐。含有此类添加剂成分的机油在重负荷工作（如行星直齿轮试验）中表现出卓越的性能。此外，此类润滑油在 ASTM D1401 试验程序中表现出良好的抗乳化性，在 CRC L-60 试验中表现出良好的清洁齿轮性能。
• Use of sulfur-containing acid phosphoric ester as internal release agent
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0553801A1

  公开（公告）日：1993-08-04

  An internal release agent comprises a sulfur-containing acid phosphoric esters selected from the group consisting of thiophosphoric acid esters and dithiophosphoric acid esters of the formula, where X and Y are independently selected from the group consisting of an oxygen atom and a sulfur atom, at least one of X and Y is a sulfur atom, and R₁ and R₂ are independently alkyl groups.

  内脱模剂包括从硫代磷酸酯和二硫代磷酸酯组成的组中选出的含硫酸性磷酸酯，其式为 其中，X 和 Y 独立地选自由氧原子和硫原子组成的组，X 和 Y 中至少有一个是硫原子，R₁ 和 R₂ 独立地为烷基。