N-(5-nitro-2-furfuryl)-p-toluidine | 73315-72-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 呋喃
• 英文名称: N-(5-nitro-2-furfuryl)-p-toluidine
• 英文别名: N-(5-nitro-2-furfuryl)-4-tolylamine；4-methyl-N-[(5-nitrofuran-2-yl)methyl]aniline
• CAS: 73315-72-7
• 化学式: C₁₂H₁₂N₂O₃
• mdl: MFCD12052283
• 分子量: 232.239
• InChiKey: OXUVRHGWGHQQNP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.166
• 拓扑面积：
  71
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N-(5-nitro-2-furfuryl)-p-toluidine 反应 92.0h， 生成 7-Nitro-3-p-tolyl-10-oxa-3-aza-tricyclo[5.2.1.0^1,5]dec-8-ene
  参考文献：
  名称：

  Klepo, Z.; Jakopcic, K., Journal of Heterocyclic Chemistry, 1987, vol. 24, p. 1787 - 1792

  摘要：

  DOI：
• 作为产物：
  描述：

  4-methyl-N-(5-nitro-furan-2-ylmethylene)-aniline 在 sodium tetrahydroborate 作用下， 生成 N-(5-nitro-2-furfuryl)-p-toluidine
  参考文献：
  名称：

  New Substituted Alkenyl-Furfuryl-Aryl Amines: Synthesis and Their Characterization

  摘要：

  Reaction of several N-(5-substituted-2-furfuryl)-p-toluidines with the appropriate substituted allyl bromide gave new examples of tertiary amines (3a-e, 4a-e) with unique capability to react spontaneously in a sense of intramolecular [4+2]cycloaddition (IMDA) reaction.

  DOI：

  10.1080/00397919608003697

文献信息

• Method of preparing conductive magnetic composite sheet and antenna device
  申请人：SKC CO., LTD.

  公开号：US10479050B2

  公开（公告）日：2019-11-19

  According to a method of preparing a conductive magnetic composite sheet, the method comprising preparing a magnetic sheet comprising a magnetic powder and a binder resin; stacking the magnetic sheet and a first conductive foil; and applying heat and pressure to the obtained stack to bond the magnetic sheet and the first conductive foil, a conductive magnetic composite sheet having excellent interlayer adhesion between the magnetic sheet and the conductive foil can be prepared while having an excellent magnetic property at NFC, WPC, and MST frequencies.

  根据一种制备导电磁性复合片材的方法，该方法包括制备由磁性粉末和粘结剂树脂组成的磁性片材；将磁性片材和第一导电箔堆叠在一起；以及对所获得的堆叠层施加热量和压力以粘合磁性片材和第一导电箔，从而制备出在磁性片材和导电箔之间具有优异层间粘合力的导电磁性复合片材，同时在 NFC、WPC 和 MST 频率下具有优异的磁性能。
• Mocelo, Raul; Kovac, Jaroslav, Collection of Czechoslovak Chemical Communications, 1983, vol. 48, # 9, p. 2682 - 2692
  作者：Mocelo, Raul、Kovac, Jaroslav

  DOI：——

  日期：——
• Indium trifluoromethanesulfonate (In(OTf)3). A novel reusable catalyst for intramolecular Diels–Alder reactions
  作者：Dipak Prajapati、Dhrubojyoti D Laskar、Jagir S Sandhu

  DOI：10.1016/s0040-4039(00)01513-6

  日期：2000.10

  Indium trifluoromethanesulfonate (In(OTf)(3)) is found to be an effective catalyst for intramolecular Diels-Alder reactions of furans. This novel catalyst, soluble in both aqueous and organic media, is easily recovered from the aqueous layer after the reaction is completed. (C) 2000 Elsevier Science Ltd. All rights reserved.
• MOCELO, R.;KOVAC, J., COLLECT. CZECH. CHEM. COMMUN., 1983, 48, N 9, 2682-2692
  作者：MOCELO, R.、KOVAC, J.

  DOI：——

  日期：——
• KLEPO, Z.;JAKOPCIC, K., J. HETEROCYCL. CHEM., 24,(1987) N 6, 1787-1791
  作者：KLEPO, Z.、JAKOPCIC, K.

  DOI：——

  日期：——