N-[2,7-ditert-butyl-9,9-dimethyl-5-[(6-methylpyridin-2-yl)methylideneamino]xanthen-4-yl]-1-(6-methylpyridin-2-yl)methanimine | 850056-38-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: N-[2,7-ditert-butyl-9,9-dimethyl-5-[(6-methylpyridin-2-yl)methylideneamino]xanthen-4-yl]-1-(6-methylpyridin-2-yl)methanimine
• CAS: 850056-38-1
• 化学式: C₃₇H₄₂N₄O
• 分子量: 558.767
• InChiKey: RARALVQCSNKIAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.6
• 重原子数：
  42
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  59.7
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  乙烯 、 trans-[PtCl(Me)(SMe2)2] 、 N-[2,7-ditert-butyl-9,9-dimethyl-5-[(6-methylpyridin-2-yl)methylideneamino]xanthen-4-yl]-1-(6-methylpyridin-2-yl)methanimine 以 氯仿 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Binuclear platinum complexes of 4,5-disubstituted xanthenes

  摘要：

  New binucleating ligands based on 4,5-disubstituted xanthenes have been prepared. The ligands, which display either mono(acyl, nitrile) or bi-dentate (diimino, dithioamide) functionalities, can be prepared through simple procedures from commercial sources. The molecules have been used to synthesise dinuclear platinum(II) complexes with coordination numbers 4 or 5. Relevant aspects of their spectroscopic characterisation and reactivity are discussed along with the molecular structure of a representative compound. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.11.034

文献信息

• Binuclear platinum complexes of 4,5-disubstituted xanthenes
  作者：Achille Panunzi、Federico Giordano、Ida Orabona、Francesco Ruffo

  DOI：10.1016/j.ica.2004.11.034

  日期：2005.3

  New binucleating ligands based on 4,5-disubstituted xanthenes have been prepared. The ligands, which display either mono(acyl, nitrile) or bi-dentate (diimino, dithioamide) functionalities, can be prepared through simple procedures from commercial sources. The molecules have been used to synthesise dinuclear platinum(II) complexes with coordination numbers 4 or 5. Relevant aspects of their spectroscopic characterisation and reactivity are discussed along with the molecular structure of a representative compound. (c) 2004 Elsevier B.V. All rights reserved.