Di-iso-bu-peroxydicarbonat | 16215-50-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: Di-iso-bu-peroxydicarbonat
• 英文别名: Di-(sec-butyl)-peroxydicarbonat；bis-isobutoxycarbonyl peroxide；μ-Peroxo-dikohlensaeure-diisobutylester；Bis-isobutoxycarbonyl-peroxid；2-Methylpropoxycarbonyloxy 2-methylpropyl carbonate
• CAS: 16215-50-2
• 化学式: C₁₀H₁₈O₆
• 分子量: 234.249
• InChiKey: ZAYGISOXMIXWHX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  16
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Di-iso-bu-peroxydicarbonat 生成 i-Butoxyradikal
  参考文献：
  名称：

  Effects of oral and transdermal 17β-estradiol with cyclical oral norethindrone acetate on insulin sensitivity, secretion, and elimination in postmenopausal women

  摘要：

  Few studies have examined the effects of 17 beta-estradiol on parameters of insulin and glucose metabolism. We studied 42 healthy, untreated postmenopausal women seeking relief from menopausal symptoms. They were randomized to receive either oral 17 beta-estradiol 2 mg daily combined with sequential oral norethindrone acetate (NETA) 1 mg daily from days 12 to 22, or transdermal 17 beta-estradiol 0.05 mg daily combined with sequential oral NETA 1 mg daily from days 17 to 28. Intravenous glucose tolerance tests (IVGTTs) were performed at baseline and after 48 weeks (estrogen-alone phase) and 48 weeks (combined phase) of completed therapy. Mathematical modeling analysis of plasma glucose, insulin, and C-peptide concentration profiles provided measures of insulin resistance, secretion, and elimination. Both types of therapy were associated with a decrease in fasting insulin and glucose levels. Insulin sensitivity was increased by oral estradiol during the estrogen-alone phase but was reversed by the addition of NETA. Transdermal estradiol did not affect insulin sensitivity. Hepatic insulin uptake and insulin secretion were increased with both types of treatment. The oral regimen of estradiol therapy was favorable to both insulin elimination and sensitivity. Transdermal estradiol therapy had relatively few effects on insulin metabolism. Copyright (C) 2000 by W.B. Saunders Company.

  DOI：

  10.1053/meta.2000.6238
• 作为产物：
  描述：

  氯甲酸异丁酯 在 sodium peroxide 作用下， 生成 Di-iso-bu-peroxydicarbonat
  参考文献：
  名称：

  Sortieren von Kunststoffen durch thermisch beeinflusste Hafteigenschaften

  摘要：

  DOI：

  10.1002/1522-2640(200011)72:11<1382::aid-cite1382>3.0.co;2-y

文献信息

• ANTI-BLUE LIGHT COMPOUND, PREPARATION METHOD AND APPLICATION THEREOF
  申请人：EUTEC NEW MATERIALS TECHNOLOGY (SUZHOU) CO., LTD.

  公开号：US20210230128A1

  公开（公告）日：2021-07-29

  Disclosed is a blue light absorbing compound, its preparation method and use. The compound has high stability and is suitable for high temperature processing conditions as well as outdoor application. A method of covalently bonding a blue light absorbing compound with an ultraviolet light absorbing compound for increasing its stability is also provided. The compound is capable of absorbing or blocking ultraviolet light (UVA, UVB) and blue light to protect eyes. But long-wavelength blue light can be absorbed diminishingly, so that the transmitted light has a particularly good visual experience.

  揭示了一种蓝光吸收化合物，其制备方法和用途。该化合物具有高稳定性，适用于高温加工条件以及户外应用。还提供了一种通过共价键合蓝光吸收化合物和紫外线吸收化合物以增加其稳定性的方法。该化合物能够吸收或阻挡紫外线光（UVA，UVB）和蓝光以保护眼睛。但是长波长的蓝光可以被吸收得很少，使得透过的光具有特别好的视觉体验。
• [EN] STABILIZED ORGANIC PEROXIDE COMPOSITION AND PROCESS FOR MAKING THE SAME<br/>[FR] COMPOSITION A BASE DE PEROXYDE ORGANIQUE STABILISE, ET PROCEDE DE FABRICATION
  申请人：CROMPTON CORP

  公开号：WO2004096762A1

  公开（公告）日：2004-11-11

  An organic peroxide stabilizing composition comprises an organic peroxide and an organic peroxide stabilizing compound selected from one of the following general formulas (I) or (II): or mixture thereof wherein R' is hydrogen, alkyl of from 1 to about 10 carbon atoms, or aryl of from 6 to about 12 carbon atoms, optionally substituted with at least one halogen, lower alkyl, or hydroxy group; R2 is hydrogen, -OH, -C(O)R3 or -C(O)OR3 in which R3 is hydrogen or lower alkyl; R4 and R5 each independently has one of the meanings of R' and, additionally, R4 can be - C(O)OR3; wherein R3 has one of the same meanings as above and m is 0 or an integer of from 1 to about 20, n is 0 or 1 and o is 0 or an integer of from 1 to about 20 in an amount sufficient to retard the rate of decomposition of the organic peroxide.

  一种有机过氧化物稳定剂组合物，包括有机过氧化物和从以下通式（I）或（II）中选择的一种有机过氧化物稳定化合物，或其混合物：其中，R'为氢，1至约10个碳原子的烷基或6至约12个碳原子的芳基，可选地被至少一个卤素，低烷基或羟基取代；R2为氢，-OH，-C（O）R3或-C（O）OR3，其中R3为氢或低烷基；R4和R5各自独立具有R'的一种含义，并且此外，R4可以是-C（O）OR3；其中R3具有与上述相同的一种含义，m为0或1至约20的整数，n为0或1，o为0或1至约20的整数，其量足以减缓有机过氧化物的分解速率。
• Rubber modified methyl methacrylate syrups, production and use in producing cast sheets and moulding materials
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0019372A2

  公开（公告）日：1980-11-26

  A continuous process for producing rubber-modified methyl methacrylate syrups which comprises continuously supplying a material liquor comprising 1 to 20 parts by weight of a rubbery polymer dissolved in 100 parts by weight of a monomer comprising 60 to 100% by weight of methyl methacrylate, and a radical-polymerization initiator to a first reaction zone, continuously polymerizing at such a stationary conversion that the rubbery polymer is dispersed in the form of particles form while maintaining the temperature and residence time in the first reaction zone so that a steady state is achieved in the zone and the steady-state concentration of the initiator in the zone 1/2 to 1/1,000 times the concentration of initiator supplied, continuously taking out the resulting reaction mixture from the first reaction zone, and passing it through a second reaction zone having a volume of 0 to 5 times the volume of the first reaction zone, to.obtain a stable syrup comprising a disperse phase which is a solution of the rubbery polymer in the monomer and a continuous phase which is a solution of the resinous polymer in the monomer, and the use of these materials in the production of methyl methacrylate cast sheets and molding materials having an excellent impact resistance from the syrups.

  一种生产橡胶改性甲基丙烯酸甲酯糖浆的连续工艺，包括向第一反应区连续供应料液，该料液由 1 至 20 份（按重量计）橡胶聚合物溶解在 100 份（按重量计）单体（包括 60 至 100% 重量的甲基丙烯酸甲酯）和自由基聚合引发剂组成、在保持第一反应区的温度和停留时间，使该反应区达到稳定状态，且该反应区中引发剂的稳定浓度为所提供引发剂浓度的 1/2 至 1/1,000 倍的情况下，以橡胶聚合物以颗粒形式分散的固定转化率进行连续聚合，从第一反应区连续取出所产生的反应混合物，并将其通过容积为第一反应区容积 0 至 5 倍的第二反应区，以。获得一种稳定的糖浆，该糖浆包括橡胶聚合物在单体中的溶液的分散相和树脂聚合物在单体中的溶液的连续相，并利用这些材料生产具有优异抗冲击性的甲基丙烯酸甲酯浇注板和成型材料。
• Disproportionation of functional olefins
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0099572A1

  公开（公告）日：1984-02-01

  A process for producing internally unsaturated esters from alpha, omega dienes by disproportionation. Also disclosed are functional olefin compositions useful in controlling insects.

  一种通过歧化反应从α、Ω 二烯生产内部不饱和酯的工艺。还公开了可用于控制昆虫的功能性烯烃组合物。
• Compositions for producing polymers of high refractive index and low yellowness
  申请人：PPG INDUSTRIES, INC.

  公开号：EP0224123A2

  公开（公告）日：1987-06-03

  The yellowness of polymerizates formed from polymerizable compositions containing bisphenol bis(allylic carbonate)-functional material is reduced by inclusion of one or more cyclohexenic compounds in the polymerizable compositions.

  在含有双酚双（烯丙基碳酸酯）官能团材料的可聚合组合物中加入一种或多种环己烯化合物，可降低由可聚合组合物形成的聚合物的黄度。