5,6-dihydropyrazion[1,2,3,4-lmn][1,10]-phenanthroline-4,7-diium | 15302-80-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 5,6-dihydropyrazion[1,2,3,4-lmn][1,10]-phenanthroline-4,7-diium
• 英文别名: 1,4-Diazoniatetracyclo[6.6.2.04,16.011,15]hexadeca-1(14),4,6,8(16),9,11(15),12-heptaene
• CAS: 15302-80-4
• 化学式: C₁₄H₁₂N₂
• 分子量: 208.263
• InChiKey: PUSYDLRAPRZFQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  7.8
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5,6-dihydropyrazion[1,2,3,4-lmn][1,10]-phenanthroline-4,7-diium 在 三丁基膦 作用下， 以 甲醇 、 乙腈 为溶剂， 生成 5,6-Dihydro-pyrazino<1.2.3.4-l,m,n>1,10-phenanthrolinium-radikalkation
  参考文献：
  名称：

  紫精受体结构变化对三丁基膦单电子转移速率的影响。

  摘要：

  在氩气气氛下，在含有大量甲醇的乙腈中，用三丁基膦（1）处理2,2'-联吡啶和1,10-菲咯啉的“柔性” 3和“刚性”环状紫精4。 。从后者到前者很容易发生单电子转移（SET），SET到4的速度是SET到3的10（5）-10（6）倍。认为后者的重组能λ比前一个SET大，因为3在单电子还原成其自由基阳离子时发生结构变化，而4的单电子还原发生时没有结构变化。考虑到lambda的差异，

  DOI：

  10.1039/b605362a
• 作为产物：
  描述：

  1,10-菲罗啉 、 alkaline earth salt of/the/ methylsulfuric acid 以 乙腈 为溶剂， 生成 5,6-dihydropyrazion[1,2,3,4-lmn][1,10]-phenanthroline-4,7-diium
  参考文献：
  名称：

  紫精受体结构变化对三丁基膦单电子转移速率的影响。

  摘要：

  在氩气气氛下，在含有大量甲醇的乙腈中，用三丁基膦（1）处理2,2'-联吡啶和1,10-菲咯啉的“柔性” 3和“刚性”环状紫精4。 。从后者到前者很容易发生单电子转移（SET），SET到4的速度是SET到3的10（5）-10（6）倍。认为后者的重组能λ比前一个SET大，因为3在单电子还原成其自由基阳离子时发生结构变化，而4的单电子还原发生时没有结构变化。考虑到lambda的差异，

  DOI：

  10.1039/b605362a

文献信息

• High affinity of p-sulfonatothiacalix[4]arene with phenanthroline-diium in aqueous solution
  作者：Kui Wang、En-Cui Yang、Xiao-Jun Zhao、Yu Liu

  DOI：10.1039/c4ra15047c

  日期：——

  The molecular binding behavior of sulfonated calixarenes with phenanthroline-diium guests were systemically investigated. p-Sulfonatothiacalix[4]arene shows a high affinity with phenanthroline-diium guests in the order of magnitude of 105 M⁻¹.

  磺化杯芳烃与菲啰啉二阳离子客体的分子结合行为被系统地研究了。p-磺酸基硫代杯[4]芳烃与菲啰啉二阳离子客体的亲和力高达105 M⁻¹。
• Method for preparing 1,1′-ethylene-2,2′-bipyridinium dichloride
  申请人：NANJING REDSUN BIOCHEMISTRY CO., LTD.

  公开号：US10858337B2

  公开（公告）日：2020-12-08

  A method for preparing 1,1′-ethylene-2,2′-bipyridinium dichloride includes mixing an aqueous diquat dibromide solution with hydrochloric acid, adding dropwise to a mixture of an organic solvent, a bromine absorbent, and an oxidant, and reacting to produce 1,1′-ethylene-2,2′-bipyridinium dichloride.

  制备 1,1′-乙烯-2,2′-联吡啶鎓二氯化物的方法包括将二溴化二氢铵水溶液与盐酸混合，滴加到有机溶剂、溴吸收剂和氧化剂的混合物中，然后反应生成 1,1′-乙烯-2,2′-联吡啶鎓二氯化物。
• Molecular Binding Behaviors of Sulfonated Calixarenes with Phenanthroline-diium in Aqueous Solution and Solid State: Cavity Size Governing Capsule Formation
  作者：Kui Wang、En-Cui Yang、Xiao-Jun Zhao、Hong-Xi Dou、Yu Liu

  DOI：10.1021/cg500730m

  日期：2014.9.3

  The molecular binding behaviors of p-sulfonatocalix[4]arene (SC4A), p-sulfonatocalix[5]arene (SC5A), and p-sulfonatothiacalix[4]arene (STC4A) with 5,6-dihydropyrazion[1,2,3,4-lmn][1,10]phenanthroline-4,7-diium (DP2+) were systematically investigated by crystallography, NMR spectroscopy, and microcalorimetry at pH 1-2. The obtained results showed that, in both aqueous solution and the solid state, DP2+ was immersed into the cavity of the sulfonated calixarene host in a slantwise degree with the aromatic moiety being included first. The different slantwise degree of the guest in the host cavity determined whether the host guest capsule could be formed in the solid state. Furthermore, all three sulfonated calixarene hosts showed high affinities with DP2+ in the magnitude of 10(5)-10(6) M-1 in aqueous solution, and the binding modes for host guest complexation were explained from a thermodynamic viewpoint.
• ORGANIC COMPOUND, ELECTROCHROMIC DEVICE, ELECTROCHROMIC APPARATUS, OPTICAL FILTER, IMAGE PICKUP APPARATUS, LENS UNIT, AND WINDOW MEMBER
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20190002758A1

  公开（公告）日：2019-01-03

  An organic compound is represented by general formula (1) below: where X 1 and X 2 are each independently selected from the group consisting of an alkyl group, an aryl group, and an aralkyl group; R 11 to R 16 are each independently selected from the group consisting of a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, a heterocyclic group, and a halogen atom; R 21 and R 22 are each independently selected from the group consisting of a hydrogen atom, an alkyl group, an aryl group, and an aralkyl group; and A 1 − and A 2 − each independently represent a monovalent anion.
• METHOD FOR PREPARING 1,1'-ETHYLENE-2,2'-BIPYRIDINIUM DICHLORIDE
  申请人：NANJING REDSUN BIOCHEMISTRY CO., LTD.

  公开号：US20200308138A1

  公开（公告）日：2020-10-01

  A method for preparing 1,1′-ethylene-2,2′-bipyridinium dichloride includes mixing an aqueous diquat dibromide solution with hydrochloric acid, adding dropwise to a mixture of an organic solvent, a bromine absorbent, and an oxidant, and reacting to produce 1,1′-ethylene-2,2′-bipyridinium dichloride.