Perfluordecylphosphonsaeure | 52299-26-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: Perfluordecylphosphonsaeure
• 英文别名: Perfluorodecylphosphonic acid；1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-henicosafluorodecylphosphonic acid
• CAS: 52299-26-0
• 化学式: C₁₀H₂F₂₁O₃P
• 分子量: 600.064
• InChiKey: CTGNCBOZEMOASL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  35
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  57.5
• 氢给体数：
  2
• 氢受体数：
  24

反应信息

• 作为产物：
  描述：

  Perfluordecyl-dijodphosphan 、 Bis(perfluordecyl)-jodphosphan 在 H₂O 、 H₂O₂ 作用下， 以 水 为溶剂， 生成 Bis(perfluordecyl)phosphinsaeure 、 Perfluordecylphosphonsaeure
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.3, 1.6, page 40 - 51

  摘要：

  DOI：

文献信息

• LIQUID COMPOSITION FOR IMPARTING ALCOHOL-REPELLENCY TO SEMICONDUCTOR SUBSTRATE MATERIAL, AND METHOD FOR TREATING SURFACE OF SEMICONDUCTOR SUBSTRATE USING SAID LIQUID COMPOSITION
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP3404700A1

  公开（公告）日：2018-11-21

  The present invention provides a liquid composition for imparting alcohol-repellency to a semiconductor substrate material, and a method for treating the surface of a semiconductor substrate using the liquid composition, wherein the liquid composition contains: 0.01-15% by mass of a surfactant (A) having a substituent represented by formula (1) (where n is an integer of 3 to 20, inclusive), and an anionic hydrophilic group; and 0.0001-20% by mass of a compound (B) having a weight-average molecular weight of 200-500000 and having 4-30 mmol of an amino group per gram, the compound (B) being selected from the group consisting of compounds having a polyethylenimine and a substituent represented by formula (2) (where R1 and R2 are each independently hydrogen or a C1-6 alkyl, alkenyl, alkynyl, or aryl) or formula (3) (where R3 and R4 are each independently hydrogen or a C1-6 alkyl, alkenyl, alkynyl, or aryl, and X- is a fluoride ion, a chloride ion, a bromide ion, an iodide ion, a fluoroborate ion, a phosphate ion, an acetate ion, a trifluoroacetate ion, a sulfate ion, a hydrogen sulfate ion, a methane sulfate ion, a hydroxide ion, a perchlorate ion, or a nitrate ion).         CnF2n+1-     (1)

  本发明提供了一种用于赋予半导体衬底材料摈醇性的液体组合物，以及一种使用该液体组合物处理半导体衬底表面的方法，其中该液体组合物包含：0.01-15%（质量）的表面活性剂 (A)，该表面活性剂具有由式 (1) 所代表的取代基（其中 n 为 3 至 20（含）的整数）和阴离子亲水基团；以及 0.0001-20% 质量百分比的化合物 (B)，其重量-平均分子量为 200-500000，每克含 4-30 mmol 氨基，该化合物 (B) 选自具有聚乙烯亚胺和由式 (2) 代表的取代基（其中 R1 和 R2 各自独立地为氢或 C1-6 烷基、烯基、炔基、或芳基）或式 (3)（其中 R3 和 R4 各自独立地为氢或 C1-6 烷基、烯基、炔基或芳基，X- 为氟离子、氯离子、溴离子、碘离子、氟硼酸根离子、磷酸根离子、乙酸根离子、三氟乙酸根离子、硫酸根离子、硫酸氢根离子、硫酸甲烷根离子、氢氧根离子、高氯根离子或硝酸根离子）。 CnF2n+1- (1)
• SANITARY FACILITY MEMBER
  申请人：TOTO LTD.

  公开号：EP4019244A1

  公开（公告）日：2022-06-29

  Provided is a part that has a water-repelling function exhibited by a water-repellent layer, while the appearance of a colored layer (color tone) is maintained. The part includes a base material, a colored layer, an intermediate layer, and a surface layer. The colored layer contains more than 35 at% to 99 at% or less of C, 0 at% or more to less than 40 at% of Cr, 0 at% or more to less than 15 at% of N, and more than 0 at% to less than 15 at% of O, in a profile obtained by an XPS depth direction analysis. The intermediate layer contains at least one metal atom selected from Cr, Zr, and Si; and an oxygen atom. The metal element in an oxidized state is detected. The intermediate layer exhibits a sputtering time of 0.5 minutes or more to 9 minutes or less, the sputtering time being a time taken from when the metal element is detected to when the amount of detected oxygen elements contained in the intermediate layer exceeds the amount of detected oxygen elements (O) contained in the colored layer. The surface layer is water-repellent, and includes a hydrophobic group, and exhibits, in a profile obtained by the XPS depth direction analysis, a sputtering time of more than 0.5 minutes to 5 minutes or less, the sputtering time being a time taken from when the sputtering starts to when the metal atom contained in the intermediate layer starts to be detected.

  本发明提供了一种零件，它具有憎水层所表现出的憎水功能，同时又能保持着色层的外观（色调）。该零件包括基材、有色层、中间层和表层。在通过 XPS 深度方向分析获得的剖面图中，有色层含有 35%以上至 99%或以下的 C、0%以上至 40%以下的 Cr、0%以上至 15%以下的 N 和 0%以上至 15%以下的 O。中间层包含至少一个选自 Cr、Zr 和 Si 的金属原子和一个氧原子。可检测到处于氧化状态的金属元素。中间层的溅射时间为 0.5 分钟（含）以上至 9 分钟（含）以下，溅射时间是从检测到金属元素到中间层中检测到的氧元素量超过有色层中检测到的氧元素量（O）所需的时间。表层具有憎水性，并包括疏水基，在通过 XPS 深度方向分析获得的剖面中，溅射时间大于 0.5 分钟至 5 分钟或更短，溅射时间是从溅射开始到中间层所含金属原子开始被检测到所需的时间。
• Slips surface based on metal-containing compound
  申请人：Presidents and Fellows of Harvard College

  公开号：US10011800B2

  公开（公告）日：2018-07-03

  A method of preparing an article having a slippery surface includes providing a metal-containing surface, chemically modifying the metal-containing surface to roughen the metal-containing surface, and disposing a lubricating layer on the roughened metal-containing surface, wherein the lubricating layer is substantially stabilized on the roughened metal-containing surface.

  制备具有光滑表面的物品的方法包括：提供含金属表面；对含金属表面进行化学改性，使含金属表面粗糙化；在粗糙化的含金属表面上设置润滑层，其中润滑层在粗糙化的含金属表面上基本稳定。
• Surface treatment agent for substrate, comprising perfluoropolyether group-containing phosphate compound
  申请人：AGC Inc.

  公开号：US10239997B2

  公开（公告）日：2019-03-26

  To provide a surface treatment agent capable of imparting excellent water/oil repellency, fingerprint stain removability, abrasion resistance and lubricity to the surface of a substrate. A surface treatment agent for a substrate, comprising a perfluoropolyether group-containing phosphate compound, a coating agent comprising the surface treatment agent and a liquid medium, and a substrate having a surface layer formed from the surface treatment agent or the coating agent.

  提供一种表面处理剂，能够赋予基材表面优异的拒水/拒油性、指纹污渍去除性、耐磨性和润滑性。 一种用于基材的表面处理剂，包括一种含全氟聚醚基团的磷酸盐化合物、一种由表面处理剂和液体介质组成的涂层剂，以及一种具有由表面处理剂或涂层剂形成的表面层的基材。
• Liquid composition for imparting alcohol-repellency to semiconductor substrate material, and method for treating surface of semiconductor substrate using said liquid composition
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：US11094526B2

  公开（公告）日：2021-08-17

  A liquid composition for imparting alcohol-repellency to a semiconductor substrate material and a method for treating a semiconductor substrate surface using the liquid composition, are disclosed. The liquid composition contains: a surfactant (A) having a substituent of formula (1) (where n is an integer of 3 to 20), and an anionic hydrophilic group; and a compound (B) being selected from the group consisting of compounds having a polyethylenimine and a substituent of formula (2) or formula (3) (where R1, R2, R3 and R4 are each independently hydrogen or a C1-6 alkyl, alkenyl, alkynyl, or aryl, and X− is a fluoride ion, a chloride ion, a bromide ion, an iodide ion, a fluoroborate ion, a phosphate ion, an acetate ion, a trifluoroacetate ion, a sulfate ion, a hydrogen sulfate ion, a methane sulfate ion, a hydroxide ion, a perchlorate ion, or a nitrate ion).

  本发明公开了一种用于赋予半导体衬底材料摈醇性的液体组合物，以及使用该液体组合物处理半导体衬底表面的方法。液体组合物包含具有式 (1) 取代基（其中 n 为 3 至 20 的整数）的表面活性剂 (A) 和阴离子亲水基团；化合物 (B) 选自具有聚乙烯亚胺和式 (2) 或式 (3) 取代基（其中 R1、R2、R3 和 R4 各自独立地为氢或 C1-6 烷基、烯基、炔基或芳基）的化合物组、和 X- 是氟离子、氯离子、溴离子、碘离子、氟硼酸根离子、磷酸根离子、乙酸根离子、三氟乙酸根离子、硫酸根离子、硫酸氢根离子、硫酸甲烷根离子、氢氧根离子、高氯根离子或硝酸根离子）。