[6-(Dihydroxymethyl)naphthalen-2-yl]methanediol

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [6-(Dihydroxymethyl)naphthalen-2-yl]methanediol
• 化学式: C₁₂H₁₂O₄
• 分子量: 220.22
• InChiKey: AWAQRFWBWNFSBR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  80.9
• 氢给体数：
  4
• 氢受体数：
  4

文献信息

• NOVEL ORGANIC/INORGANIC HYBRID DMOF-1-N3 SOLID PROVIDED WITH AN AZIDE FUNCTION, AND METHOD FOR PREPARING SAME
  申请人：Savonnet Marie

  公开号：US20120283435A1

  公开（公告）日：2012-11-08

  The invention describes a crystallized hybrid solid with an organic-inorganic matrix, of three-dimensional structure, containing an inorganic network of zinc-based metal centers connected to one another by organic ligands constituted by the entities —O 2 C—C 6 H 3 —N 3 —CO 2 — and C 6 H 12 N 2 . Said solid is called DMOF-1-N 3 and has an X-ray diffraction diagram as provided below.
• CAU-1-N3 ORGANIC-INORGANIC HYBRID SOLID, EQUIPPED WITH AN AZIDE GROUP, AND PROCESS FOR ITS PREPARATION
  申请人：Savonnet Marie

  公开号：US20120296104A1

  公开（公告）日：2012-11-22

  The invention describes a crystallized hybrid solid with an organic-inorganic matrix, of a three-dimensional structure, containing an inorganic network of aluminum-based metal centers that are connected to one another by organic ligands that consist of the entity —O 2 C—C 6 H 3 —N 3 —CO 2 —. Said solid is called CAU-1-N 3 and has an X-ray diffraction diagram as given below.
• IHM-2 ORGANIC-INORGANIC HYBRID MATERIAL AND PROCESSES FOR PREPARATION
  申请人：Savonnet Marie

  公开号：US20120277454A1

  公开（公告）日：2012-11-01

  A new crystallized hybrid material with an organic-inorganic matrix, called IHM-2, containing an inorganic network of metal centers based on the element indium that are connected to one another by organic ligands that are formed by the entity 2-aminoterephthalate —O 2 C—C 6 H 3 —N 2 —CO 2 — is described. Said material has an X-ray diffraction diagram as given below.
• NOVEL ORGANIC/INORGANIC HYBRID SOLID IHM-2-N3 PROVIDED WITH AN AZIDE FUNCTION, AND METHOD FOR MANUFACTURING SAME
  申请人：Savonnet Marie

  公开号：US20120283456A1

  公开（公告）日：2012-11-08

  The invention describes a crystallized hybrid solid with an organic-inorganic matrix, of a three-dimensional structure, containing an inorganic network of indium-based metal centers that are connected to one another by organic ligands that consist of the entity —O 2 C—C 6 H 3 —N 3 —CO 2 —. Said solid is called IHM-2-N 3 and has an X-ray diffraction diagram as given below.
• METHOD FOR PREPARING ORGANIC/INORGANIC HYBRID FUNCTIONALIZED SOLIDS HAVING A TRIAZOLE RING
  申请人：Savonnet Marie

  公开号：US20120296095A1

  公开（公告）日：2012-11-22

  A process is described for the preparation of a functionalized hybrid solid with an organic-inorganic matrix, crystallized, bearing at least one reactive group based on a triazole ring, from a hybrid solid with an organic-inorganic matrix, MOF—NH 2 , comprising: i/ introduction, in a polar solvent S1, of said crystallized hybrid solid MOF—NH 2 , of at least one organic compound Q containing a nitride function N 3 and at least one intermediate reagent R containing a nitrite function NO 2 , ii/ reaction of said reaction mixture, iii/ introduction in the reaction mixture of at least one reagent A bearing an alkyne function or an activated cyanide function, at least one Cu-based catalyst C and at least one polar solvent S2, iv/ reaction of said reaction mixture, v/ filtration and then washing and vi/ drying of said crystallized functionalized hybrid solid.