trimethylphosphine-triethylborane (1/1) | 856316-88-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: trimethylphosphine-triethylborane (1/1)
• CAS: 856316-88-6
• 化学式: C₃H₉P*C₆H₁₅B
• 分子量: 174.074
• InChiKey: RAHBRRQSJQZABY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  三乙基硼 、 [((cyclopentadienyl)2ZrCH2CCCH2)Zr(cyclopentadienyl)2(trimethylphosphine)] 以 氘代四氢呋喃 、 正己烷 为溶剂， 生成 trimethylphosphine-triethylborane (1/1) 、 Cp2Zr[μ-(η4:η2-H2C4H2)]ZrCp2
  参考文献：
  名称：

  Reaction of 1-Zirconacyclopent-3-yne with “Zirconocene”:  Synthesis and Structure of Bimetallic 1,2,3-Butatriene Complexes¹

  摘要：

  A 1-zirconacyclopent-3-yne complex (1) reacted with "zirconocene" to give a symmetrical, bimetallic 1,2,3-butatriene complex (6) in which butatriene coordinates to two equivalent zirconocene units. Treatment of 6 with trimethylphosphine gave the phosphine-stabilized zirconocene-1 complex (2), which was transformed into 6 by addition of triethylborane.

  DOI：

  10.1021/om049288h