tris(3-(trimethylsilyl)ethynyl-2,4-pentanedionato)ruthenium(III) | 246236-83-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: tris(3-(trimethylsilyl)ethynyl-2,4-pentanedionato)ruthenium(III)
• CAS: 246236-83-9
• 化学式: C₃₀H₄₅O₆RuSi₃
• 分子量: 687.01
• InChiKey: AXSUIJUEICFUKQ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  tris(3-(trimethylsilyl)ethynyl-2,4-pentanedionato)ruthenium(III) 在 四丁基氟化铵 作用下， 以 四氢呋喃 、 苯 为溶剂， 以66%的产率得到tris(3-ethynyl-2,4-pentanedionato)ruthenium(III)
  参考文献：
  名称：

  Synthesis and characterization of a metal coordination polymer consisting of ruthenium(III) β-diketone units linked by butadiyne bridges

  摘要：

  A new metal coordination polymer consisting of ruthenium(III) beta-diketone units linked by butadiyne bridges was synthesized, and two mononuclear complexes, [Ru(mESima)(3)] and [Ru(mEma)(3)] (mESima(-) = 3-(trimethylsilyl)ethynyl-2,4-pentanedionate ion and mEma(-) = 3-ethynyl-2,4-pentanedionate ion), were also prepared as starting materials for the polymerization. The polymer was soluble in dichloromethane, chloroform, and benzene. The number-average molecular weight, 5400, corresponding to about 11 monomer units, was obtained from the FT-NMR integrated intensities for the protons on the ethynyl group of the mEma ligand end-group relative to the methyl protons of the entire chains. The NMR spectra also showed that the polymer structure was not a star-burst type but a chain-like type. The polymer exhibited one oxidation peak and one reduction peak on differential pulse voltammograms at 25 degrees C; however, the one anodic peak separated into two peaks at -36 degrees C. The difference in peak potentials between the first and the second oxidation waves was 0.23 V, which was very similar to the difference (0.22 V) in peak potentials for the corresponding binuclear complex. This indicated that metal-metal interactions in the polymer operate between only the closest neighboring units. Results of the controlled potential coulometry of the polymer in dichloromethane medium indicated that each monomer unit underwent a one-electron reduction. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00172-3
• 作为产物：
  描述：

  tris(3-iodo-2,4-pentanedionato)ruthenium(III) 、 三甲基乙炔基硅 在 catalyst: PdCl₂(PPh₃)2/CuI 作用下， 以 三乙胺 为溶剂， 以8%的产率得到tris(3-(trimethylsilyl)ethynyl-2,4-pentanedionato)ruthenium(III)
  参考文献：
  名称：

  Synthesis and characterization of a metal coordination polymer consisting of ruthenium(III) β-diketone units linked by butadiyne bridges

  摘要：

  A new metal coordination polymer consisting of ruthenium(III) beta-diketone units linked by butadiyne bridges was synthesized, and two mononuclear complexes, [Ru(mESima)(3)] and [Ru(mEma)(3)] (mESima(-) = 3-(trimethylsilyl)ethynyl-2,4-pentanedionate ion and mEma(-) = 3-ethynyl-2,4-pentanedionate ion), were also prepared as starting materials for the polymerization. The polymer was soluble in dichloromethane, chloroform, and benzene. The number-average molecular weight, 5400, corresponding to about 11 monomer units, was obtained from the FT-NMR integrated intensities for the protons on the ethynyl group of the mEma ligand end-group relative to the methyl protons of the entire chains. The NMR spectra also showed that the polymer structure was not a star-burst type but a chain-like type. The polymer exhibited one oxidation peak and one reduction peak on differential pulse voltammograms at 25 degrees C; however, the one anodic peak separated into two peaks at -36 degrees C. The difference in peak potentials between the first and the second oxidation waves was 0.23 V, which was very similar to the difference (0.22 V) in peak potentials for the corresponding binuclear complex. This indicated that metal-metal interactions in the polymer operate between only the closest neighboring units. Results of the controlled potential coulometry of the polymer in dichloromethane medium indicated that each monomer unit underwent a one-electron reduction. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00172-3