tetraaqua(oxalato)nickelate(II) | 782486-49-1

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物
• 英文名称: tetraaqua(oxalato)nickelate(II)
• CAS: 782486-49-1
• 化学式: C₂H₈NiO₈
• 分子量: 218.771
• InChiKey: DRAOHZYHTRQETB-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  tetraaqua(oxalato)nickelate(II) 在 三苯基膦 作用下， 生成 nickel(II) oxide
  参考文献：
  名称：

  Synthesis and characterization of NiO nanoclusters via thermal decomposition

  摘要：

  Thermal decomposition process has been developed to synthesize nickel oxide (NiO) nanoclusters Via the reaction between a new precursor, nickel oxalate [Ni(O4C2)(H2O)(4)] and oleylamine (C18H37N). The combination of triphenylphosphine (C18H15P) and C18H37N were added as surfactants to control the particle size. The products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectroscopy. thermogravimetric analysis (TGA) and Ultraviolet-visible (UV-Vis) spectroscopy. The synthesized NiO nanoclusters have a cubic structure with average size 2-10 nm. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.01.026
• 作为产物：
  描述：

  nickel(II) acetate tetrahydrate 、 potassium oxalate monohydrate 以 水 为溶剂， 生成 tetraaqua(oxalato)nickelate(II)
  参考文献：
  名称：

  Synthesis and characterization of NiO nanoclusters via thermal decomposition

  摘要：

  Thermal decomposition process has been developed to synthesize nickel oxide (NiO) nanoclusters Via the reaction between a new precursor, nickel oxalate [Ni(O4C2)(H2O)(4)] and oleylamine (C18H37N). The combination of triphenylphosphine (C18H15P) and C18H37N were added as surfactants to control the particle size. The products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectroscopy. thermogravimetric analysis (TGA) and Ultraviolet-visible (UV-Vis) spectroscopy. The synthesized NiO nanoclusters have a cubic structure with average size 2-10 nm. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.01.026