di-3-butenyl sulfoxide | 82167-41-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 亚砜
• 英文名称: di-3-butenyl sulfoxide
• 英文别名: 4-But-3-enylsulfinylbut-1-ene
• CAS: 82167-41-7
• 化学式: C₈H₁₄OS
• 分子量: 158.265
• InChiKey: HAPBYHATGNDXSM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  36.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  dibut-3-enyl sulfide 在 双氧水 、 C₄₀H₄₈N₆O₈V₂ 作用下， 以 水 、 乙腈 为溶剂， 生成 di-3-butenyl sulfoxide
  参考文献：
  名称：

  酰胺-亚胺缀合物的聚合铜（II）和二聚氧钒（V）配合物：胆红素识别和绿色催化

  摘要：

  一种极其简单的酰胺-亚胺缀合物，( E ) -N '-(4-(二乙氨基)-2-羟基亚苄基)-4-甲基苯甲酰肼 ( L )，由 4-甲基苯甲酰肼 ( PTA ) 与利用4-(二乙氨基)-2-羟基苯甲醛制备二聚氧代钒( V1 )和一维(1D)铜( II )配位聚合物( C1 )。通过单晶X射线衍射分析证实了L 、 V1和C1的结构。实验结果表明， V1是一种很有前景的硫化物氧化绿色催化剂，而C1则具有以更绿色的方式进行C-S交叉偶联反应的潜力。最重要的是， C1是一种有效的胆红素“开启”荧光传感器，通过配体置换方法发挥作用。位移平衡常数为7.78×10 5 M -1 。氯仿水溶液（氯仿/水，1/4，v/v，PBS 缓冲液，pH 8.0）中胆红素的检测限为 1.15 nM。

  DOI：

  10.1039/d3ra00702b

文献信息

• [EN] SURFACTANTS FOR AGRICULTURAL PRODUCTS<br/>[FR] TENSIOACTIFS POUR PRODUITS AGRICOLES
  申请人：ADVANSIX RESINS & CHEMICALS LLC

  公开号：WO2021183560A1

  公开（公告）日：2021-09-16

  Agricultural products, such as pesticides, plant growth regulators, fungicides, herbicides, and insecticides, may be formulated to include one or more surfactants, from one or more surfactant classes, such as derivatives of amino acids that have surface-active properties.

  农业产品，如杀虫剂、植物生长调节剂、杀菌剂、除草剂和杀虫剂，可以配制成包含一种或多种表面活性剂的配方，来自一种或多种表面活性剂类别，例如具有表面活性特性的氨基酸衍生物。
• Oil suspension concentrates based on a cyclohexenone oxime ether lithium salt and the use thereof as plant protection agents
  申请人：——

  公开号：US20040097374A1

  公开（公告）日：2004-05-20

  The present invention relates to oil suspension concentrates based on 2-{1-[2-(4-chlorophenoxy)propoxyimino]butyl}-3-hydroxy-5-(tetrahydrothiopyran-3-yl)cyclohex-2-enone lithium salt and certain formulation auxiliaries and to the use of the oil suspension concentrates as crop protection compositions and in particular as rice herbicides. Preferred formulation auxiliaries are mono- and/or dicarboxylic esters, for example fluid fatty acid esters, anionic surfactants of the sulfonate type, for example alkyl- and alkylarylsulfonates and also sulfosuccinates, and nonionic surfactants of the type of the nonethoxylated or ethoxylated carboxylic acids and esters of mono- or polyfunctional alcohols, for example ethoxylated fatty acids and polyoxyethylene sorbitan fatty acid esters. The oil suspension concentrates described herein are storage-stable and have excellent use properties.

  本发明涉及基于2-【1-【2-(4-氯苯氧)丙氧基亚氨基】丁基】-3-羟基-5-(四氢硫代吡喷-3-基)环己-2-酮锂盐和某些配方助剂的油悬浮浓缩物，以及将油悬浮浓缩物用作作物保护组合物，特别是稻田除草剂的用途。首选的配方助剂为单酸和/或二酸酯，例如流体脂肪酸酯，磺酸盐类型的阴离子表面活性剂，例如烷基和烷基芳基磺酸盐以及磺酸琥珀酸盐，以及非离子表面活性剂，例如非环氧化或环氧化羧酸和单醇或多醇酯，例如环氧化脂肪酸和聚氧乙烯山梨醇脂肪酸酯。本文描述的油悬浮浓缩物具有良好的储存稳定性和优异的使用性能。
• LONG-CHAINED MONO AND DI-ESTERS OF 2,5-DI(HYDROXYMETHYL)TETRAHYDROFURAN, USE AND PRODUCTION THEREOF
  申请人：BASF SE

  公开号：US20170305871A1

  公开（公告）日：2017-10-26

  The present invention relates to novel mono- and diesters of 2,5-di(hydroxymethyl)tetrahydrofuran, processes for their preparation by esterification in the presence of tertiary amines or in the presence of enzymatic esterification catalysts and the use of these mono- and diesters as interface-active compounds, rheology modifiers and emollients. The invention further relates to cosmetic and pharmaceutical compositions, and to detergents, cleaners and dishwashing compositions which comprise these mono- and diesters of 2,5-di(hydroxymethyl)-tetrahydrofuran.

  本发明涉及2,5-二(羟甲基)四氢呋喃的新型单酯和双酯，其制备方法包括在三级胺或酶催化剂存在下进行酯化反应，并将这些单酯和双酯作为界面活性化合物、流变改性剂和润肤剂。本发明还涉及包含这些2,5-二(羟甲基)四氢呋喃的单酯和双酯的化妆品和药物组合物，以及包含这些单酯和双酯的洗涤剂、清洁剂和洗碗剂。
• BRANCHED AMINO ACID SURFACTANTS FOR AGRICULTURAL PRODUCTS
  申请人：AdvanSix Resins & Chemicals LLC

  公开号：US20220007641A1

  公开（公告）日：2022-01-13

  Agricultural products, such as pesticides, plant growth regulators, fungicides, herbicides, and insecticides, may be formulated to include one or more branched surfactants, from one or more surfactant classes, such as derivatives of amino acids that have surface-active properties.

  农业产品，例如杀虫剂、植物生长调节剂、杀菌剂、除草剂和杀虫剂，可以配制成包括一种或多种分支表面活性剂的配方，来自一种或多种表面活性剂类别，例如具有表面活性性质的氨基酸衍生物。
• MIRTAZAPINE-CONTAINING TRANSDERMALLY-ABSORBABLE SKIN-ADHESIVE PREPARATION
  申请人：Yutoku Pharmaceutical Industries Co., Ltd.

  公开号：EP2857020A1

  公开（公告）日：2015-04-08

  The purpose is to provide a mirtazapine-containing transdermal patch capable of suppressing deposition of a crystalline component derived from mirtazapine, deterioration in sense of use, and deterioration in adhesiveness to the skin. The transdermal patch contains a support, a drug-containing layer and a release liner, and the drug-containing layer contains mirtazapine and an organic acid.

  其目的是提供一种含米氮平的透皮贴片，该贴片能够抑制由米氮平衍生的结晶成分的沉积、使用感的降低以及与皮肤粘附性的降低。透皮贴片包含支撑物、含药层和释放衬垫，含药层包含米氮平和有机酸。