tris(4-hydroxyphenyl) isocyanurate | 138006-23-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: tris(4-hydroxyphenyl) isocyanurate
• 英文别名: 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-tris(4-hydroxyphenyl)-；1,3,5-tris(4-hydroxyphenyl)-1,3,5-triazinane-2,4,6-trione
• CAS: 138006-23-2
• 化学式: C₂₁H₁₅N₃O₆
• 分子量: 405.367
• InChiKey: POVXNJNMCOXEEL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  30
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  122
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  tris<4-<(trimethylsilyl)oxy>phenyl>isocyanurate 在 盐酸 作用下， 以 丙酮 为溶剂， 反应 0.17h， 以81%的产率得到tris(4-hydroxyphenyl) isocyanurate
  参考文献：
  名称：

  Synthesis of novel aromatic isocyanurates by the fluoride-catalyzed selective trimerization of isocyanates

  摘要：

  DOI：

  10.1021/jo00059a055

文献信息

• Aromatic isocyanurate compound
  申请人：ASAHI DENKA KOGYO KABUSHIKI KAISHA

  公开号：EP0447073A2

  公开（公告）日：1991-09-18

  A novel tri-substituted triphenyl isocyanurate is defined by the following formula and useful as a crossliking agent for resin.    wherein X represents -O- or -COO-; and R represents a hydrogen atom, a straight-chain or branched alkyl group having 1 to 10 carbon atoms which may be either unsubstituted or substituted with a hydroxyl group, an aryl group or an R'₃Si group (wherein a plurality of R' groups may be the same or different from each other and each represent a straight-chain or branched alkyl group having 1 to 10 carbon atoms or a phenyl group), excepting the case wherein X is -O- and R is CH₃.

  一种新型三取代三苯基异氰尿酸酯由下式定义，可用作树脂的交联剂。 其中 X 代表-O-或-COO-；和 R 代表氢原子、具有 1 至 10 个碳原子的直链或支链烷基，该直链或支链烷基可 以是未取代的，也可以是被羟基、芳基或 R'₃Si 基团取代的（其中多个 R' 基团可以相同，也可以不同，并且各自代表具有 1 至 10 个碳原子的直链或支链烷基或苯基），但 X 为 -O- 和 R 为 CH₃ 的情况除外。
• Flame retardant polyolefin resin composition
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1270613A2

  公开（公告）日：2003-01-02

  To provide a flame retardant polyolefin resin composition having an excellent flame retardancy and enabling the preparation of a molded product free from soapiness, a flame retardant polyolefin resin composition comprises (A) 100 parts by mass of a polyolefin resin, (B) 10 to 60 parts by mass of melamine polyphosphate and (C) 10 to 60 parts by mass of a carbonizing agent, wherein the compounding ratio [(B)/(C)] of the component (B) to the component (C) (mass ratio) is in a range from 0.5 to 4.5, optionally further including (D) 1 to 30 parts by mass of a carbonizing promoter.

  为了提供一种阻燃性聚烯烃树脂组合物，该组合物具有优异的阻燃性，并且能够制备无皂性的模塑产品，阻燃性聚烯烃树脂组合物包括 (A) 100 份（质量份）聚烯烃树脂、(B) 10 至 60 份（质量份）三聚氰胺聚磷酸盐和 (C) 10 至 60 份（质量份）增碳剂，其中组分 (B) 与组分 (C) 的复配比[(B)/(C)]（质量比）在 0.5 至 4.5 之间，可选地进一步包括 (D) 1 至 30 份（质量份）增碳剂。5 至 4.5，可选地进一步包括 (D) 1 至 30 份（质量份数）的碳化促进剂。
• SELF-EXTINGUISHING RESIN MOLDED BODY
  申请人：Daicel Miraizu Ltd.

  公开号：EP3862378A1

  公开（公告）日：2021-08-11

  A self-extinguishing resin molded body obtained from a resin composition containing a polyolefin resin (A), a phosphorus-based flame retardant (B), and a glass fiber (C), wherein the self-extinguishing resin molded body contains from 15 to 30 mass% of the phosphorus-based flame retardant (B) and from 5 to 50 mass% of the glass fiber (C); and the self-extinguishing resin molded body satisfies the following (I) to (III). (I) A thickness of the self-extinguishing resin molded body is from 1.5 to 8.0 mm. (II) The self-extinguishing resin molded body self-extinguishes within 2 minutes after the completion of a burning test using burning test method E as described below. (III) The self-extinguishing resin molded body does not have a hole after being subjected to a burning test using burning test method E as described below. Burning test method E: A plaque (150 × 150 × 2.0 mm) made of the molded body described above is used. A 200 mm-long flame is applied from above the plaque directly onto the center of the plaque for 130 seconds. The distance from the flame contact position on the plaque to the burner mouth is 150 mm.

  一种自熄灭树脂模塑体，由含有聚烯烃树脂（A）、磷系阻燃剂（B）和玻璃纤维（C）的树脂组合物制成，其中自熄灭树脂模塑体含有 15 至 30 质量％的磷系阻燃剂（B）和 5 至 50 质量％的玻璃纤维（C）；并且自熄灭树脂模塑体满足以下（I）至（III）。(I) 自熄树脂模塑体的厚度为 1.5 至 8.0 毫米。(II) 自熄树脂模塑体在完成下述燃烧测试方法 E 的燃烧测试后 2 分钟内自熄。(III) 自熄树脂模塑体在经过下述燃烧试验方法 E 的燃烧试验后没有破洞。燃烧试验方法 E：使用由上述模塑体制成的牌匾（150 × 150 × 2.0 毫米）。从牌匾上方向牌匾中心直接喷射 200 毫米长的火焰，持续 130 秒。从牌匾上火焰接触位置到燃烧器口的距离为 150 毫米。
• RESIN MOLDED BODY
  申请人：Daicel Miraizu Ltd.

  公开号：EP3862379A1

  公开（公告）日：2021-08-11

  A resin molded body obtained from a resin composition containing a thermoplastic resin (A), a flame retardant (B), and a metal fiber (C). The resin molded body contains from 15 to 30 mass% of the flame retardant (B) and from 2.5 to 7.5 mass% of the metal fiber (C), with the remainder being component (A) to make a total of 100 mass%. The resin molded body has a determination result of V-0 or V-1 in a burning test using the UL 94 V test method on a test piece having a thickness of 1.5 mm. The resin molded body satisfies the requirements described in the following (I) to (IV). (I) A thickness of the resin molded body is from 1.5 to 8.0 mm. (II) The resin molded body self-extinguishes within five minutes after the completion of a burning test using burning test method E as described below. (III) The resin molded body does not have a hole after being subjected to a burning test using burning test method E as described below. (IV) The resin molded body has an electromagnetic wave shielding property of more than 30 dB using a KEC method electric field in a frequency range from 1 to 100 MHz. Burning test method E: A plaque (150 × 150 × 2.0 mm) made of the molded body described above is used. A 200 mm-long flame is applied from above the plaque directly onto the center of the plaque for 130 seconds. The distance from the flame contact position on the plaque to the burner mouth is 150 mm.

  一种树脂模塑体，由含有热塑性树脂（A）、阻燃剂（B）和金属纤维（C）的树脂组合物制成。树脂模塑体中阻燃剂（B）的含量为 15 至 30%，金属纤维（C）的含量为 2.5 至 7.5%，其余为成分（A），总含量为 100%。在使用 UL 94 V 测试方法对厚度为 1.5 毫米的测试片进行的燃烧测试中，树脂模塑体的测定结果为 V-0 或 V-1。树脂模塑体满足以下（I）至（IV）项的要求。(I) 树脂模塑体的厚度为 1.5 至 8.0 毫米。(II) 树脂模塑体在用下述燃烧试验方法 E 完成燃烧试验后五分钟内自熄。(III) 树脂模塑体在按下述燃烧试验方法 E 进行燃烧试验后，没有破洞。(IV) 在 1 至 100 兆赫的频率范围内，使用 KEC 法电场，树脂模塑体具有 30 分贝以上的电磁波屏蔽性能。燃烧试验方法 E：使用由上述模塑体制成的牌匾（150 × 150 × 2.0 毫米）。从牌匾上方向牌匾中心直接喷射 200 毫米长的火焰，持续 130 秒。从牌匾上的火焰接触位置到燃烧器口的距离为 150 毫米。
• JPH04139211A
  申请人：——

  公开号：JPH04139211A

  公开（公告）日：1992-05-13