2,2'-((((1-phenylethane-1,1-diyl)bis(4,1-phenylene))bis(oxy))bis(methylene))bis(oxirane) | 13368-56-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 2,2'-((((1-phenylethane-1,1-diyl)bis(4,1-phenylene))bis(oxy))bis(methylene))bis(oxirane)
• 英文别名: diglycidyl ether of 1,1-bis(4-hydroxylphenyl)-1-phenylethane；2-[[4-[1-[4-(Oxiran-2-ylmethoxy)phenyl]-1-phenylethyl]phenoxy]methyl]oxirane
• CAS: 13368-56-4
• 化学式: C₂₆H₂₆O₄
• 分子量: 402.49
• InChiKey: BSSTUBRSXXGFIO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  30
• 可旋转键数：
  9
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  43.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  双酚AP 、 环氧氯丙烷 在 四丁基溴化铵 、 sodium hydroxide 作用下， 以 丁酮 、 水 为溶剂， 反应 5.17h， 生成 2,2'-((((1-phenylethane-1,1-diyl)bis(4,1-phenylene))bis(oxy))bis(methylene))bis(oxirane)
  参考文献：
  名称：

  [EN] HIGH HEAT MONOMERS AND METHODS OF USE THEREOF
  [FR] MONOMÈRES À CHALEUR ÉLEVÉE ET LEURS PROCÉDÉS D'UTILISATION

  摘要：

  本发明提供了高纯度环氧化合物、制备高纯度环氧化合物的方法以及从环氧化合物衍生的组合物。还提供了从环氧化合物衍生的材料和物品。

  公开号：

  WO2016014536A1

文献信息

• Polycyclic dihydroxy compound and methods for preparation
  申请人：Raj Tilak T.

  公开号：US20070123713A1

  公开（公告）日：2007-05-31

  A process of forming a polycyclic dihydroxy compound is described. The polycyclic dihydroxy compound has Formula (I) wherein R 1 , R 2 and R 3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; and wherein each occurrence of “n”, “m”, and “p” independently has a value of 0, 1, 2, 3, or 4. Also described are polycyclic dihydroxy compounds of Formula (I) in which the phthalimide group is meta to the triaryl-substituted carbon.

  描述了一种形成多环二羟基化合物的过程。该多环二羟基化合物的化学式为（I），其中R1、R2和R3在每次出现时独立地选择自氰基、卤素、具有1至10个碳原子的脂肪基、具有3至10个碳原子的环脂肪基和具有6至10个碳原子的芳香基的群组中的一种功能基；且“n”、“m”和“p”的每次出现独立地具有0、1、2、3或4的值。还描述了化学式（I）中邻苯二甲酰亚胺基团位于三芳基取代碳的情况下的多环二羟基化合物。
• Polyhydroxy polyether, process for its production and its use
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0199564A2

  公开（公告）日：1986-10-29

  A substantially linear polyhydroxy polyether, which (1) is composed substantially of aromatic units and aliphatic units, the proportion of the aromatic units being 50 to 98 mole % based on the total amount of the aromatic units and the aliphatic units, (2) has an intrinsic viscosity, measured at 25°C in o-chlorophenol, of from 0.3 to 2 dl/g, and (3) has a glass transition temperature of from 30 to 120°C. Two processes for preparing the polyhydroxy polyether are proposed. The polyhydroxy polyether is useful in applications which require gas-barrier property.

  一种基本线性的聚羟基聚醚，其(1)主要由芳香族单元和脂肪族单元组成，芳香族单元的比例为 50 至 98 摩尔%（基于芳香族单元和脂肪族单元的总量），(2)在 25°C 邻氯苯酚中测量的固有粘度为 0.3 至 2 分升/克，(3)玻璃化转变温度为 30 至 120°C。提出了制备聚羟基聚醚的两种工艺。这种聚羟基聚醚在需要气体阻隔性能的应用中非常有用。
• POLYMER MATERIAL AND METHOD FOR MANUFACTURING SAME
  申请人：Osaka University

  公开号：EP3760646A1

  公开（公告）日：2021-01-06

  Provided are a macromolecular material that can form various structures, and that exhibits excellent toughness and strength; and a method for producing the macromolecular material. The macromolecular material includes in a polymer chain thereof a structural unit represented by the following formula (1):         -R1-RH     (1) (R1 represents NH or O, and RH represents a host group), wherein the host group is a monovalent group formed by removing one hydrogen atom or hydroxy group from a cyclodextrin derivative, and the cyclodextrin derivative has a structure formed such that a hydrogen atom of at least one hydroxy group contained in a cyclodextrin is replaced with at least one group selected from the group consisting of a hydrocarbon group, an acyl group, and -CONHR (R represents a methyl group or an ethyl group).

  本发明提供了一种可形成各种结构、具有优异韧性和强度的高分子材料，以及生产该高分子材料的方法。该高分子材料在其聚合物链中包括由下式（1）表示的结构单元： -R1-RH (1) (R1代表NH或O，RH代表主基)，其中主基是从环糊精衍生物中除去一个氢原子或羟基而形成的单价基团，环糊精衍生物具有这样一种结构，即环糊精中所含至少一个羟基的氢原子被至少一个选自烃基，酰基和-CONHR(R代表甲基或乙基)的基团所取代。
• High heat monomers and methods of use thereof
  申请人：SABIC GLOBAL TECHNOLOGIES B.V.

  公开号：US10465037B2

  公开（公告）日：2019-11-05

  High purity epoxide compounds, methods for preparing the high purity epoxide compounds, and compositions derived from the epoxide compounds are provided. Also provided are materials and articles derived from the epoxide compounds.

  提供了高纯度环氧化物化合物、制备高纯度环氧化物化合物的方法以及由环氧化物化合物衍生的组合物。此外，还提供了由环氧化合物衍生的材料和物品。
• Polymers, polymer compositions, and method of preparation
  申请人：Raj Tilak T.

  公开号：US20070123682A1

  公开（公告）日：2007-05-31

  A polymer comprising structural units derived from a polycyclic dihydroxy compound of Formula (I) wherein R 1 , R 2 and R 3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; wherein each occurrence of “n”, “m”, and “p” independently has a value of 0, 1, 2, 3, or 4; and wherein the polymer is substantially linear.