thallium monodeuteride | 13763-70-7

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: thallium monodeuteride
• 英文别名: tallium hydride；Deuteriothallium
• CAS: 13763-70-7
• 化学式: HTl
• 分子量: 206.383
• InChiKey: YWUHBIFVNJARPY-IEOVAKBOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.65
• 重原子数：
  1
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  thallium 、 氘 以 neat (no solvent) 为溶剂， 生成 thallium monodeuteride
  参考文献：
  名称：

  The ground state infrared spectra of four diatomic deuterides (GaD, InD, TlD, AgD) and the determination of mass‐independent molecular parameters

  摘要：

  The infrared spectra of two isotopic forms of the monodeuterides of the metals gallium, indium, thallium, and silver have been measured in their ground electronic state (1Σ) in the gas phase using a diode laser spectrometer. The analysis of the experimental data was carried out in two ways: (a) a complete set of Dunham parameters was determined for each isotopic species independently and (b) all the available data over both deuterated and protonated species of a particular compound were simultaneously fitted to obtain a set of mass-independent parameters. Mass scaling coefficients, which take into account effects arising from a breakdown of the Born–Oppenheimer approximation, were determined for the hydrogen atom.

  DOI：

  10.1063/1.459877

文献信息

• Infrared Spectra of Indium Hydrides in Solid Hydrogen and of Solid Indane
  作者：Lester Andrews、Xuefeng Wang

  DOI：10.1002/anie.200353216

  日期：2004.3.19

  One little indium: Reactions of laser‐ablated indium atoms with pure hydrogen give sharp IR absorptions corresponding to InH intermediate species. Irradiation at 193 nm maximizes further reaction to give the indane monomer InH3. Annealing provides evidence for In2H6 and ultimately the sharp absorption bands are replaced with a broad IR band centered at 1460 cm−1 assigned to solid indane (InH3)n [see Equation].$\vcenter\openup.5em\halign$#$\cr \rm InH}_3}\rightarrow 1\over 2}\rm In}_2}\rm H}_6}\rightarrow 1\over n}(\rm InH}_3})_n}\hfill\cr}}}$