(4-Ethenylphenyl) 3,4,5-tridodecoxybenzoate | 1221120-80-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: (4-Ethenylphenyl) 3,4,5-tridodecoxybenzoate
• CAS: 1221120-80-4
• 化学式: C₅₁H₈₄O₅
• 分子量: 777.225
• InChiKey: FOIQNBNWKDIUOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.8
• 重原子数：
  56
• 可旋转键数：
  40
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  54
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  (4-Ethenylphenyl) 3,4,5-tridodecoxybenzoate 、 三(4-碘苯)胺 以23%的产率得到
  参考文献：
  名称：

  A new disc-shaped mesogenic compound with olefinic linkage derived from triphenylamine: synthesis, mesogenic behavior and fluorescence properties

  摘要：

  A new disc-like triphenylamine containing mesogenic compound has been synthesized by the implementation of the Heck and ring-closing metathesis-based reactions in good yield. The designed and synthesized compound showed rectangular columnar mesophase and this is the first report of liquid crystalline phase of the triphenylamine-based compound with an olefinic linkage. The disc-shaped compound exhibited excellent fluorescence properties. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.09.140
• 作为产物：
  描述：

  甲基三苯基碘化膦 、 4-formylphenyl 3,4,5-tris(dodecyloxy)benzoate 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 反应 1.25h， 生成 (4-Ethenylphenyl) 3,4,5-tridodecoxybenzoate
  参考文献：
  名称：

  A new disc-shaped mesogenic compound with olefinic linkage derived from triphenylamine: synthesis, mesogenic behavior and fluorescence properties

  摘要：

  A new disc-like triphenylamine containing mesogenic compound has been synthesized by the implementation of the Heck and ring-closing metathesis-based reactions in good yield. The designed and synthesized compound showed rectangular columnar mesophase and this is the first report of liquid crystalline phase of the triphenylamine-based compound with an olefinic linkage. The disc-shaped compound exhibited excellent fluorescence properties. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.09.140