Iron;yttrium

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: Iron;yttrium
• 英文别名: iron;yttrium
• 化学式: FeY
• 分子量: 144.75
• InChiKey: MTRJKZUDDJZTLA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  Iron;yttrium 、 乙酰丙酮 在 Et₄NBr 作用下， 以 乙腈 为溶剂， 生成 iron(III) oxide 、 Iron;yttrium 、 diaquabisacetylacetonatodiaquairon(II) 、 iron(II) yttrium acetylacetonate
  参考文献：
  名称：

  Synthesis, structure, and magnetic properties of iron ? yttrium complexes containing acetylacetonate ligands

  摘要：

  Two new compounds have been obtained by the synthesis of heteronuclear iron-yttrium acetylacetonate, using the modified electrochemical dissolution of the [YFe2] alloy. One of these compounds, with the Fe(acac)(2) . 2H(2)O composition, has been studied by X-ray diffraction analysis. X-ray diffraction data: a = 11.002(5), b = 5.412(2), c = 11.179(5) Angstrom; beta = 106.39(4)degrees; V = 638.6 Angstrom(3), space group P2(1)/c, Z = 2. According to the data on magnetic susceptibility, Mossbauer spectroscopy, and X-ray electron microanalysis, single crystals of this complex are covered with an amorphous film containing finely dispersed [Y1-aFea](n) clusters and, probably, superparamagnetic gamma-Fe2O3 Species. The second oligomeric acetylacetonate complex contains ions of high-spin two-valence iron, yttrium, and finely dispersed ferromagnetic [Y1-aFea](n) intermetallide clusters.

  DOI：

  10.1007/bf00714416

文献信息

• Synthesis, structure, and magnetic properties of iron ? yttrium complexes containing acetylacetonate ligands
  作者：M. V. Tsodikov、O. V. Bukhtenko、O. G. Ellert、I. A. Petrunenko、A. S. Antsyshkina、G. G. Sadikov、Yu. V. Maksimov、Yu. V. Titov、V. M. Novotortsev

  DOI：10.1007/bf00714416

  日期：1995.8

  Two new compounds have been obtained by the synthesis of heteronuclear iron-yttrium acetylacetonate, using the modified electrochemical dissolution of the [YFe2] alloy. One of these compounds, with the Fe(acac)(2) . 2H(2)O composition, has been studied by X-ray diffraction analysis. X-ray diffraction data: a = 11.002(5), b = 5.412(2), c = 11.179(5) Angstrom; beta = 106.39(4)degrees; V = 638.6 Angstrom(3), space group P2(1)/c, Z = 2. According to the data on magnetic susceptibility, Mossbauer spectroscopy, and X-ray electron microanalysis, single crystals of this complex are covered with an amorphous film containing finely dispersed [Y1-aFea](n) clusters and, probably, superparamagnetic gamma-Fe2O3 Species. The second oligomeric acetylacetonate complex contains ions of high-spin two-valence iron, yttrium, and finely dispersed ferromagnetic [Y1-aFea](n) intermetallide clusters.