perfluorohexyl-(5-bromothien-2-yl)methanol | 796994-63-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻吩类
• 英文名称: perfluorohexyl-(5-bromothien-2-yl)methanol
• 英文别名: 1-(5-Bromothiophen-2-yl)-2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptan-1-ol；1-(5-bromothiophen-2-yl)-2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptan-1-ol
• CAS: 796994-63-3
• 化学式: C₁₁H₄BrF₁₃OS
• 分子量: 511.101
• InChiKey: DQQMSBHUWIOPCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  27
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  48.5
• 氢给体数：
  1
• 氢受体数：
  15

反应信息

• 作为反应物：
  描述：

  perfluorohexyl-(5-bromothien-2-yl)methanol 在 manganese(IV) oxide 作用下， 以 二氯甲烷 为溶剂， 以98%的产率得到2-全氟己基羰基-5-溴噻吩
  参考文献：
  名称：

  Organic Thin-Film Transistors Based on Carbonyl-Functionalized Quaterthiophenes:  High Mobility N-Channel Semiconductors and Ambipolar Transport

  摘要：

  New carbonyl-functionalized quaterthiophenes, 5, 5' ''-diheptanoyl-2,2':5',2' ':5' ',2' ''-quaterthiophene (DHCO-4T), 5, 5' ''-diperfluorohexylcarbonyl-2,2':5',2' ':5' ',2' ''-quaterthiophene (DFHCO-4T), and 2,7-[bis-(5-perfluorohexylcarbonylthien-2-yl)]-4H-cyclopenta[2,1-b:3,4-b']-dithiophen-4-one (DFHCO-4TCO) have been synthesized and characterized. Field-effect transistors fabricated with these materials exhibit high electron mobilities both in a vacuum (up to 0.6 cm2 V-1 s-1) and in air (up to 0.02 cm2 V-1 s-1) and very high Ion:Ioff currents ratios (>107). DHCO-4T is the first organic material exhibiting excellent ambipolar transport (mue/muh up to 0.1/0.01 cm2 V-1 s-1, (Ion:Ioff)e/(Ion:Ioff)h up to 107/108 for the same device) over a broad range of deposition temperatures. These materials are therefore promising for organic complementary circuits.

  DOI：

  10.1021/ja045124g
• 作为产物：
  描述：

  全氟己基碘烷 在 甲基锂 、 溴 作用下， 以 乙醚 、 二氯甲烷 为溶剂， 反应 0.67h， 生成 perfluorohexyl-(5-bromothien-2-yl)methanol
  参考文献：
  名称：

  Organic Thin-Film Transistors Based on Carbonyl-Functionalized Quaterthiophenes:  High Mobility N-Channel Semiconductors and Ambipolar Transport

  摘要：

  New carbonyl-functionalized quaterthiophenes, 5, 5' ''-diheptanoyl-2,2':5',2' ':5' ',2' ''-quaterthiophene (DHCO-4T), 5, 5' ''-diperfluorohexylcarbonyl-2,2':5',2' ':5' ',2' ''-quaterthiophene (DFHCO-4T), and 2,7-[bis-(5-perfluorohexylcarbonylthien-2-yl)]-4H-cyclopenta[2,1-b:3,4-b']-dithiophen-4-one (DFHCO-4TCO) have been synthesized and characterized. Field-effect transistors fabricated with these materials exhibit high electron mobilities both in a vacuum (up to 0.6 cm2 V-1 s-1) and in air (up to 0.02 cm2 V-1 s-1) and very high Ion:Ioff currents ratios (>107). DHCO-4T is the first organic material exhibiting excellent ambipolar transport (mue/muh up to 0.1/0.01 cm2 V-1 s-1, (Ion:Ioff)e/(Ion:Ioff)h up to 107/108 for the same device) over a broad range of deposition temperatures. These materials are therefore promising for organic complementary circuits.

  DOI：

  10.1021/ja045124g

文献信息

• Carbonyl-functionalized thiophene compounds and related device structures
  申请人：Marks J. Tobin

  公开号：US20060186401A1

  公开（公告）日：2006-08-24

  Carbonyl-functionalized oligo/polythiophene compounds, and related semiconductor components and related device structures.

  羰基官能化的寡/聚噻吩化合物，以及相关的半导体组件和相关的器件结构。
• Carbonyl-Functionalized Thiophene Compounds and Related Device Structures
  申请人：Marks Tobin J.

  公开号：US20090267061A1

  公开（公告）日：2009-10-29

  Carbonyl-functionalized oligo/polythiophene compounds, and related semiconductor components and related device structures.

  含有羰基官能团的寡/聚噻吩化合物，以及相关的半导体组件和相关的器件结构。
• WO2007/50049
  申请人：——

  公开号：——

  公开（公告）日：——
• CARBONYL-FUNCTIONALIZED THIOPHENE COMPOUNDS AND RELATED DEVICE STRUCTURES
  申请人：Northwestern University

  公开号：EP1831205A1

  公开（公告）日：2007-09-12
• US7528176B2
  申请人：——

  公开号：US7528176B2

  公开（公告）日：2009-05-05