bis-dimethyldithiocarbamate palldium(II) | 23941-63-1

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: bis-dimethyldithiocarbamate palldium(II)
• 英文别名: Pd(dimethyldithiocarbamate)₂；Pd{(CH₃)₂DTC}₂；Pd(Me2NCS2)2；bis(dimethyldithiocarbamato)palladium(II)；[Pd(dimethyldithiocarbamato)2]；[Pd(S2CNMe2)2]；N,N-dimethylcarbamodithioate;palladium(2+)
• CAS: 23941-63-1
• 化学式: C₆H₁₂N₂PdS₄
• 分子量: 346.859
• InChiKey: LPJHMZFQPJJNOB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  0.76
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  72.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  [Pd(Me2NCS2)(ethylenediamine)]Cl 以 氘代二甲亚砜 为溶剂， 生成 bis-dimethyldithiocarbamate palldium(II)
  参考文献：
  名称：

  Palladium and platinum dithiocarbamato complexes containing mono- and diamines

  摘要：

  The [M(DMDT)X](n) (M=Pd or Pt; DMDT=Me2NCS2-; X=Cl or Br) species have been reacted with various amines (Py, pyridine; Pra, n-propylamine; Cba, cyclobutylamine; Dap, 1,3-diaminopropane; En, ethylenediamine) in dichloromethane with the aim of obtaining mixed complexes of various stoichiometries. Along with the neutral complexes M(DMDT)(L)X (L=Py, Pra or Cba), the ionic species IM(DMDT)(L,)IX, [M(DMDT)(En)]X and [M(DMDT)(Dap)]X have been isolated, which have been characterised by IR and proton NMR spectroscopy. Thermogravimetric data suggest a particular behaviour for the palladium-Pra and palladium-Cba derivatives, with formation of low-stoichiometry intermediates of formula Pd-2(DMDT)(2)AmX2. The behaviour of the prepared complexes in various solvents has been described on the basis of the proton NMR spectra. All complexes have been tested for in vitro cytostatic activity against KB cells. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00197-7

文献信息

• Allyl palladium dithiocarbamates and related dithiolate complexes as precursors to palladium sulfides
  作者：Anthony Birri、Benjamin Harvey、Graeme Hogarth、Elif Subasi、Fadime Uğur

  DOI：10.1016/j.jorganchem.2007.02.015

  日期：2007.5

  Allyl-palladium dithiocarbamate complexes, [Pd(allyl)(S2CNR2)], have been prepared from the addition of dithiocarbamate salts to [Pd(allyl)(μ-Cl)]2 and TGA and DSC studies have been carried out in order to assess their potential as MOCVD precursors to palladium sulfides. For comparison [(η3-C4H7)Pd(S2PPh2)] and [Pd(S2CNMeR)2] (R = Bu, Hex) have also been prepared and tested as precursors. The unsymmetrical

  烯丙基钯二硫代氨基甲酸酯络合物[Pd（烯丙基）（S 2 CNR 2）]是通过在[Pd（烯丙基）（μ-Cl）] 2中添加二硫代氨基甲酸酯盐制备的，已进行了TGA和DSC研究为了评估其作为硫化钯MOCVD前体的潜力。为了进行比较[（η 3 -C 4 ħ 7）的Pd（S 2 PPH 2）]和[钯（S 2 CNMeR）2 ]（R =卜，十六进制）也已被制备并作为前体进行测试。不对称二硫代氨基甲酸配合物，[（η 3 -C 3 H ^ 5）的Pd（S 2CNMeHex）]的熔点为65°C，被选为最佳的单一来源前体，并且在载玻片上沉积了主要为Pd 2.8 S的薄膜。[（η的晶体结构3 -C 4 ħ 7）的Pd（S 2 CNME 2）]，[（η 3 -C 4 ħ 7）的Pd（S 2 CNPr 2）]，[（η 3 -C 4 ħ报告了7）Pd（S 2 PPh 2）]和[Pd（S 2 CNMeBu）2 ]。所有除[（η
• Organopalladium(II) Complexes Derived from Chloro[4-[2-(diphenylphosphino)ethylamino]-3-penten-2-onato-<i>O</i>,<i>N</i>,<i>P</i>]palladium(II)
  作者：Katsuma Hiraki、Toyohiko Masumoto、Yoshio Fuchita、Yasushi Zegi

  DOI：10.1246/bcsj.54.1044

  日期：1981.4

  A new tertiary phosphine containing α,β-unsaturated β-amino ketone, 4-[2-(diphenylphosphino)ethylamino]-3-penten-2-one (Hdpeap), reacts with sodium tetrachloropalladate(II) in the absence or presence of sodium ethoxide to give [PdCl2(Hdpeap)2] or [PdCl(dpeap)] [dpeap ≡ 4-[2-(diphenylphosphino)ethylamino]-3-penten-2-onatoO,N,P], respectively. The latter complex reacts with terminal acetylenes in the presence of catalytic amounts of copper(I) iodide to produce alkynyl complexes, [Pd(C≡CR)(dpeap)]. Carbanions derived from active methylene compounds, and sodium dimethyldithiocarbamate also react with [PdCl(dpeap)] to afford [Pd(CHYY′)(dpeap)] and [Pd(S2CNMe2)2], respectively.

  一种新的含 α、β-不饱和 β-氨基酮的三级膦，4-[2-（二苯基膦）乙基氨基]-3-戊烯-2-酮（Hdpeap）、与四氯钯酸钠（II）在没有或有乙醇钠存在的情况下反应，分别生成 [PdCl2(Hdpeap)2] 或 [PdCl(dpeap)] [dpeap ≡ 4-[2-（二苯基膦）乙基氨基]-3-戊烯-2-onatoO,N,P]。后一种络合物与末端乙炔在催化量的碘化铜存在下发生反应，生成炔基络合物 [Pd(C≡CR)(dpeap)]。从活性亚甲基化合物中提取的卡巴酮和二甲基二硫代氨基甲酸钠也会与[PdCl(dpeap)]发生反应，分别生成[Pd(CHYY′)(dpeap)]和[Pd(S2CNMe2)2]。