4-氯-N-乙基-6-甲硫基-1,3,5-三嗪-2-胺 | 30357-95-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 中文名称: 4-氯-N-乙基-6-甲硫基-1,3,5-三嗪-2-胺
• 英文名称: 2-Methylmercapto-4-ethylamino-6-chlor-s-triazin
• 英文别名: (4-chloro-6-methylsulfanyl-[1,3,5]triazin-2-yl)-ethyl-amine；4-chloro-N-ethyl-6-methylsulfanyl-1,3,5-triazin-2-amine
• CAS: 30357-95-0
• 化学式: C₆H₉ClN₄S
• 分子量: 204.683
• InChiKey: DYACWKSWPIBIJU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  76
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  三甲胺 、 4-氯-N-乙基-6-甲硫基-1,3,5-三嗪-2-胺 以93%的产率得到
  参考文献：
  名称：

  DOVLATYAN V. V.; XACHATRYAN L. A.; AMBARTSUMYAN EH. N., AJKAKAN KIMIAKAN AMSAGIR, ARM. XIM. ZH., 1979, 32, HO 6, 492-495

  摘要：

  DOI：
• 作为产物：
  描述：

  4,6-二氯-2-乙氨基-1,3,5-均三嗪 、 sodium thiomethoxide 以 甲醇 为溶剂， 生成 4-氯-N-乙基-6-甲硫基-1,3,5-三嗪-2-胺
  参考文献：
  名称：

  Dimethoxypyrimidines as Novel Herbicides. Part 1. Synthesis and Herbicidal Activity of Dimethoxyphenoxyphenoxypyrimidines and Analogues

  摘要：

  A number of 6-(4-phenoxyphenoxy)pyrimidines and triazines were synthesized and their herbicidal activity was measured. Compounds with the methoxy groups at the 2- and 4-positions on the pyrimidine and triazine rings exhibited high herbicidal activity. Introduction of a substituent into the 5-position of the pyrimidine ring diminished the activity. In the phenoxyphenoxy substructure at the 6-position, the central ether bond can be replaced by a methylene group without loss of activity. The optimum substituent on the terminal phenyl ring was 3-trifluoromethyl. The compounds showed a strong Hill reaction inhibition, but unfortunately showed poor selectivity between weeds and crops.

  DOI：

  10.1002/(sici)1096-9063(199606)47:2<103::aid-ps396>3.0.co;2-z

文献信息

• SYNTHETIC POLYMERS AND METHODS OF MAKING AND USING THE SAME
  申请人：Battelle Memorial Institute

  公开号：US20160257785A1

  公开（公告）日：2016-09-08

  Disclosed herein are monomer embodiments that can be used to make polymers, such as homopolymers, heteropolymers, and that can be used in particular embodiments to make sequence-defined polymers. Also disclosed herein are methods of making polymers using such monomer embodiments. Methods of using the polymers disclosed herein also are described.

  本文揭示了可用于制造聚合物的单体实施例，例如同聚物、异聚物，并且可以用于特定实施例中制造序列定义的聚合物。本文还揭示了使用此类单体实施例制造聚合物的方法。还描述了使用本文所揭示的聚合物的方法。
• Zur Kenntnis der Reaktionsf�higkeit des unsubstituierten Thiomorpholins und alkylsubstituierter Thiomorpholine, 5. Mitt.
  作者：Friedrich Asinger、Manfred Kau�en、Irmgard Gold-Martin、Alfons Saus

  DOI：10.1007/bf00899678

  日期：1981.5
• DOVLATYAN, V. V.;GOMKTSYAN, T. A.;XACHATRYAN, N. X., ARM. XIM. ZH., 42,(1989) N, S. 187-191
  作者：DOVLATYAN, V. V.、GOMKTSYAN, T. A.、XACHATRYAN, N. X.

  DOI：——

  日期：——
• ASINGER F.; KAUSSEN M.; GOLD-MARTIN I.; SAUS A., MONATSH. CHEM., 1981, 112, NO 5, 643-657
  作者：ASINGER F.、 KAUSSEN M.、 GOLD-MARTIN I.、 SAUS A.

  DOI：——

  日期：——
• DOVLATYAN V. V.; GEVORKYAN R. A., AJKAKAN KIMIAKAN AMSAGIR, ARM. XIM. ZH., 1978, 31, HO 11, 851-856
  作者：DOVLATYAN V. V.、 GEVORKYAN R. A.

  DOI：——

  日期：——