| 12076-63-0

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 12076-63-0
• 化学式: C₃V₄
• 分子量: 239.799
• InChiKey: CYFRXPCJHLKLMN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  7.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  氢气 、 以 neat (no solvent) 为溶剂， 生成 vanadium carbide 、 methane
  参考文献：
  名称：

  Aleskeev, V. I.; Shvartsman, L. A., Fizika Metallov i Metallovedenie, 1961, vol. 11, # 4, p. 63 - 67

  摘要：

  DOI：
• 作为产物：
  描述：

  tetracarbonyl(η(5)-cyclopentadienyl)vanadium(I) 以 solid 为溶剂， 以33%的产率得到vanadocene
  参考文献：
  名称：

  Brown, Gilbert M.; Maya, Leon, Inorganic Chemistry, 1989, vol. 28, # 10, p. 2007 - 2010

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: V: MVol.B1, 125, page 328 - 330
  作者：

  DOI：——

  日期：——
• A novel reaction between physically separated solid reactants
  作者：James E. Gareh、Marten G. Barker、Michael J. Begley、Andrei S. Batsanov

  DOI：10.1039/dt9950003825

  日期：——

  Ternary oxides were converted to ternary sulfides by a metathesis reaction with a sulfur source such as diyttrium trisulfide. Reactions took place between two physically separated solid reactants under vacuum in a sealed silica tube. Preparation of the alkali-metal niobium disulfides ANbS(2) (A = Li, Na, K, Rb or Cs) has been attempted with isolation of quality crystals of the materials LixNbS2 [a = 3.3412(2) and c = 12.876(1) Angstrom] and Na0.41NbS2 [a = 3.3424(8) and c = 14.664(4) Angstrom] in the space group P6(3)/mmc. Also considered has been the metathesis reaction of sodium metavanadate, alkaline-earth metal titanates and selected Group 6 ternary oxides with diyttrium trisulfide. The mechanism of these metathesis reactions has been studied, and in the course of these investigations the reduced hexagonal LiNbO2 [a = 2.9070(6) and c = 10.457(3) Angstrom] was characterised. Formation of binary nitrides and carbides has been possible by replacing the sulfur source. Y2S3, with a source of nitrogen (e.g. YN) or carbon (e.g. TiC).