4,6-Dichloro-N,N-dimethyl-1,3,5,2,4,6-triazatriborinan-2-amine | 51310-48-6

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: 4,6-Dichloro-N,N-dimethyl-1,3,5,2,4,6-triazatriborinan-2-amine
• CAS: 51310-48-6
• 化学式: C₂H₉B₃Cl₂N₄
• 分子量: 192.459
• InChiKey: AGVTZQJTBKHCSX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.24
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  39.3
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tris(isopropylamino)borane 、 4,6-Dichloro-N,N-dimethyl-1,3,5,2,4,6-triazatriborinan-2-amine 在 tertiary amine 作用下， 以 甲苯 为溶剂， 生成 (NMe2)[(NHPr(i))2B(NPr(i)]2B3N3H3
  参考文献：
  名称：

  Borylborazines as new precursors for boron nitride fibres

  摘要：

  A variety of borylborazine-based polymers were successfully converted into boron nitride fibres via the preceramic polymer route. In this procedure, four monomers were polycondensed into highly tractable polymers which could be easily melt-spun into fine-diameter green fibres. These polymeric filaments were then transformed into boron nitride fibres after a well-defined heat-treatment at 1800 degrees C in a controlled atmosphere. All the resulting ceramic fibres were mechanically tested. In particular, results showed that the promising mechanical properties for two of the polymer-derived fibres were closely related to the structural units of the corresponding preceramic polymers. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.02.039

文献信息

• NARULA, CHAITANYA K.;SCHAEFFER, RILEY;DATYE, ABHAYA K.;BOREK, THEODORE T.+, CHEM. MATER., 2,(1990) N, C. 384-389
  作者：NARULA, CHAITANYA K.、SCHAEFFER, RILEY、DATYE, ABHAYA K.、BOREK, THEODORE T.+

  DOI：——

  日期：——
• Borylborazines as new precursors for boron nitride fibres
  作者：Philippe Miele、Bérangère Toury、David Cornu、Samuel Bernard

  DOI：10.1016/j.jorganchem.2005.02.039

  日期：2005.6

  A variety of borylborazine-based polymers were successfully converted into boron nitride fibres via the preceramic polymer route. In this procedure, four monomers were polycondensed into highly tractable polymers which could be easily melt-spun into fine-diameter green fibres. These polymeric filaments were then transformed into boron nitride fibres after a well-defined heat-treatment at 1800 degrees C in a controlled atmosphere. All the resulting ceramic fibres were mechanically tested. In particular, results showed that the promising mechanical properties for two of the polymer-derived fibres were closely related to the structural units of the corresponding preceramic polymers. (c) 2005 Elsevier B.V. All rights reserved.