1,1,6,6-tetrakis(trimethylsilyl)-1,6-bis[(trimethylsilyl)methyl]-2,2,3,3,4,4,5,5-octamethylhexasilane | 1314029-98-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,1,6,6-tetrakis(trimethylsilyl)-1,6-bis[(trimethylsilyl)methyl]-2,2,3,3,4,4,5,5-octamethylhexasilane
• 英文别名: [Bis(trimethylsilyl)-(trimethylsilylmethyl)silyl]-[[[[bis(trimethylsilyl)-(trimethylsilylmethyl)silyl]-dimethylsilyl]-dimethylsilyl]-dimethylsilyl]-dimethylsilane；[bis(trimethylsilyl)-(trimethylsilylmethyl)silyl]-[[[[bis(trimethylsilyl)-(trimethylsilylmethyl)silyl]-dimethylsilyl]-dimethylsilyl]-dimethylsilyl]-dimethylsilane
• CAS: 1314029-98-5
• 化学式: C₂₈H₈₂Si₁₂
• 分子量: 755.985
• InChiKey: SJRUDGGLKKGIDV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.53
• 重原子数：
  40
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2-(trimethylsilyl)-2-[(trimethylsilyl)methyl]hexamethyltrisilane 在 potassium tert-butylate 作用下， 以 苯 为溶剂， 反应 6.0h， 生成 1,1,6,6-tetrakis(trimethylsilyl)-1,6-bis[(trimethylsilyl)methyl]-2,2,3,3,4,4,5,5-octamethylhexasilane
  参考文献：
  名称：

  Conformational Control of Polysilanes: Use of CH₂ Spacers in the Silicon Backbone

  摘要：

  By the reaction of a number of oligosilyl potassium compounds with (trimethylsilyl)chloromethane, derivatives containing the (trimethylsilyl)methyl substituent were prepared. Using X-ray single-crystal structure analysis and UV spectroscopy the conformational properties of some of the compounds were studied. It was found that the (trimethylsilyl)methylated examples exhibit UV absorption properties which correspond to lower energy transitions in comparison to those of analogous trimethyl-silylated molecules. The influence of this effect decreases, however, with increasing chain lengths.

  DOI：

  10.1021/om1011159

文献信息

• Conformational Control of Polysilanes: Use of CH₂ Spacers in the Silicon Backbone
  作者：Andreas Wallner、Johann Hlina、Harald Wagner、Judith Baumgartner、Christoph Marschner

  DOI：10.1021/om1011159

  日期：2011.8.8

  By the reaction of a number of oligosilyl potassium compounds with (trimethylsilyl)chloromethane, derivatives containing the (trimethylsilyl)methyl substituent were prepared. Using X-ray single-crystal structure analysis and UV spectroscopy the conformational properties of some of the compounds were studied. It was found that the (trimethylsilyl)methylated examples exhibit UV absorption properties which correspond to lower energy transitions in comparison to those of analogous trimethyl-silylated molecules. The influence of this effect decreases, however, with increasing chain lengths.