3-(2-(ethyl(4-((4-nitrophenyl)diazenyl)phenyl)amino)ethoxy)-2-hydroxybenzaldehyde | 1142067-27-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 3-(2-(ethyl(4-((4-nitrophenyl)diazenyl)phenyl)amino)ethoxy)-2-hydroxybenzaldehyde
• CAS: 1142067-27-3
• 化学式: C₂₃H₂₂N₄O₅
• 分子量: 434.451
• InChiKey: HBBZKEJFGNMUIF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.43
• 重原子数：
  32.0
• 可旋转键数：
  10.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  117.63
• 氢给体数：
  1.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  3-(2-(ethyl(4-((4-nitrophenyl)diazenyl)phenyl)amino)ethoxy)-2-hydroxybenzaldehyde 、 乙二胺 以 乙醇 为溶剂， 以89.7%的产率得到2-[2-[N-ethyl-4-[(4-nitrophenyl)diazenyl]anilino]ethoxy]-6-[2-[[3-[2-[N-ethyl-4-[(4-nitrophenyl)diazenyl]anilino]ethoxy]-2-hydroxyphenyl]methylideneamino]ethyliminomethyl]phenol
  参考文献：
  名称：

  Synthesis and two-photon absorption property of novel salen complexes incorporated with two pendant azo dyes

  摘要：

  New salen compounds have been developed to possess two pendant azo dye chromophores. The two-photon absorption properties have been observed which result from the chromophores. The additive property has been found to exist as a result of no detrimental dipole-dipole interaction between chromophores. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.12.112
• 作为产物：
  描述：

  2-(allyloxy)-3-(2-(ethyl(4-((4-nitrophenyl)diazenyl)phenyl)amino)ethoxy)benzaldehyde 在 高氯酸 、 palladium 10% on activated carbon 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 48.0h， 以83%的产率得到3-(2-(ethyl(4-((4-nitrophenyl)diazenyl)phenyl)amino)ethoxy)-2-hydroxybenzaldehyde
  参考文献：
  名称：

  Synthesis and two-photon absorption property of novel salen complexes incorporated with two pendant azo dyes

  摘要：

  New salen compounds have been developed to possess two pendant azo dye chromophores. The two-photon absorption properties have been observed which result from the chromophores. The additive property has been found to exist as a result of no detrimental dipole-dipole interaction between chromophores. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.12.112