cobalt(II) valinate | 115730-00-2

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: cobalt(II) valinate
• 英文别名: Co(Val)2
• CAS: 115730-00-2
• 化学式: C₈H₁₆CoN₂O₄
• 分子量: 263.219
• InChiKey: UNLDDVNFHMSYDE-QTNFYWBSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  N-methyl-5,10,15,20-tetraphenylporphyrin 、 cobalt(II) valinate 以 二甲基亚砜 为溶剂， 生成 cobalt(II) N-methyltetraphenylporphine
  参考文献：
  名称：

  Reactions of Chelate Complexes with Macrocyclic Ligands. Tetra-tert-butylphthalocyanine

  摘要：

  Complexation reactions of tetra-tert-butylphthalocyanine (I) with Cu(II) acetate, acetylacetonate, 8-hydroxyquinolate, glycinate, valinate or dithizonate, as well as with Zn(II), Co(II), and Ni(II) 8-hydroxyquinolates, valinates, and dithizonates were studied. Unlike porphyrins themselves and porphyrins with planar distortions, compound I was found to form metal phthalocyanines with all indicated chelate salts in common solvents. It was established that compound I exhibits more equalized dependences of the coordination rate on the nature of the salt anion and cation as compared to the majority of the other porphyrins.

  DOI：

  10.1023/b:ruco.0000026003.90733.86

文献信息

• Mamardashvili; Chizhova; Berezin, Russian Journal of Inorganic Chemistry, 2004, vol. 49, # 3, p. 408 - 411
  作者：Mamardashvili、Chizhova、Berezin

  DOI：——

  日期：——