1,3,5-三丙基-1,3,5-三嗪-2,4,6(1H,3H,5H)-三酮 | 4015-16-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 中文名称: 1,3,5-三丙基-1,3,5-三嗪-2,4,6(1H,3H,5H)-三酮
• 中文别名: 5-(1-甲基-4-哌啶基)-5H-二苯并[a,d]环庚烯-5-醇盐酸
• 英文名称: Tri(n-propylisocyanurat)
• 英文别名: 1,3,5-Tripropyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione；1,3,5-tripropyl-1,3,5-triazinane-2,4,6-trione
• CAS: 4015-16-1
• 化学式: C₁₂H₂₁N₃O₃
• 分子量: 255.317
• InChiKey: OFHWSHGIZXHMJP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  60.9
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2933699090

反应信息

• 作为产物：
  描述：

  异氰酸丙酯 在 1,3-二甲基-2-咪唑啉酮 、 sodium 4-methylbenzenesulfinate 作用下， 反应 24.0h， 以78%的产率得到1,3,5-三丙基-1,3,5-三嗪-2,4,6(1H,3H,5H)-三酮
  参考文献：
  名称：

  二异氰酸酯向具有刚性异氰脲酸酯结构的高性能网络聚合物的环三聚：芳族和脂族二异氰酸酯的组合可调节灵活性

  摘要：

  通过二异氰酸酯的环三聚反应，使用亚甲基二苯基4,4'-二异氰酸酯和1,6-六亚甲基二异氰酸酯（HMDI）以几种进料比率合成了一系列带有异氰脲酸酯部分的网络聚合物。尽管这两种二异氰酸酯之间的内在反应性差异很大，但它们分别通过使用对甲苯磺酸钠（pTolSO 2 Na）和1,3-二甲基-2-咪唑啉酮作为催化剂和溶剂有效地进行了共成膜。所得的网状聚合物是透明的，并表现出优异的热稳定性。此外，富含HMDI的进料比可以形成具有更大柔韧性的网状聚合物。©2013 Wiley Periodicals，Inc. J. Polym。科学，A部分：Polym。化学 2013、51、2631-2637

  DOI：

  10.1002/pola.26651

文献信息

• HYDRAZONYL GROUP-CONTAINING CONDENSED HETEROCYCLIC COMPOUND OR SALT THEREOF, AGRICULTURAL AND HORTICULTURAL INSECTICIDE COMPRISING THE COMPOUND, AND METHOD FOR USING THE INSECTICIDE
  申请人：Nihon Nohyaku Co., Ltd.

  公开号：US20190177319A1

  公开（公告）日：2019-06-13

  An object of the present invention is to develop and provide a novel agricultural and horticultural insecticide in view of the still immense damage caused by insect pests etc. and the emergence of insect pests resistant to existing insecticides in crop production in the fields of agriculture, horticulture and the like. Provided is a hydrazonyl group-containing condensed heterocyclic compound or a salt thereof, preferably a condensed heterocyclic compound represented by the general formula (1): wherein R 1 represents, for example, an alkyl group, R 2 represents, for example, a hydrogen atom, R 3 and R 4 each represent, for example, an alkyl group, a haloalkyl group or an acyl group, A 1 represents, for example, a nitrogen atom, A 2 represents, for example, N-Me or an oxygen atom, A 3 represents, for example, a carbon atom or a nitrogen atom, A 4 represents, for example, C—H, m represents, for example, 2, and n represents, for example, 1}, or a salt thereof; an agricultural and horticultural insecticide comprising the compound or a salt thereof as an active ingredient; and a method for using the insecticide.

  本发明的一个目的是开发并提供一种新型农艺和园艺杀虫剂，鉴于昆虫害虫等造成的损害仍然巨大，以及在农业、园艺等领域作物生产中出现的对现有杀虫剂具有抗性的昆虫害虫。 提供了一种含有肼酰基的稠合杂环化合物或其盐，优选为通式(1)表示的稠合杂环化合物： 其中R1代表例如烷基，R2代表例如氢原子，R3和R4各自代表例如烷基、卤代烷基或酰基，A1代表例如氮原子，A2代表例如N-Me或氧原子，A3代表例如碳原子或氮原子，A4代表例如C—H，m代表例如2，n代表例如1}，或其盐；一种包含该化合物或其盐作为活性成分的农艺和园艺杀虫剂；以及使用该杀虫剂的方法。
• The Synthesis of Isocyanurates on the Trimerization of Isocyanates under High Pressure
  作者：Yoichi Taguchi、Isao Shibuya、Masahiko Yasumoto、Tohru Tsuchiya、Katsumi Yonemoto

  DOI：10.1246/bcsj.63.3486

  日期：1990.12

  The trimerization of phenyl isocyanate in the presence of triethylamine was accelerated under high pressure to give triphenyl isocyanurate almost quantitatively. The reaction in benzene was remarkably accelerated by compression. The effects of pressure, temperature, catalysts, and solvents were examined on the trimerization of phenyl isocyanate. Aryl and normal alkyl isocyanates trimerized under high

  异氰酸苯酯在三乙胺存在下的三聚反应在高压下加速，得到几乎定量的异氰脲酸三苯酯。苯中的反应通过压缩显着加速。考察了压力、温度、催化剂和溶剂对异氰酸苯酯三聚反应的影响。芳基和正烷基异氰酸酯在高压下三聚以良好的产率得到相应的异氰脲酸酯，而具有庞大烷基如叔丁基和环己基的异氰酸酯即使在800 MPa下也不会三聚。
• PYRIDONE COMPOUNDS AND AGRICULTURAL AND HORTICULTURAL FUNGICIDES CONTAINING THE SAME AS ACTIVE INGREDIENTS
  申请人：MITSUI CHEMICALS AGRO, INC.

  公开号：US20200172486A1

  公开（公告）日：2020-06-04

  Provided are a pyridone compound represented by Formula (1): wherein R1 represents a C1-C6 alkyl group which may be substituted, etc., R2 represents a halogen atom, a cyano group, etc., R3 and R4 are independent to each other, and each represents a hydrogen atom, a C1-C6 alkyl group which may be substituted, etc., or in combination with the nitrogen atom to which they are bonded form a pyrrolidinyl group, a piperidinyl group, etc., which may be substituted, Y represents a phenyl group which may be substituted, etc., X represents an oxygen atom or a sulfur atom, and an agricultural and horticultural fungicide containing the same as an active ingredient.

  提供的是由化学式（1）表示的吡啶酮化合物： 其中 R1代表一个可能被取代的C1-C6烷基，等等， R2代表一个卤素原子，一个氰基，等等， R3和R4彼此独立，每个代表一个氢原子，一个可能被取代的C1-C6烷基，等等，或者与它们结合的氮原子形成一个可能被取代的吡咯啉基团，一个哌啶基团，等等， Y代表一个可能被取代的苯基，等等， X代表一个氧原子或硫原子， 以及含有该化合物作为活性成分的农业和园艺用杀菌剂。
• HETEROCYCLE-BOUND CONDENSED HETEROCYCLIC COMPOUND OR SALT THEREOF, AGRICULTURAL AND HORTICULTURAL INSECTICIDE COMPRISING THE COMPOUND, AND METHOD FOR USING THE INSECTICIDE
  申请人：Nihon Nohyaku Co., Ltd.

  公开号：US20200361940A1

  公开（公告）日：2020-11-19

  In crop production in the fields of agriculture, horticulture and the like, the damage caused by insect pests etc. is still immense, and insect pests resistant to existing insecticides have emerged. To solve the problems, the present invention has been made, and an object of the present invention is to develop and provide a novel agricultural and horticultural insecticide. The present invention provides a heterocycle-bound condensed heterocyclic compound represented by the general formula (1): wherein R 1 represents an ethyl group, R 2 represents a haloalkyl group, A 1 represents a N-methyl group, A 2 and A 3 represent a nitrogen atom, n represents 1, m represents 2, and Q represents an oxadiazole}, or a salt thereof; an agricultural and horticultural insecticide comprising the compound or a salt thereof as an active ingredient; and a method for using the insecticide.

  在农业、园艺等领域的作物生产中，由昆虫害等造成的损害仍然巨大，并且出现了对现有杀虫剂具有抗性的昆虫害。为解决这些问题，已经制定了本发明，本发明的目的是开发并提供一种新型的农业和园艺杀虫剂。 本发明提供了一种由通式（1）表示的杂环结合的缩合杂环化合物： 其中R1代表乙基基团，R2代表卤代烷基基团，A1代表N-甲基基团，A2和A3代表氮原子，n代表1，m代表2，Q代表噁二唑基}，或其盐；一种以该化合物或其盐为活性成分的农业和园艺杀虫剂；以及使用该杀虫剂的方法。
• OXIME GROUP-CONTAINING CONDENSED HETEROCYCLIC COMPOUND OR SALT THEREOF, AGRICULTURAL AND HORTICULTURAL INSECTICIDE COMPRISING THE COMPOUND, AND METHOD FOR USING THE INSECTICIDE
  申请人：NIHON NOHYAKU CO., LTD.

  公开号：US20210371424A1

  公开（公告）日：2021-12-02

  Provided are an oxime group-containing condensed heterocyclic compound or a salt thereof, preferably a condensed heterocyclic compound represented by general formula (1): (wherein the symbols are defined in the specification); an agricultural and horticultural insecticide comprising the compound or a salt thereof as an active ingredient; and a method for using the insecticide.

  提供的是含有肟基的缩合杂环化合物或其盐，优选是由通式（1）表示的缩合杂环化合物： （其中符号在规范中定义）；包括该化合物或其盐作为活性成分的农业和园艺杀虫剂；以及使用该杀虫剂的方法。