ethyl 2-[2-(ethylsulfinyl)ethyl]sulfanylethyl sulfoxide | 74857-98-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 亚砜
• 英文名称: ethyl 2-[2-(ethylsulfinyl)ethyl]sulfanylethyl sulfoxide
• 英文别名: Ethane, 1,1'-thiobis(2-(ethylsulfinyl)-；1-ethylsulfinyl-2-(2-ethylsulfinylethylsulfanyl)ethane
• CAS: 74857-98-0
• 化学式: C₈H₁₈O₂S₃
• 分子量: 242.428
• InChiKey: RMOCMUXMGXDLFH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  97.9
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  ethyl-vinyl sulfoxide 在 sodium sulfide 作用下， 以 水 为溶剂， 反应 3.0h， 以55%的产率得到ethyl 2-[2-(ethylsulfinyl)ethyl]sulfanylethyl sulfoxide
  参考文献：
  名称：

  Reaction of vinyl sulfoxides with sodium sulfide and polysulfides

  摘要：

  Sodium sulfide and polysulfides readily (50-55 degrees C, 3 h, aqueous medium) react with alkyl vinyl sulfoxides to afford bis(alkylsulfinylethyl)sulfides and -polysulfides in up to 75% yield. Under comparable conditions the reaction of divinyl sulfoxide with sodium sulfide proceeds by the mechanism of addition-cyclization and results in 1,4-dithiane-1-oxide and 1,4-oxathiane-4-oxide. Microwave activation of the studied reactions allows to increase their rate and efficiency.

  DOI：

  10.1134/s1070363208050174

文献信息

• PREISS U., TECHN. UNIV. MUNCHEN, DISS. DOKT. NATURWISS. FAK. LANDWIRT. UND GARTENBAU+
  作者：PREISS U.

  DOI：——

  日期：——
• Reaction of vinyl sulfoxides with sodium sulfide and polysulfides
  作者：N. A. Chernysheva、N. K. Gusarova、S. V. Yas’ko、L. M. Sinegovskaya、B. A. Trofimov

  DOI：10.1134/s1070363208050174

  日期：2008.5

  Sodium sulfide and polysulfides readily (50-55 degrees C, 3 h, aqueous medium) react with alkyl vinyl sulfoxides to afford bis(alkylsulfinylethyl)sulfides and -polysulfides in up to 75% yield. Under comparable conditions the reaction of divinyl sulfoxide with sodium sulfide proceeds by the mechanism of addition-cyclization and results in 1,4-dithiane-1-oxide and 1,4-oxathiane-4-oxide. Microwave activation of the studied reactions allows to increase their rate and efficiency.