| 143238-47-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• CAS: 143238-47-5
• 化学式: C₂₄H₅₀OSn
• 分子量: 473.37
• InChiKey: ZRUKCIFCAMIENN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  26
• 可旋转键数：
  20
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  在 4 A molecular sieve 、 tert-butylammonium hexafluorophosphate(V) 作用下， 以 二氯甲烷 为溶剂， 以98%的产率得到4-Fluoro-2-heptyloxane
  参考文献：
  名称：

  Yoshida, Jun-Ichi; Ishichi, Yuji; Isoe, Sachihiko, Journal of the American Chemical Society, 1992, vol. 114, # 19, p. 7594 - 7595

  摘要：

  DOI：

文献信息

• Anodic cyclization of unsaturated α-stannyl ethers. Termination by bromide derived from dibromomethane
  作者：Jun-ichi Yoshida、Kazunori Takada、Yuji Ishichi、Sachihiko Isoe

  DOI：10.1039/c39940002361

  日期：——

  Anodic oxidation of unsaturated α-stannyl ethers in Bu4NClO4–CH2Br2 results in effective cyclization and the introduction of bromide into one of the original olefinic carbons; a mechanism involving the coupling between the cyclized carbocation and Br– generated by cathodic reduction of CH2Br2 is suggested.

  Bu4NClO4·CH2Br2 中不饱和α-甲锡烷基醚的阳极氧化导致有效环化并将溴化物引入原始烯属碳之一；提出了一种涉及环化碳正离子与 CH2Br2 阴极还原产生的 Br- 之间偶联的机制。
• Redox selective reactions of organo-silicon and -tin compounds
  作者：Jun-ichi Yoshida、Keiji Nishiwaki

  DOI：10.1039/a803343i

  日期：——

  The C-Si and C-Sn sigma orbitals are higher in energy than C-H or C-C sigma orbitals, and therefore can interact with neighboring pi systems, non-bonding orbitals of heteroatoms, and other sigma systems such as those of C-Si and C-Sn, Such interactions cause an increase of the HOMO level which in turn favors electron transfer. On the basis of this effect various types of redox selective reactions of organo-silicon and -tin compounds have been developed.
• Yoshida, Jun-Ichi; Ishichi, Yuji; Isoe, Sachihiko, Journal of the American Chemical Society, 1992, vol. 114, # 19, p. 7594 - 7595
  作者：Yoshida, Jun-Ichi、Ishichi, Yuji、Isoe, Sachihiko

  DOI：——

  日期：——