2,3-difluoro-6-[(4,6-dimethoxytriazin-2-yl)methyl]aniline | 1205556-85-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 2,3-difluoro-6-[(4,6-dimethoxytriazin-2-yl)methyl]aniline
• 英文别名: 6-[(4,6-Dimethoxy-1,3,5-triazin-2-yl)methyl]-2,3-difluorobenzenamine；6-[(4,6-dimethoxy-1,3,5-triazin-2-yl)methyl]-2,3-difluoroaniline
• CAS: 1205556-85-9
• 化学式: C₁₂H₁₂F₂N₄O₂
• 分子量: 282.25
• InChiKey: GRULUTBIHOVYBT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  83.2
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  2,3-difluoro-6-[(4,6-dimethoxytriazin-2-yl)methyl]aniline 、 二氟甲烷磺酰氯 在 吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 49.0h， 以29.9%的产率得到2,3-difluoro-6-[(4,6-dimethoxytriazin-2-yl)methyl]-N-difluoromethanesulfonanilide
  参考文献：
  名称：

  WO2007/31208

  摘要：

  公开号：

文献信息

• [EN] A USE OF SULFONANILIDES AS AGRICULTURAL AND HORTICULTURAL FUNGICIDE<br/>[FR] UTILISATION DE SULFONANILIDES COMME FONGICIDES POUR L'AGRICULTURE ET L'HORTICULTURE
  申请人：BAYER CROPSCIENCE AG

  公开号：WO2006008159A1

  公开（公告）日：2006-01-26

  Compounds of the formula ( I ), wherein Z represents C-R7 or N, and R5 represents alkyl that may be optionally substituted, alkenyl, alkynyl, cycloalkyl or alkoxycarbonylamino, are useful as agricultural and horticultural fungicides.

  式（I）的化合物，其中Z代表C-R7或N，而R5代表可以选择性取代的烷基，烯基，炔基，环烷基或烷氧羰基氨基，对农业和园艺真菌杀菌剂具有用处。
• Use of Sulfonanilides as Agricultural and Horticultural Fungicide
  申请人：Araki Koichi

  公开号：US20070219199A1

  公开（公告）日：2007-09-20

  Compounds of the formula (I), wherein Z represents C—R 7 or N, and R represents alkyl that may be optionally substituted, alkenyl, alkynyl, cycloalkyl or alkoxycarbonylamino, are useful as agricultural and horticultural fungicides.

  公式（I）的化合物，在该公式中，Z代表C—R7或N，R代表可以选择性地被取代的烷基，烯基，炔基，环烷基或烷氧羰基氨基，作为农业和园艺杀真菌剂是有用的。
• use of sulfonanilides as herbicide
  申请人：Araki Koichi

  公开号：US20090305894A1

  公开（公告）日：2009-12-10

  Herbicidal compositions comprising containing sulfonanilides of the formula (I), wherein R 1 represents hydrogen, fluorine, chlorine, C 1-4 alkyl, C 1-4 alkoxy, C 3-6 cycloalkyl-C 1-4 alkyloxy or C 1-4 haloalkoxy, R 2 represents hydrogen, fluorine or chlorine, R 3 represents hydrogen or fluorine, R 4 represents hydrogen or C 1-4 alkyl which may be optionally C 1-4 alkoxy-substituted, C 3-6 alkenyl or C 3-6 alkynyl, R 5 represents hydrogen, R 6 represents hydroxy, fluorine or chlorine, or R 5 and R 6 may form, together with the carbon to which they are bonded, C═O, and X represents CH or N, provided that the following cases are excluded: (i) R 1 represents hydrogen, fluorine or chlorine, R 2 represents hydrogen, R 3 represents hydrogen, R 4 represents hydrogen, R 5 represents hydrogen, and R 6 represents hydroxy, (ii) R 1 represents hydrogen, fluorine or chlorine, R 2 represents hydrogen, R 3 represents hydrogen, R 4 represents hydrogen, and R 5 and R 6 form C═O together with the carbon to which they are bonded, (iii) R 1 represents C 1-4 alkyl, R 2 represents hydrogen, R 3 represents hydrogen, R 4 represents hydrogen, R 5 represents hydrogen, R 6 represents hydroxy, and X represents CH, or (iv) R 1 represents C 1-4 alkyl, R 2 represents hydrogen, R 3 represents hydrogen, R 4 represents hydrogen, R 5 and R 6 form C═O together with the carbon to which they are bonded, and X represents CH, and new compounds being embraced by the formula (I).

  含有式(I)中的磺酰苯胺类化合物的除草组合物，其中R1代表氢、氟、氯、C1-4烷基、C1-4烷氧基、C3-6环烷基-C1-4烷氧基或C1-4卤代烷氧基，R2代表氢、氟或氯，R3代表氢或氟，R4代表氢或C1-4烷基，可以是可选择地C1-4烷氧基取代，C3-6烯基或C3-6炔基，R5代表氢，R6代表羟基、氟或氯，或者R5和R6可以与它们连接的碳一起形成C═O，X代表CH或N，但排除以下情况：(i) R1代表氢、氟或氯，R2代表氢，R3代表氢，R4代表氢，R5代表氢，R6代表羟基，(ii) R1代表氢、氟或氯，R2代表氢，R3代表氢，R4代表氢，R5和R6与它们连接的碳形成C═O，(iii) R1代表C1-4烷基，R2代表氢，R3代表氢，R4代表氢，R5代表氢，R6代表羟基，X代表CH，或(iv) R1代表C1-4烷基，R2代表氢，R3代表氢，R4代表氢，R5和R6与它们连接的碳形成C═O，X代表CH，新的化合物包括在式(I)中。
• USE OF SULFONANILIDES AS HERBICIDE
  申请人：Araki Koichi

  公开号：US20100323896A1

  公开（公告）日：2010-12-23

  Herbicidal compositions comprising containing sulfonanilides of the formula (I) wherein R 1 represents hydrogen, fluorine, chlorine, C 1-4 alkyl, C 1-4 alkoxy, C 3-6 cycloalkyl-C 1-4 alkyloxy or C 1-4 haloalkoxy, R 2 represents hydrogen, fluorine or chlorine, R 3 represents hydrogen or fluorine, R 4 represents hydrogen or C 1-4 alkyl which may be optionally C 1-4 alkoxy-substituted, C 3-6 alkenyl or C 3-6 alkynyl, R 5 represents hydrogen, R 6 represents hydroxy, fluorine or chlorine, or R 5 and R 6 may form, together with the carbon to which they are bonded, C═O, and X represents CH or N, provided that the following cases are excluded: (i) R 1 represents hydrogen, fluorine or chlorine, R 2 represents hydrogen, R 3 represents hydrogen, R 4 represents hydrogen, R 5 represents hydrogen, and R 6 represents hydroxy, (ii) R 1 represents hydrogen, fluorine or chlorine, R 2 represents hydrogen, R 3 represents hydrogen, R 4 represents hydrogen, and R 5 and R 6 form C═O together with the carbon to which they are bonded, (iii) R 1 represents C 1-4 alkyl, R 2 represents hydrogen, R 3 represents hydrogen, R 4 represents hydrogen, R 5 represents hydrogen, R 6 represents hydroxy, and X represents CH, or (iv) R 1 represents C 1-4 alkyl, R 2 represents hydrogen, R 3 represents hydrogen, R 4 represents hydrogen, R 5 and R 6 form C═O together with the carbon to which they are bonded, and X represents CH, and new compounds being embraced by the formula (I).

  含有公式（I）中的磺酰苯胺类化合物的除草剂组合物，其中R1代表氢、氟、氯、C1-4烷基、C1-4烷氧基、C3-6环烷基-C1-4烷氧基或C1-4卤代烷氧基，R2代表氢、氟或氯，R3代表氢或氟，R4代表氢或C1-4烷基，该C1-4烷基可以选择性地被C1-4烷氧基取代、C3-6烯基或C3-6炔基，R5代表氢，R6代表羟基、氟或氯，或者R5和R6可以与它们所连接的碳原子形成C═O，X代表CH或N，但排除以下情况：（i）R1代表氢、氟或氯，R2代表氢，R3代表氢，R4代表氢，R5代表氢，R6代表羟基，（ii）R1代表氢、氟或氯，R2代表氢，R3代表氢，R4代表氢，R5和R6与它们所连接的碳原子形成C═O，（iii）R1代表C1-4烷基，R2代表氢，R3代表氢，R4代表氢，R5代表氢，R6代表羟基，X代表CH，或（iv）R1代表C1-4烷基，R2代表氢，R3代表氢，R4代表氢，R5和R6与它们所连接的碳原子形成C═O，X代表CH，并且新化合物符合公式（I）。
• A USE OF SULFONANILIDES AS AGRICULTURAL AND HORTICULTURAL FUNGICIDE
  申请人：Bayer CropScience Aktiengesellschaft

  公开号：EP1773124B1

  公开（公告）日：2012-08-22