| 444809-29-4

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 444809-29-4
• 化学式: C₁₂H₈Br₂F₁₈Sn
• 分子量: 772.685
• InChiKey: BZTJPQUFOCPIBO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  8.93
• 重原子数：
  33
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为反应物：
  描述：

  、 水 在 NaOH 作用下， 以 四氢呋喃 、 水 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of fluoroalkyldistannoxanes

  摘要：

  1.3-Disubstituted tetrakis(fluoroalkyl)distannoxanes (XRf(2)SnOSnRf(2)Y)(2) (Rf = C6F13C2H4, C4F9C2H4; X, Y = Cl, Br, NCS) were synthesized from readily available dibenzyltin dibromide. The dimeric formulation of these compounds that was confirmed by Sn-119-NMR spectra gave rise to a structure in which the metalloxane core is covered by the surface fluorophilic alkyl groups. Thus. these compounds exhibited high solubility in fluorocarbon solvents and large partition coefficients for FC-72 against common organic solvent. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01398-5
• 作为产物：
  描述：

  1H,1H,2H,2H-全氟溴己烷 在 Mg 作用下， 以 四氢呋喃 、 四氯化碳 、 乙醚 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and characterization of fluoroalkyldistannoxanes

  摘要：

  1.3-Disubstituted tetrakis(fluoroalkyl)distannoxanes (XRf(2)SnOSnRf(2)Y)(2) (Rf = C6F13C2H4, C4F9C2H4; X, Y = Cl, Br, NCS) were synthesized from readily available dibenzyltin dibromide. The dimeric formulation of these compounds that was confirmed by Sn-119-NMR spectra gave rise to a structure in which the metalloxane core is covered by the surface fluorophilic alkyl groups. Thus. these compounds exhibited high solubility in fluorocarbon solvents and large partition coefficients for FC-72 against common organic solvent. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01398-5

文献信息

• Synthesis and characterization of fluoroalkyldistannoxanes
  作者：Jiannan Xiang、Akihiro Orita、Junzo Otera

  DOI：10.1016/s0022-328x(01)01398-5

  日期：2002.4

  1.3-Disubstituted tetrakis(fluoroalkyl)distannoxanes (XRf(2)SnOSnRf(2)Y)(2) (Rf = C6F13C2H4, C4F9C2H4; X, Y = Cl, Br, NCS) were synthesized from readily available dibenzyltin dibromide. The dimeric formulation of these compounds that was confirmed by Sn-119-NMR spectra gave rise to a structure in which the metalloxane core is covered by the surface fluorophilic alkyl groups. Thus. these compounds exhibited high solubility in fluorocarbon solvents and large partition coefficients for FC-72 against common organic solvent. (C) 2002 Elsevier Science B.V. All rights reserved.