Orange Luminescence and Structural Properties of Three Isostructural Halocyclohexylisonitrilegold(I) Complexes
作者:Rochelle L. White-Morris、Marilyn M. Olmstead、Alan L. Balch、O. Elbjeirami、Mohammad A. Omary
DOI:10.1021/ic0341946
日期:2003.10.1
not lie within the range of significant aurophilic bonding. The closest Au...Au distance is 3.7182(11) A while every other Au...Au distance is 3.9304(12) A. The steric factor of the X ligand and dipole-dipole interactions between the antiparallel complexes is much more significant than aurophilicinteractions in governing the self-association of the complexes in this series. The colorless crystals of