sodium N,N-dipropyldithiocarbamate monohydrate | 925458-17-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: sodium N,N-dipropyldithiocarbamate monohydrate
• 英文别名: sodium dipropyldithiocarbamate monohydrate；sodium N,N-dipropyldithiocarbamate；Na(PDtc)*H2O；sodium;N,N-dipropylcarbamodithioate;hydrate
• CAS: 925458-17-9
• 化学式: C₇H₁₄NS₂*H₂O*Na
• 分子量: 217.332
• InChiKey: MSJXVESFOZPUSP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.88
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  cadmium(II) perchlorate hexahydrate 、 sodium N,N-dipropyldithiocarbamate monohydrate 以 水 为溶剂， 以77%的产率得到bis[μ-(N,N-dipropyldithiocabamato)(N,N-dipropyldithiocabamato)cadmium(II)]
  参考文献：
  名称：

  Ivanov; Konzelko; Gerasimenko, Russian Journal of Inorganic Chemistry, 2005, vol. 50, # 11, p. 1710 - 1726

  摘要：

  DOI：

文献信息

• Synthesis and characterisation by spectroscopy and X-ray structure determination of palladium complexes containing the 1–3-η-1,2-di-t-butyl-3-methyl-4-methylenecyclobutenyl ligand
  作者：Philip J. Ridgwell、Pamela M. Bailey、Stuart N. Wetherell、Elizabeth A. Kelley、Peter M. Maitlis

  DOI：10.1039/dt9820000999

  日期：——

  The (1,2-di-t-butyl-3,4-dimethylcyclobutadiene)palladium complex [Pd2C4(Me)2( But)2}2Cl4] reacts with base with loss of HCl to give [Pd2C4:CH2(Me)(But)2}2Cl2](2). An X-ray crystal structure determination on the acetylacetonato-derivative [PdC4:CH2(Me)(But)2}(acac)](3) shows the acetylacetonatopalladium 1–3-η-bonded to a cyclobutenyl ligand bearing an unco-ordinated methylene substituent at C4, t-butyl

  的（1,2-二-叔-丁基-3,4-二dimethylcyclobutadiene）钯络合物[钯2 C 4（Me）的2（BU吨）2 } 2氯4 ]发生反应用碱，用HCl的损失，得到[ Pd 2 C 4：CH 2（Me）（Bu t）2 } 2 Cl 2 ]（2）。乙酰丙酮衍生物[Pd C 4：CH 2（Me）（Bu t）2的X射线晶体结构测定}（acac）]（3）显示与环丁烯基配体键合的乙酰基乙酰基萘钯铝1-3-η在C 4处带有不配位的亚甲基取代基，在C 1和C 2处带有叔丁基，在C 3处带有甲基。Nmr（1 H和13 C）光谱表明（2）中的配体具有相同的结构。合成的以下衍生物也是如此：[Pd 2（A）2 X 2 ]（X = Br，I或SCN），[Pd（A）（L）Cl]（L = Bu t NC，对-ClC 6 H 4 NC，对-MeC 6 H 4 NH2，PMe 2 Ph，PMePh 2，PPh
• Fixation modes of gold(III) from solutions using cadmium(II) dithiocarbamates. Preparation, supramolecular structure and thermal behaviour of polynuclear and heteropolynuclear gold(III) complexes: Bis(N,N-dialkyldithiocarbamato-S,S′)gold(III) polychlorometallates, [Au(S2CNR2)2]nX (n=1: X=[AuCl4]−; n=2: X=[CdCl4]2−, [Cd2Cl6]2−)
  作者：Tatyana A. Rodina、Alexander V. Ivanov、Andrey V. Gerasimenko、Olga V. Loseva、Oleg N. Antzutkin、Valentin I. Sergienko

  DOI：10.1016/j.poly.2012.03.043

  日期：2012.6

  single-crystal X-ray diffraction and simultaneous thermal analysis (STA) under an argon atmosphere. In all molecular structures (1–4), one of the gold atoms coordinates two dialkyldithiocarbamate ligands in the S,S′-bidentate mode, forming a square-planar coordination polygon [AuS4], while the other gold atom (in 3 and 4) has four neighbouring chlorine atoms [AuCl4]. At the supramolecular level, compounds 1 and

  通式[Au（S 2 CNR 2）2 ] 2 X（X = [CdCl 4 ] 2−，R = CH 3（1）; X = [Cd 2 Cl 6 ] 2−的四种新颖的杂多核和多核配合物，R = C 3 H 7（2））和[Au（S 2 CNR 2）2 ] [AuCl 4 ]（R = 异-C 3 H 7（3）； R = 异-C 4 H 9（4））是使用适当新鲜沉淀的双核二烷基二硫代氨基甲酸镉（II）与AuCl 3在2 M盐酸中的非均相反应制备的。通过13 C CP / MAS NMR光谱，单晶X射线衍射和氩气气氛下的同时热分析（STA）对分离的配合物进行了研究。在所有的分子结构（1 - 4），金原子坐标之一在两个二烷基二配体小号，小号'-bidentate模式，形成一个正方形平面协调多边形[AUS 4 ]，而其他金原子（在3和4）具有四个相邻的氯原子[AuCl 4 ]。在超分子水平上，化合物1和2包含双核阳离子[Au
• Chemisorption Synthesis of the Ion-Polymeric Heteronuclear Gold(III)–Bismuth(III) Complex ([Au{S2CN(C3H7)2}2]3[Bi2Cl9])n Based on [Bi2{S2CN(C3H7)2}6]: 13C MAS NMR, Supramolecular Structure, and Thermal Behavior
  作者：A. V. Ivanov、A. V. Gerasimenko、I. V. Egorova、A. S. Zaeva、E. V. Novikova、N. A. Rodionova、V. Gowda、O. N. Antzutkin

  DOI：10.1134/s1070328418080043

  日期：2018.8

  [Au2S2CN(C3H7)2}4]2+. The character of the thermal behavior of compounds I and II is studied by simultaneous thermal analysis with the identification of intermediate and final products of the thermal transformations. The thermolysis of compound I at 193–320°C is accompanied by the formation of Bi2S3 with an impurity of reduced metallic bismuth particles. The final products of the thermal transformations of compound

  摘要 的双核化合物的基础上化学吸附合成[毕2 S 2 CN（C 3 H ^ 7）2 } 6 ]（我）和（III）络合物（[的离子聚合异金（III）铋制备隔离进行Au S 2 CN（C 3 H 7）2 } 2 ] 3 [Bi 2 Cl 9 ]）n（II）。通过红外光谱和13的比较，对化合物I和II进行了表征C CP-MAS NMR。根据X射线衍射分析数据（CIF文件CCDC号1407705），化合物II的阳离子部分具有异常复杂的超分子结构，包括六个异构的非中心对称络合物阳离子[Au S 2 CN（C 3 H 7）2 } 2 ] +（以下为A–F）和两个双核阴离子[Bi 2 Cl 9 ] 3–作为构象体。异构金（III）阳离子具有各种结构功能。由于成对的次级相互作用，Au···S，阳离子B，C，E和F形成中心对称（[E··E]，[F··F]）和非中心对称（[B···C]）双核聚集体[Au
• Ivanov; Zinkin; Konzelko, Russian Journal of Inorganic Chemistry, 2004, vol. 49, # 4, p. 593 - 598
  作者：Ivanov、Zinkin、Konzelko、Forsling

  DOI：——

  日期：——
• Dithiocarbamates of dimethylthallium(III). Crystal structure of dimethyl(di-n-propyldithiocarbamato)thallium(III)
  作者：José S. Casas、María V. Castaño、Celestino Freire、Agustín Sánchez、José Sordo、Eduardo E. Castellano、Julio Zukerman-Schpector

  DOI：10.1016/0020-1693(93)03703-d

  日期：1994.2

  Six solid compounds of composition [TlMe2(dtc)] (where dtc is a dithiocarbamate anion) have been obtained. [TlMe2(S2CNnPr2)] Crystallizes in the space group C2 with a = 19.672(2), b = 8.5698(5), c = 9.194(2) angstrom, beta = 116.02(1)-degrees and Z = 4. The thallium atom is coordinated to the two sulfur atoms of a slightly anisobidentate dithiocarbamate ligand and to the two methyl groups, which form a highly distorted tetrahedral environment. In the crystal lattice these units are linked by additional weak Tl...S interactions. The main coordination characteristics of this compound seem to be common to the other complexes prepared, both in the solid state and in solution in CDCl3 or DMSO-d6, to judge by their spectral (IR and NMR) properties.