5-phenyl-1,2-didehydroazepine | 590364-47-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吖庚因类
• 英文名称: 5-phenyl-1,2-didehydroazepine
• CAS: 590364-47-9
• 化学式: C₁₂H₉N
• 分子量: 167.21
• InChiKey: BUPDZPIYYGEACT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  二乙胺 、 5-phenyl-1,2-didehydroazepine 以 环己烷 为溶剂， 生成 4-氨基联苯 、 2-(diethylamino)-5-phenyl-3H-azepine
  参考文献：
  名称：

  1,2-Didehydroazepines from the photolysis of substituted aryl azides: analysis of their chemical and physical properties by time-resolved spectroscopic methods

  摘要：

  DOI：

  10.1021/ja00232a022
• 作为产物：
  描述：

  Azobenzol -Radikal 以 环己烷 为溶剂， 生成 5-phenyl-1,2-didehydroazepine
  参考文献：
  名称：

  1,2-Didehydroazepines from the photolysis of substituted aryl azides: analysis of their chemical and physical properties by time-resolved spectroscopic methods

  摘要：

  DOI：

  10.1021/ja00232a022

文献信息

• Organic electroluminescent materials and devices
  申请人：Universal Display Corporation

  公开号：US10833276B2

  公开（公告）日：2020-11-10

  This invention relates to carbazole- or indolocarbazole-containing donor acceptor type compounds with an ortho substitution on the aromatic group that is connected to carbazole. This unique substitution pattern will provide materials with superior performance for host applications. These compounds can also be used as delayed fluorescent emitters.

  本发明涉及含咔唑或吲哚咔唑的供体受体型化合物，与咔唑相连的芳香基团上有一个正交取代基。这种独特的取代模式将为宿主应用提供性能优越的材料。这些化合物还可用作延迟荧光发射器。
• Organic Electroluminescent Materials and Devices
  申请人：Universal Display Corporation

  公开号：US20180145262A1

  公开（公告）日：2018-05-24

  This invention relates to carbazole- or indolocarbazole-containing donor acceptor type compounds with an ortho substitution on the aromatic group that is connected to carbazole. This unique substitution pattern will provide materials with superior performance for host applications. These compounds can also be used as delayed fluorescent emitters.
• US9997712B2
  申请人：——

  公开号：US9997712B2

  公开（公告）日：2018-06-12
• 1,2-Didehydroazepines from the photolysis of substituted aryl azides: analysis of their chemical and physical properties by time-resolved spectroscopic methods
  作者：Yu Zhuo. Li、John P. Kirby、Michael W. George、Martyn. Poliakoff、Gary B. Schuster

  DOI：10.1021/ja00232a022

  日期：1988.11