[4-(4-Methoxybenzoyl)oxyphenyl] 4-hydroxybenzoate | 59138-69-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: [4-(4-Methoxybenzoyl)oxyphenyl] 4-hydroxybenzoate
• 英文别名: [4-(4-methoxybenzoyl)oxyphenyl] 4-hydroxybenzoate
• CAS: 59138-69-1
• 化学式: C₂₁H₁₆O₆
• 分子量: 364.354
• InChiKey: YEWVEYQJCPIQNN-UHFFFAOYSA-N

物化性质

• 沸点：
  576.9±45.0 °C(Predicted)
• 密度：
  1.307±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  27
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  82.1
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  [4-(4-Methoxybenzoyl)oxyphenyl] 4-hydroxybenzoate 、 (2S)-2-methyloctan-1-ol 在 三苯基膦 、 偶氮二甲酸二乙酯 作用下， 以 苯 为溶剂， 反应 20.0h， 生成
  参考文献：
  名称：

  Prediction of the absolute configuration of optically active pheromones using liquid crystals

  摘要：

  Prediction of the absolute configuration of optically active methyl branched pheromones is possible by combining them with mesogens to give them liquid crystalline properties and measuring the helical senses of the chiral nematic phases.

  DOI：

  10.1016/s0957-4166(00)80176-7
• 作为产物：
  描述：

  4-(甲氧基甲基)苯甲酸 在 盐酸 、 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 80.0h， 生成 [4-(4-Methoxybenzoyl)oxyphenyl] 4-hydroxybenzoate
  参考文献：
  名称：

  Prediction of the absolute configuration of optically active pheromones using liquid crystals

  摘要：

  Prediction of the absolute configuration of optically active methyl branched pheromones is possible by combining them with mesogens to give them liquid crystalline properties and measuring the helical senses of the chiral nematic phases.

  DOI：

  10.1016/s0957-4166(00)80176-7

文献信息

• POLYMERIZABLE COMPOUND AND POLYMERIZABLE COMPOSITION
  申请人：Adeka Corporation

  公开号：EP2067796A1

  公开（公告）日：2009-06-10

  A polymerizable compound represented by general formula (1): wherein Z1 and Z2 each represent a (meth)acryloyloxy group; X1 and X2 each independently represent a single bond, an optionally branched alkylene group having 1 to 8 carbon atoms, an ether linkage, -COO-, -OCO-, -OCOO-, a 6-membered ring optionally having a substituent, or a combination thereof; R1 represents -R', -OR', -CO-R', or -OCO-R'; R' represents a halogen atom, an optionally branched alkyl group having 1 to 8 carbon atoms, or a 6-membered ring optionally having a substituent, L1 and L2 each independently represent a member selected from a single bond, -CH2CH2-, -CH=CH-, -C≡C-, -CH2O-, -OCH2-, -COO-, and -OCO-; m represents an integer of 1 to 4; and the R1's may be the same or different.

  由通式(1)代表的可聚合化合物： 其中 Z1 和 Z2 各自代表(甲基)丙烯酰氧基；X1 和 X2 各自独立地代表单键、具有 1 至 8 个碳原子的任选支链亚烷基、醚键、-COO-、-OCO-、-OCOO-、任选具有取代基的 6 元环或它们的组合；R1 代表-R'、-OR'、-CO-R'或-OCO-R'；R'代表卤素原子、具有 1 至 8 个碳原子的任选支链烷基或任选具有取代基的 6 元环，L1 和 L2 各自独立地代表选自单键、-CH2CH2-、-CH=CH-、-C≡C-、-CH2O-、-OCH2-、-COO-和-OCO-的成员；m 代表 1 至 4 的整数；且 R1 可以相同或不同。
• POLYMER-STABILIZED LIQUID CRYSTAL DISPLAY DEVICE AND MANUFACTURING METHOD THEREFOR
  申请人：Beijing BOE Optoelectronics Technology Co., Ltd.

  公开号：EP2755076B1

  公开（公告）日：2017-12-06
• LIQUID DISPLAY PANEL AND PROCESS FOR PREPARING SAME
  申请人：BEIJING BOE OPTOELECTRONICS TECHNOLOGY CO., LTD.

  公开号：US20140078455A1

  公开（公告）日：2014-03-20

  Embodiments of the invention provide a liquid display panel and a process for preparing the same comprising: coating a polymerizable siloxane solution onto either of an array substrate and a color filter substrate; applying a mixture comprising a liquid crystalline polymerizable monomer, a photoinitiator, and liquid crystal between the color filter substrate and the array substrate; and allowing the liquid crystalline polymerizable monomer and the polymerizable siloxane to polymerize under effect of the photoinitiator with UV irradiation to generate a network of high molecular polymers, thereby anchoring liquid crystal molecules in the liquid crystal to a state of vertical orientation. The liquid display panel effectively increases the uniformity of the arrangement of the long axes of the liquid crystal molecules vertical to the array substrate, reduces the deviation of arrangement in the vertical direction among the liquid crystal molecules at different positions of the liquid display panel, and improves display performance of the liquid display panel.
• US7160586B2
  申请人：——

  公开号：US7160586B2

  公开（公告）日：2007-01-09
• US8344175B2
  申请人：——

  公开号：US8344175B2

  公开（公告）日：2013-01-01