1-amino-1'-(2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopent-1-yl)ferrocene | 727728-52-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1-amino-1'-(2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopent-1-yl)ferrocene
• 英文别名: cyclopenta-2,4-dien-1-amine;1-cyclopenta-2,4-dien-1-yl-2,2,5,5-tetramethyl-1,2,5-azadisilolidine;iron(2+)
• CAS: 727728-52-1
• 化学式: C₁₆H₂₆FeN₂Si₂
• 分子量: 358.414
• InChiKey: GRLKVJWVXJYDGN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1-amino-1'-(2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopent-1-yl)ferrocene 生成 2,2,5,5-四甲基-2,5-二硅-1-噁环戊烷
  参考文献：
  名称：

  A novel [6]ferrocenophane containing a N–Si–C–C–Si–N bridge, in equilibrium by ring-opening with an 1,1 ′ -diaminoferrocene derivative

  摘要：

  The reaction of 1,1'-diaminoferrocene 1 with 1,2-bis(chlorodimethylsilyl)ethane in the presence of triethylamine leads to the ferrocene derivative 5 bearing in 1'-position the amino group and in F-position an azadisilacyclopentyl ring. Complex 5 is shown to be in equilibrium with the 1,6,2,5-diazadisila-[6]ferrocenophane 6. Both complexes 5 and 6 were characterised by X-ray structural analysis, and in solution by H-1, C-13 and Si-29 NMR spectroscopy. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.12.029
• 作为产物：
  描述：

  tetramethyl-1,6,2,5-diazadisila-[6]ferrocenophane 以 二氯甲烷 为溶剂， 生成 1-amino-1'-(2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopent-1-yl)ferrocene
  参考文献：
  名称：

  A novel [6]ferrocenophane containing a N–Si–C–C–Si–N bridge, in equilibrium by ring-opening with an 1,1 ′ -diaminoferrocene derivative

  摘要：

  The reaction of 1,1'-diaminoferrocene 1 with 1,2-bis(chlorodimethylsilyl)ethane in the presence of triethylamine leads to the ferrocene derivative 5 bearing in 1'-position the amino group and in F-position an azadisilacyclopentyl ring. Complex 5 is shown to be in equilibrium with the 1,6,2,5-diazadisila-[6]ferrocenophane 6. Both complexes 5 and 6 were characterised by X-ray structural analysis, and in solution by H-1, C-13 and Si-29 NMR spectroscopy. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.12.029