diethylbromosilane | 18243-42-0

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: diethylbromosilane
• 英文别名: diethyl-bromo-silane；Diaethyl-brom-silan；Brom-diaethyl-silan；Diethyl-bromosilan；Bromo(diethyl)silane；bromo(diethyl)silane
• CAS: 18243-42-0
• 化学式: C₄H₁₁BrSi
• 分子量: 167.121
• InChiKey: HEMAEYDQCYFFKF-UHFFFAOYSA-N

物化性质

• 沸点：
  121 °C(Press: 750 Torr)
• 密度：
  1.1903 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.14
• 重原子数：
  6
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  diethylbromosilane 在 lithium nitrate 、 溴 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 二溴(二乙基)硅烷
  参考文献：
  名称：

  Hetflejs,J. et al., Collection of Czechoslovak Chemical Communications, 1972, vol. 37, p. 1713 - 1720

  摘要：

  DOI：
• 作为产物：
  描述：

  二乙基硅烷 在 Ag(II) bromide 作用下， 生成 diethylbromosilane
  参考文献：
  名称：

  A Further Study of the Flash Photolysis of Iodine¹

  摘要：

  DOI：

  10.1021/ja01552a023

文献信息

• Synthesis of Bromohydrosilanes: Reactions of Hydrosilanes with CuBr₂in the Presence of CuI
  作者：Atsutaka Kunai、Takahiko Ochi、Arihiro Iwata、Joji Ohshita

  DOI：10.1246/cl.2001.1228

  日期：2001.12

  Reactions of hydrosilanes, R4−nSiHn (R = alkyl or phenyl, n = 1–3), with 2 equiv of CuBr2 in the presence of a catalytic amount of CuI led to selective replacement of an H–Si bond with a Br–Si bond giving R3SiBr, R2SiHBr, or RSiH2Br, while treatment of R2SiH2 and RSiH3 with 4 equiv of the reagent produced R2SiBr2 and RSiHBr2, respectively. Similar reaction of Het2SiSiEt2H afforded Het2SiSiEt2Br.

  在一定量的 CuI 催化下，氢硅烷 R4-nSiHn（R = 烷基或苯基，n = 1-3）与 2 等量的 CuBr2 反应，导致 H-Si 键被 Br-Si 键选择性置换，得到 R3SiBr、R2SiHBr 或 RSiH2Br，而用 4 等量的试剂处理 R2SiH2 和 RSiH3 则分别得到 R2SiBr2 和 RSiHBr2。Het2SiSiEt2H 发生类似反应后可得到 Het2SiSiEt2Br。
• Transition Metal Catalyzed Reaction of Peralkylated 3,4-Bis(alkylidene)-1,2-disilacyclobutane
  作者：Takahiro Kusukawa、Yoshio Kabe、Wataru Ando

  DOI：10.1246/cl.1993.985

  日期：1993.6

  Peralkylated 3,4-bis(alkylidene)-1,2-disilacyclobutanes prepared by convenient synthetic route were quantitatively converted to 3,4,7,8-tetrakis(alkylidene)-1,2,5,6-tetrasilacyclooctane (twist and chair 1:1 mixture) by Pd-catalyzed reaction. In the presence of unsaturated compounds, this disilane metathesis reaction was inhibited to give double silylation products. The reaction pathways are highly dependent upon electronic factors of unsaturated compounds and the catalyst.

  通过简便的合成路线制备的过烷基化 3,4 双（亚烷基）-1,2-二硅氧烷环丁烷在钯催化反应下定量转化为 3,4,7,8 四（亚烷基）-1,2,5,6-四硅氧烷环辛烷（捻和椅 1:1 混合物）。在存在不饱和化合物的情况下，这种二硅烷偏合成反应受到抑制，生成双硅烷化产物。反应途径在很大程度上取决于不饱和化合物和催化剂的电子因素。
• Selective synthesis of halosilanes from hydrosilanes and utilization for organic synthesis
  作者：Atsutaka Kunai、Joji Ohshita

  DOI：10.1016/s0022-328x(03)00254-7

  日期：2003.11

  Selective synthesis of halosilanes has been examined. Various types of halosilanes and halohydrosilanes, such as R3SiX, R2SiHX, R2SiX2, RSiH2X, RSiHX2 (X = Cl, Br, F), were obtained by the reactions of the corresponding hydrosilanes with Cu(II)-based reagents selectively in high yields. This method could be also applied to the synthesis of chlorofluorosilanes and chlorohydrogermanes. On the other hand, iodo- and bromosilanes and germanes were obtained by Pd- or Ni-catalyzed hydride-halogen exchange reactions of hydrosilanes with alkyl or allyl halides. Their synthetic applications have been demonstrated by using iodo-and bromosilanes and chlorofluorosilanes. (C) 2003 Elsevier Science B.V. All rights reserved.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Hg: MVol.B2, 171, page 759 - 760
  作者：

  DOI：——

  日期：——
• Reactions of Triethylsilane and Diethylsilane with Inorganic Halides and Acids
  作者：Herbert H. Anderson

  DOI：10.1021/ja01552a022

  日期：1958.10