pentamethyldisalonol | 18135-02-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: pentamethyldisalonol
• 英文别名: pentamethyldisilanol；Pentamethyl-disilanol；hydroxy-dimethyl-trimethylsilylsilane
• CAS: 18135-02-9
• 化学式: C₅H₁₆OSi₂
• 分子量: 148.352
• InChiKey: RSRKFRJVUFMLEU-UHFFFAOYSA-N

物化性质

• 沸点：
  33 °C(Press: 2 Torr)
• 密度：
  0.8311 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  iron(II) bis(trimethylsilyl)amide 、 pentamethyldisalonol 以 正己烷 为溶剂， 以92%的产率得到iron(II) pentamethyldisiloxide
  参考文献：
  名称：

  摘要：

  Iron and cobalt siloxides and germyloxides [(Me3Si)(3)SiO](2)M (M = Fe (1), Co (2)), (Me5Si2O)(2)Fe (3), ((Pr3SiO)-Si-i)(2)M (M = Fe (4), Co (5)), ((Pr3GeO)-Ge-i)(2)Fe (6), (Ph3SiO)(2)Fe (7), (Me3SiO)(2)Fe (8), ((Pr3GeO)-Ge-i)(2)Fe(bpy) (9), and [(Me3Si)(2)NFe(mu-OSi2Me5)(2)](2)Fe.C6H6 (10) were synthesized by the reactions of metal silylamides [(Me3Si)(2)N](2)M (M = Fe, Co) with the corresponding silanols or triisopropylgermanol. The reaction of pentamethyldisilanol with iron(II) silylamide affords either polymeric complex 3 or coordination oligomer 10, depending on the ratio of the reactants. The structures of complexes 9 and 10 were established by X-ray diffraction analysis. The interaction of the prepared compounds with carbon oxides was studied. Low-coordination cobalt siloxide is the only among all prepared compounds that absorbs CO (2 mol) at room temperature and under 1 atm to form an unstable cluster. Compounds 1, 2, and 4-8 react with CO2 to form carbonate complexes, and their reactivity decreases with a decrease in the electron-donating ability of the substituents at the central atom: (Me3Si)(3)SiO > (Pr3GeO)-Ge-i approximate to (Pr3SiO)-Si-i > Me3SiO much greater than Ph3SiO.

  DOI：

  10.1023/a:1023423202997
• 作为产物：
  描述：

  一氯五甲基二硅烷 在 ammonium hydroxide 作用下， 以 乙醚 为溶剂， 生成 pentamethyldisalonol
  参考文献：
  名称：

  Razuaev, G. A.; Brevnova, T. N.; Semenov, V. V., Journal of general chemistry of the USSR, 1980, p. 1472 - 1476

  摘要：

  DOI：

文献信息

• Liquid-Phase Oxidation of Pentamethyldisilane with Oxygen
  作者：V. I. Timokhin、A. B. Zaborovskii、K. Ferreri、C. Chatgilialoglu

  DOI：10.1023/b:rugc.0000030409.75067.37

  日期：2004.3
• RAZUVAEV G. A.; BREVNOVA T. N.; CEMEHOB V. V., ZH. OBSHCH. XIMII, 1980, 50, HO 8, 1806-1811
  作者：RAZUVAEV G. A.、 BREVNOVA T. N.、 CEMEHOB V. V.

  DOI：——

  日期：——
• ITINOXEH, SEHJDZI;XAMADA, JOSITAKA
  作者：ITINOXEH, SEHJDZI、XAMADA, JOSITAKA

  DOI：——

  日期：——
• Razuaev, G. A.; Brevnova, T. N.; Semenov, V. V., Journal of general chemistry of the USSR, 1980, p. 1472 - 1476
  作者：Razuaev, G. A.、Brevnova, T. N.、Semenov, V. V.

  DOI：——

  日期：——
• ——
  作者：Ya. V. Fedotova

  DOI：10.1023/a:1023423202997

  日期：——

  Iron and cobalt siloxides and germyloxides [(Me3Si)(3)SiO](2)M (M = Fe (1), Co (2)), (Me5Si2O)(2)Fe (3), ((Pr3SiO)-Si-i)(2)M (M = Fe (4), Co (5)), ((Pr3GeO)-Ge-i)(2)Fe (6), (Ph3SiO)(2)Fe (7), (Me3SiO)(2)Fe (8), ((Pr3GeO)-Ge-i)(2)Fe(bpy) (9), and [(Me3Si)(2)NFe(mu-OSi2Me5)(2)](2)Fe.C6H6 (10) were synthesized by the reactions of metal silylamides [(Me3Si)(2)N](2)M (M = Fe, Co) with the corresponding silanols or triisopropylgermanol. The reaction of pentamethyldisilanol with iron(II) silylamide affords either polymeric complex 3 or coordination oligomer 10, depending on the ratio of the reactants. The structures of complexes 9 and 10 were established by X-ray diffraction analysis. The interaction of the prepared compounds with carbon oxides was studied. Low-coordination cobalt siloxide is the only among all prepared compounds that absorbs CO (2 mol) at room temperature and under 1 atm to form an unstable cluster. Compounds 1, 2, and 4-8 react with CO2 to form carbonate complexes, and their reactivity decreases with a decrease in the electron-donating ability of the substituents at the central atom: (Me3Si)(3)SiO > (Pr3GeO)-Ge-i approximate to (Pr3SiO)-Si-i > Me3SiO much greater than Ph3SiO.