4-((3-aminophenoxy)carbonyl)phenyl 4-(tetradecyloxy)benzoate | 1228118-16-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-((3-aminophenoxy)carbonyl)phenyl 4-(tetradecyloxy)benzoate
• CAS: 1228118-16-8
• 化学式: C₃₄H₄₃NO₅
• 分子量: 545.719
• InChiKey: UAXJDQSDOAYTGB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.79
• 重原子数：
  40.0
• 可旋转键数：
  18.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  87.85
• 氢给体数：
  1.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  4-((3-aminophenoxy)carbonyl)phenyl 4-(tetradecyloxy)benzoate 、 4-Tetradecyloxy-benzoic acid 4-formyl-3-hydroxy-phenyl ester 在 溶剂黄146 作用下， 以 乙醇 为溶剂， 反应 1.0h， 生成 [4-[3-[[2-Hydroxy-4-(4-tetradecoxybenzoyl)oxyphenyl]methylideneamino]phenoxy]carbonylphenyl] 4-tetradecoxybenzoate
  参考文献：
  名称：

  Synthesis and Characterization of Unsymmetrical Five-Ring Achrial Banana-Shaped Compounds With a B2 Phase

  摘要：

  Two series of unsymmetrical banana-shaped materials have been prepared with laterally substituted hydroxy and nitro groups. All the compounds exhibit liquid crystalline properties. The syntheses and liquid crystalline properties of these compounds are discussed.

  DOI：

  10.1080/15421400902841445
• 作为产物：
  描述：

  4-(4-tetradecyloxybenzoyloxy)benzoic acid 在 4-二甲氨基吡啶 、 palladium on activated charcoal 、 氢气 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 、 乙酸乙酯 为溶剂， 生成 4-((3-aminophenoxy)carbonyl)phenyl 4-(tetradecyloxy)benzoate
  参考文献：
  名称：

  Synthesis and Characterization of Unsymmetrical Five-Ring Achrial Banana-Shaped Compounds With a B2 Phase

  摘要：

  Two series of unsymmetrical banana-shaped materials have been prepared with laterally substituted hydroxy and nitro groups. All the compounds exhibit liquid crystalline properties. The syntheses and liquid crystalline properties of these compounds are discussed.

  DOI：

  10.1080/15421400902841445