2-(6-Chloro-4-oxo-2,3-dihydrothiochromen-2-yl)acetic acid | 57537-91-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫铬烷
• 英文名称: 2-(6-Chloro-4-oxo-2,3-dihydrothiochromen-2-yl)acetic acid
• CAS: 57537-91-4
• 化学式: C₁₁H₉ClO₃S
• 分子量: 256.71
• InChiKey: RQBFVISIBJCWDX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  79.7
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  甲醇 、 2-(6-Chloro-4-oxo-2,3-dihydrothiochromen-2-yl)acetic acid 在 硫酸 作用下， 反应 10.0h， 以90%的产率得到2H-1-Benzothiopyran-2-acetic acid, 3,4-dihydro-6-chloro-4-oxo-, methyl ester
  参考文献：
  名称：

  Shridhar, D. R.; Sastry, C. V. Reddy; Lal, B., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1983, vol. 22, # 3, p. 300 - 302

  摘要：

  DOI：
• 作为产物：
  描述：

  戊烯二酸二甲酯 在 盐酸 、 硫酸 、 苄基三甲基氢氧化铵 作用下， 以 甲醇 为溶剂， 反应 24.0h， 生成 2-(6-Chloro-4-oxo-2,3-dihydrothiochromen-2-yl)acetic acid
  参考文献：
  名称：

  Shridhar, D. R.; Sastry, C. V. Reddy; Lal, B., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1983, vol. 22, # 3, p. 300 - 302

  摘要：

  DOI：

文献信息

• ACTINIC RADIATION-CURING TYPE INK SET, INKJET RECORDING METHOD, AND PRINTED MATERIAL
  申请人：FUJIFILM CORPORATION

  公开号：US20130230701A1

  公开（公告）日：2013-09-05

  Disclosed is an actinic radiation-curing type ink set comprising a colored ink composition and a clear ink composition (C1), the colored ink composition comprising (Component A1) a radically polymerizable compound, (Component B1) a polymerization initiator, and (Component D) a colorant, and the clear ink composition (C1) comprising (Component A2) a radically polymerizable compound, (Component B2) a polymerization initiator, and (Component S) an organic solvent.

  公开了一种光致固化型油墨套装，包括一种有色油墨组合和一种清晰油墨组合（C1），其中有色油墨组合包括（成分A1）一种自由基聚合物化合物，（成分B1）一种聚合引发剂和（成分D）一种着色剂，而清晰油墨组合（C1）包括（成分A2）一种自由基聚合物化合物，（成分B2）一种聚合引发剂和（成分S）一种有机溶剂。
• Photocurable coating composition, and overprint and process for producing same
  申请人：FUJIFILM Corporation

  公开号：EP2042563A1

  公开（公告）日：2009-04-01

  A photocurable coating composition is provided that includes (A) a compound represented by Formula (I) below, (B) a photopolymerization initiator, and (C) a compound having an ethylenically unsaturated bond. (In Formula (I), X denotes O, S, or NR, n denotes an integer of 0 to 4, R denotes a hydrogen atom, an alkyl group, or an acyl group, R1 to R8 independently denote a hydrogen atom or a monovalent substituent, and R1 to R4 may form a ring in which two thereof that are adjacent are bonded to each other.) There are also provided an overprint having on an electrophotographically printed material an overprint layer in which the photocurable coating composition is photocured, and a process for producing the overprint that includes a step of obtaining an electrophotographically printed material by carrying out electrophotographic printing on a printing substrate, a step of coating the electrophotographically printed material with the photocurable coating composition, and a step of photocuring the photocurable coating composition.

  光固化涂料组合物包括 (A) 下式 (I) 所代表的化合物、(B) 光聚合引发剂和 (C) 具有乙烯不饱和键的化合物。 (在式(I)中，X 表示 O、S 或 NR，n 表示 0 至 4 的整数，R 表示氢原子、烷基或酰基，R1 至 R8 独立地表示氢原子或单价取代基，R1 至 R4 可形成其中相邻的两个相互键合的环)。 还提供了一种罩印，其在电致发光印刷材料上具有罩印层，在罩印层中光固化了光固化涂层组合物，还提供了一种生产罩印的工艺，该工艺包括通过在印刷基底上进行电致发光印刷获得电致发光印刷材料的步骤、在电致发光印刷材料上涂布光固化涂层组合物的步骤，以及对光固化涂层组合物进行光固化的步骤。
• Ink-jet ink composition, and ink-jet recording method
  申请人：Fujifilm Corporation

  公开号：EP2154213A1

  公开（公告）日：2010-02-17

  An ink-jet ink composition containing the following components of (a), (b), and (c), and having a viscosity at 25°C in the range of from 5 mPa·s to 100 mPa·s, (a) a polymerizable compound, (b) a photopolymerization initiator, and (c) a sensitizer represented by the following formula (i): in the Formula (i), X represents O, S or NR; n represents an integer of 0 or 1; R represents a hydrogen atom, an alkyl group or an acyl group; each of R1, R2, R3, R4, R5, R6, R7 and R8 independently represents a hydrogen atom or a monovalent substituent, provided that any neighboring two of R1, R2, R3 and R4 may be bonded to each other to form a ring, and R5 and R7 or R8, or R6 and R7 or R8, may be bonded to each other to form an aliphatic ring but do not form an aromatic ring.

  一种喷墨墨水组合物，含有(a)、(b)和(c)中的下列成分，在 25℃时的粘度在 5 mPa-s 至 100 mPa-s 之间、 (a) 可聚合化合物、 (b) 光聚合引发剂，和 (c) 下式(i)所代表的敏化剂： 式（i）中，X 代表 O、S 或 NR；n 代表 0 或 1 的整数；R 代表氢原子、烷基或酰基；R1、R2、R3、R4、R5、R6、R7 和 R8 中的每一个独立地代表一个氢原子或一个一价取代基，但 R1、R2、R3 和 R4 中的任意相邻两个可相互键合形成一个环，R5 和 R7 或 R8 或 R6 和 R7 或 R8 可相互键合形成一个脂肪族环，但不形成一个芳香族环。
• Aqueous ink composition, aqueous ink composition for inkjet recording, and inkjet recording method
  申请人：Fujifilm Corporation

  公开号：EP2145932A1

  公开（公告）日：2010-01-20

  The present invention provides an aqueous ink composition including at least a sensitizing dye represented by the following Formula (i), an ethylenically unsaturated bond-containing water-soluble polymerizable compound, a polymerization initiator and water: wherein, in Formula (i), X represents O, S or NR; n represents an integer of 0 or 1; R represents a hydrogen atom, an alkyl group or an acyl group; each of R1, R2, R3, R4, R5, R6, R7 and R8 independently represents a hydrogen atom or a monovalent substituent, provided that any neighboring two of R1, R2, R3 and R4 may be bonded to each other to form a ring, and R5 and R7 or R8, or R6 and R7 or R8, may be bonded to each other to form an aliphatic ring but do not form an aromatic ring.

  本发明提供了一种水性油墨组合物，其中至少包括一种由下式(i)表示的敏化染料、一种含乙烯不饱和键的水溶性可聚合化合物、一种聚合引发剂和水： 其中，在式 (i) 中，X 代表 O、S 或 NR；n 代表 0 或 1 的整数；R 代表氢原子、烷基或酰基；R1、R2、R3、R4、R5、R6、R7 和 R8 中的每一个独立地代表一个氢原子或一个单价取代基，但 R1、R2、R3 和 R4 中的任意相邻两个可相互键合形成一个环，R5 和 R7 或 R8 或 R6 和 R7 或 R8 可相互键合形成一个脂肪族环，但不形成一个芳香族环。
• Ink set, ink jet recording method, and ink jet recording apparatus
  申请人：Fujifilm Corporation

  公开号：EP2457963A1

  公开（公告）日：2012-05-30

  An ink set including a yellow ink composition, a magenta ink composition, a cyan ink composition, and a black ink composition, in which the respective ink compositions contain a radical polymerizable compound (component A), a radical polymerization initiator (component B), and a colorant (component C) respectively, the component B included in the respective ink compositions contains an acylphosphine oxide compound (component B-1) and a thioxanthone compound (component B-2) respectively, the respective ink compositions contain from 3% by mass to less than 17% by mass of the component B-1, the magenta ink composition and the cyan ink composition contain from 0.1% by mass to less than 2% by mass of the component B-2, and the yellow ink composition and the black ink composition contain from 2% by mass to less than 6% by mass of the component B-2.

  一种油墨组合物，包括黄色油墨组合物、品红色油墨组合物、青色油墨组合物和黑色油墨组合物，其中各油墨组合物分别含有可自由基聚合的化合物（组分 A）、自由基聚合引发剂（组分 B）和着色剂（组分 C）、各油墨组合物中包含的组分 B 分别含有酰基氧化膦化合物（组分 B-1）和硫氧杂蒽酮化合物（组分 B-2），各油墨组合物中的组分 B-1 的质量百分比为 3%至小于 17%，品红色油墨组合物和青色油墨组合物中的组分 B-1 的质量百分比为 0.以质量计，品红色油墨组合物和青色油墨组合物含有 0.1% 至低于 2% 的组分 B-2，而黄色油墨组合物和黑色油墨组合物含有 2% 至低于 6% 的组分 B-2。