1-allyl-1,1,2,2-tetramethyl-2-(4-trimethylsilanylethynylphenyl)disilane | 834966-32-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1-allyl-1,1,2,2-tetramethyl-2-(4-trimethylsilanylethynylphenyl)disilane
• 英文别名: 1-Allyl-1,1,2,2-tetramethyl-2-(4-trimethylsilanylethynylphenyl) disilane；[dimethyl(prop-2-enyl)silyl]-dimethyl-[4-(2-trimethylsilylethynyl)phenyl]silane
• CAS: 834966-32-4
• 化学式: C₁₈H₃₀Si₃
• 分子量: 330.693
• InChiKey: YBYNIRKDFCGKPI-UHFFFAOYSA-N

物化性质

• 沸点：
  332.5±42.0 °C(Predicted)
• 密度：
  0.89±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-allyl-1,1,2,2-tetramethyl-2-(4-trimethylsilanylethynylphenyl)disilane 在 氢氧化钾 作用下， 以 水 为溶剂， 生成 [二甲基(丙-2-烯基)甲硅烷基]-(4-乙炔基苯基)-二甲基硅烷
  参考文献：
  名称：

  Synthesis of organosilicon polymers by using the Lewis-acid-catalyzed trans-allylsilylation of alkynes

  摘要：

  The HfCl4 catalyzed polymerization of allyl(4-ethynylphenyl)dimethylsilane (1a) proceeded smoothly to give poly[dimethyl-(1,4-pentadienyl)phenylsilane] (2a), and the HfCl4 catalyzed reaction of 1-aallyl-2-(4-ethynyphenyl)-1,1,2,2-tetramethyl-disilane (1b) afforded poly[1,1,2,2-tetramethyl-1-(1,4-pentadienyl)-2-phenyldisilane] (2b). These polymerization reactions proceeded via the stereoselective trans-allylsilylation of the 4-ethynyl group attached to the aromatic ring. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.11.048
• 作为产物：
  描述：

  对溴碘苯 、 alkaline earth salt of/the/ methylsulfuric acid 在 钯 正丁基锂 作用下， 生成 1-allyl-1,1,2,2-tetramethyl-2-(4-trimethylsilanylethynylphenyl)disilane
  参考文献：
  名称：

  Synthesis of organosilicon polymers by using the Lewis-acid-catalyzed trans-allylsilylation of alkynes

  摘要：

  The HfCl4 catalyzed polymerization of allyl(4-ethynylphenyl)dimethylsilane (1a) proceeded smoothly to give poly[dimethyl-(1,4-pentadienyl)phenylsilane] (2a), and the HfCl4 catalyzed reaction of 1-aallyl-2-(4-ethynyphenyl)-1,1,2,2-tetramethyl-disilane (1b) afforded poly[1,1,2,2-tetramethyl-1-(1,4-pentadienyl)-2-phenyldisilane] (2b). These polymerization reactions proceeded via the stereoselective trans-allylsilylation of the 4-ethynyl group attached to the aromatic ring. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.11.048

文献信息

• Organosilicon compounds and method of manufacturing the same
  申请人：Japan Science and Technology Agency

  公开号：US07253243B2

  公开（公告）日：2007-08-07

  There is provided a method of synthesizing an organosilicon compound. This method comprises polymerizing, as a starting material, allyl-(4-alkynyl-phenyl) silane represented by the following general formula (3) in a solvent selected from methylene chloride, chloroform, carbon tetrachloride and 1,2-dichloroethane and under the presence of hafnium tetrachloride to obtain an organosilicon compound represented by the following general formula (1). (wherein R is a hydrogen atom, an alkyl group having 1 to 6 carbon atoms or a phenyl group, R's may be the same or different and are individually an alkyl group having 1 or 2 carbon atoms or a phenyl group, and n is an integer of 4 to 2500).

  提供一种合成有机硅化合物的方法。该方法包括在甲烷氯、氯仿、四氯化碳和1,2-二氯乙烷等溶剂中，以铪四氯化物存在下，聚合以下通式（3）所表示的烯丙基-（4-炔基苯基）硅烷作为起始物质，以获得以下通式（1）所表示的有机硅化合物。（其中，R是氢原子、具有1至6个碳原子的烷基或苯基，R可以相同或不同，分别是具有1或2个碳原子的烷基或苯基，n是4至2500的整数。）
• Synthesis of organosilicon polymers by using the Lewis-acid-catalyzed trans-allylsilylation of alkynes
  作者：Naoki Asao、Hisamitsu Tomeba、Yoshinori Yamamoto

  DOI：10.1016/j.tetlet.2004.11.048

  日期：2005.1

  The HfCl4 catalyzed polymerization of allyl(4-ethynylphenyl)dimethylsilane (1a) proceeded smoothly to give poly[dimethyl-(1,4-pentadienyl)phenylsilane] (2a), and the HfCl4 catalyzed reaction of 1-aallyl-2-(4-ethynyphenyl)-1,1,2,2-tetramethyl-disilane (1b) afforded poly[1,1,2,2-tetramethyl-1-(1,4-pentadienyl)-2-phenyldisilane] (2b). These polymerization reactions proceeded via the stereoselective trans-allylsilylation of the 4-ethynyl group attached to the aromatic ring. (C) 2004 Elsevier Ltd. All rights reserved.