3,3-bis(trimethylsilyl)tricyclo[4.2.1.0^2,5]nonene-7

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: 3,3-bis(trimethylsilyl)tricyclo[4.2.1.0^2,5]nonene-7
• 英文别名: 3,3-bis(trimethylsilyl)-exo-tricyclo[4.2.1.0(2,5)]non-7-ene；trimethyl-[(1R,2R,5S,6S)-3-trimethylsilyl-3-tricyclo[4.2.1.02,5]non-7-enyl]silane
• 化学式: C₁₅H₂₈Si₂
• 分子量: 264.558
• InChiKey: FQNZXIDXAPWTMD-ZOBORPQBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.78
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  3,3-bis(trichlorosilyl)-exo-tricyclo[4.2.1.0(2,5)]non-7-ene 、 甲基溴化镁 以 乙醚 为溶剂， 反应 70.0h， 以54%的产率得到3,3-bis(trimethylsilyl)tricyclo[4.2.1.0^2,5]nonene-7
  参考文献：
  名称：

  Synthesis of silicon-substituted tricyclononenes

  摘要：

  A new series of tricyclononene derivatives with two and three silyl groups are successfully synthesized via [2 sigma+2 sigma+2 pi]-cycloaddition of silylethylenes to quadricyclane. The activity of the silylethylenes in the cycloaddition reactions was estimated. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.09.009

文献信息

• A Novel, Highly Gas-Permeable Polymer Representing a New Class of Silicon-Containing Polynorbornens As Efficient Membrane Materials
  作者：Pavel P. Chapala、Maxim V. Bermeshev、Ludmila E. Starannikova、Nikolay A. Belov、Victoria E. Ryzhikh、Victor P. Shantarovich、Valentin G. Lakhtin、Natalia N. Gavrilova、Yuri P. Yampolskii、Eugene Sh. Finkelshtein

  DOI：10.1021/acs.macromol.5b02087

  日期：2015.11.24

  synthesis and gas permeation properties of addition-type poly(3,3-bis(trimethylsilyl)tricyclononene-7) (PTCNSi2g) are first reported. High molecular weight PTCNSi2g was obtained via addition polymerization of 3,3-bis(trimethylsilyl)tricylononene-7 on a Pd-containing catalyst. It possessed a BET surface area as high as 790 m2/g. This new polymer is distinguished by extra high gas permeability and solubility

  首先报道了加成型聚（3,3-双（三甲基甲硅烷基）三环壬烯-7）（PTCNSi2g）的合成和气体渗透性能。通过在含Pd的催化剂上3，3-双（三甲基甲硅烷基）三苯乙炔-7的加成聚合反应获得高分子量PTCNSi2g。它具有高达790 m 2 / g的BET表面积。这种新型聚合物的特点是具有极高的气体渗透性和烃类的溶解度受控的渗透性。正电子an没寿命光谱显示自由体积元素的尺寸非常大（8.3Å）。PTCNSi2g是用于天然气分离的有前途的膜材料。
• Synthesis of silicon-substituted tricyclononenes
  作者：M.V. Bermeshev、A.V. Syromolotov、M.L. Gringolts、V.G. Lakhtin、E.Sh. Finkelshtein

  DOI：10.1016/j.tetlet.2011.09.009

  日期：2011.11

  A new series of tricyclononene derivatives with two and three silyl groups are successfully synthesized via [2 sigma+2 sigma+2 pi]-cycloaddition of silylethylenes to quadricyclane. The activity of the silylethylenes in the cycloaddition reactions was estimated. (C) 2011 Elsevier Ltd. All rights reserved.