(E)-1-戊烯基三甲基硅烷 | 56183-56-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: (E)-1-戊烯基三甲基硅烷
• 英文名称: (E)-1-pentenyltrimethylsilane
• 英文别名: trimethyl-pent-1-en-t-yl-silane；Trimethyl-pent-1-en-t-yl-silan；trans-1-Trimethylsilyl-penten-(1)；1-trans-Pentenyltrimethylsilan；trans-1-Trimethylsilylpenten；trimethyl-[(E)-pent-1-enyl]silane
• CAS: 56183-56-3
• 化学式: C₈H₁₈Si
• 分子量: 142.316
• InChiKey: UFUHTHNESOEDRH-BQYQJAHWSA-N

物化性质

• 沸点：
  133-135 °C
• 密度：
  0.734 g/cm3(Temp: 28 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  3.22
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (E)-1-戊烯基三甲基硅烷 以68%的产率得到
  参考文献：
  名称：

  Adam Waldemar, Richter Markus J., J. Org. Chem., 59 (1994) N 12, S 3335- 3340

  摘要：

  DOI：
• 作为产物：
  描述：

  4-propyl-3-trimethylsilanyl-oxetan-2-one 生成 (E)-1-戊烯基三甲基硅烷
  参考文献：
  名称：

  ZAJTSEVA G. S.; LIVANTSOVA L. I.; BAUKOV YU. I.; LUTSENKO I. F., ZH. OBSHCH. XIMII, 1980, 50, HO 8, 1880

  摘要：

  DOI：

文献信息

• Highly Stereoselective Synthesis of Vinylsilanes from Carbonyl Compounds
  作者：José Barluenga、José L. Fernández-Simón、José M. Concellón、Miguel Yus

  DOI：10.1055/s-1988-27526

  日期：——

  The in situ generated (chlorolithiomethyl)trimethylsilane reacts at - 60°C to - 45°C with different aldehydes or ketones 1 to afford, after lithiation with lithium naphthalenide at - 78 °C to 20 °C, vinylsilanes 5a-b in a stereoselective manner.

  在-60°C至-45°C条件下，原位生成的（氯甲基）三甲基硅烷与不同的醛或酮1反应，在-78°C至20°C条件下与萘锂发生锂化反应后，以立体选择性方式生成乙烯基硅烷5a-b。
• Regioselectivity of the Singlet Oxygen Ene Reaction (Schenck Reaction) with Vinylsilanes
  作者：Waldemar Adam、Markus J. Richter

  DOI：10.1021/jo00091a020

  日期：1994.6

  The ene reaction-of singlet oxygen and vinylsilanes 1 with various substitution patterns and double-bond geometry has been studied. beta-Silyl allylic hydroperoxides 2 were the major products of the photooxygenation, accompanied by smaller amounts of alpha,beta-unsaturated ketones 3. The latter derive from decomposition of the regioisomeric alpha-hydroperoxy silanes 4 by elimination of silanol. Regioselectivities up to 97:3 were observed for vinylsilanes with a methyl group geminal to the silyl group and with cyclic derivatives. Z-Configurated substrates showed lower regioselectivity and reactivity. Elongation of the carbon chain at the geminal position also increased the amount enone formed. These results are rationalized in terms of stereoelectronic effects imposed by the silyl group on the ring-opening of the perepoxide intermediate.
• Zaitseva, G. S.; Livantsova, L. I.; Bekker, R. A., Journal of general chemistry of the USSR, 1983, vol. 53, # 9, p. 1867 - 1874
  作者：Zaitseva, G. S.、Livantsova, L. I.、Bekker, R. A.、Baukov, Yu. I.、Lutsenko, I. F.

  DOI：——

  日期：——
• The Stereochemistry of the Addition of Silicochloroform to Acetylenes
  作者：Robert A. Benkeser、Richard A. Hickner

  DOI：10.1021/ja01552a072

  日期：1958.10
• The Stereochemistry of the Addition of Silicochloroform to Acetylenes. A Comparison of Catalyst Systems
  作者：Robert A. Benkeser、Merwyn L. Burrous、Lee E. Nelson、Joseph V. Swisher

  DOI：10.1021/ja01482a022

  日期：1961.11